Process for preparing polymer dispersions, the resulting dispersions and their use
View Patent ↗A description is given of a process of emulsion polymerization of free-radically polymerizable ethylenically unsaturated monomers selected from the group of the monoesters or diesters of ethylenically unsaturated monocarboxylic or dicarboxylic acids with alkanols, vinyl esters and/or vinylaromatics and, if desired, further monomers copolymerizable therewith, at least 60% of the total conversion in the polymerization taking place at a temperature of 100° C. to 160° C., the polymerization being performed in the presence of emulsifiers and an amount of 0% to 1% by weight, based on the total amount of the monomers used, of protective colloid. The process can be used to obtain significantly faster conversions for comparable quality of the process products. The dispersions obtained can be employed in a wide variety of different applications, such as binders for paints or as adhesives.
1. A process of emulsion polymerization of free-radically polymerizable ethylenically unsaturated monomers selected from the group of monoesters or diesters of ethylenically unsaturated monocarboxylic or dicarboxylic acids with alkanols, vinyl esters and/or vinylaromatics and, optionally, further monomers copolymerizable therewith, at least 60% of total conversion in the emulsion polymerization taking place at a temperature of 100° C. to 160° C., which comprises performing the emulsion polymerization in the presence of emulsifiers and optionally in the presence of protective colloids, the protective colloids being present in an amount of from 0% to 0.8% by weight, based on a total amount of the monomers used, and wherein a water-soluble initiator is used without the use of an oil soluble initiator, and wherein the process comprises a metering process in which 5% to 50% by weight of the monomers, based on the total amount of monomers, is included in the initial charge.
2. The process as claimed in claim 1 , wherein the duration of polymerization is less than 1.5 hours.
3. The process as claimed in claim 1 , wherein the emulsion polymerization is performed at least partly under pressure.
4. The process as claimed in claim 3 , wherein at least one gaseous monomer is used which is added under pressure and wherein the gaseous monomer is added only after 10%-50% by weight of the total amount of monomers have undergone conversion.
5. The process as claimed in claim 3 , wherein at least one gaseous monomer is used which is added under pressure and wherein the gaseous monomer is added at the beginning of the emulsion polymerization.
6. The process as claimed in claim 1 , wherein the ethylenically unsaturated monomers comprise esters of ethylenically unsaturated monocarboxylic or dicarboxylic acids, optionally in combination with one or more ethylenically unsaturated monomers copolymerizable therewith.
7. The process as claimed in claim 1 , wherein the ethylenically unsaturated monomers comprise vinyl esters, optionally in combination with one or more ethylenically unsaturated monomers copolymerizable therewith.
8. The process as claimed in claim 7 , wherein the polymerization is performed under pressure and wherein monomers used are vinyl acetate and ethylene and, optionally, further monomers copolymerizable therewith, the copolymerization taking place in the presence of nonionic emulsifiers, optionally in combination with polyvinyl alcohol, or in the presence of nonionic and anionic emulsifiers, optionally in combination with polyvinyl alcohol.
9. The process as claimed in claim 2 , wherein the duration of polymerization phase is less than 1 hour.
10. The process as claimed in claim 3 , wherein the emulsion polymerization is performed at least partly at a pressure of from 10 to 80 bar.
11. The process as claimed in claim 6 , wherein the esters of ethylenically unsaturated monocarboxylic or dicarboxylic acids comprise esters of α,β-ethylenically unsaturated C 3 -C 8 monocarboxylic or dicarboxylic acids.
12. The process as claimed in claim 11 , wherein the esters of α,β-ethylenically unsaturated C 3 -C 8 monocarboxylic or dicarboxylic acids comprise esters of acrylic acid, esters of methacrylic acid, or combinations thereof.
13. The process as claimed in claim 7 , wherein the monomers used in polymerization are selected from the group consisting of vinyl acetate homopolymers, copolymers of vinyl acetate with one or more other vinyl esters, copolymers of vinyl acetate with one or more other vinyl esters and with one or more acrylic esters and/or methacrylic esters, copolymers of vinyl acetate with ethylene, copolymers of vinyl acetate with ethylene and with one or more other vinyl esters, copolymers of vinyl acetate with ethylene and with one or more acrylic esters and/or methacrylic esters, copolymers of vinyl acetate with ethylene and with one or more ethylenically unsaturated epoxide compounds, copolymers of vinyl acetate with ethylene and with one or more ethylenically unsaturated silanes, copolymers of vinyl acetate with ethylene and with one or more ethylenically unsaturated epoxide compounds and with one or more ethylenically unsaturated silanes, and copolymers of vinyl acetate with ethylene and with vinyl chloride.
14. The process as claimed in claim 8 , wherein further monomers copolymerizable with vinyl acetate and ethylene are utilized, the further monomers selected from the group consisting of acrylic esters, methacrylic esters, other vinyl esters, ethylenically unsaturated epoxide compounds, ethylenically unsaturated silanes, and combinations thereof.
15. A process of emulsion polymerization of free-radically polymerizable ethylenically unsaturated monomers selected from the group of monoesters or diesters of ethylenically unsaturated monocarboxylic or dicarboxylic acids with alkanols, vinyl esters and/or vinylaromatics and, optionally, further monomers copolymerizable therewith, at least 60% of total conversion in the emulsion polymerization taking place at a temperature of 100° C. to 160° C., which comprises performing the emulsion polymerization in the presence of emulsifiers and optionally in the presence of protective colloids, the protective colloids being present in an amount of from 0% to 0.8% by weight, based on a total amount of the monomers used, and wherein a water-soluble initiator is used without the use of an oil soluble initiator, and wherein the emulsion polymerization is performed at least partly under pressure and wherein at least one gaseous monomer is used which is added under pressure and wherein the gaseous monomer is added only after 10%-50% by weight of the total amount of monomers have undergone conversion.
16. The process as claimed in claim 15 , wherein the duration of the polymerization is less than 1.5 hours.
17. The process as claimed in claim 15 , wherein the ethylenically unsaturated monomers comprise esters of ethylenically unsaturated monocarboxylic or dicarboxylic acids, optionally in combination with one or more ethylenically unsaturated monomers copolymerizable therewith.
18. The process as claimed in claim 15 , wherein the ethylenically unsaturated monomers comprise vinyl esters, optionally in combination with one or more ethylenically unsaturated monomers copolymerizable therewith.
19. The process as claimed in claim 15 , wherein the emulsion polymerization is performed at least partly at a pressure of from 10 to 80 bar.