Polyurea and polyurethane compositions for golf equipment
View Patent ↗Golf equipment having improved cut and shear resistance that includes a polyurea composition, preferably saturated and/or water resistant, formed of a polyurea prepolymer and a curing agent, wherein the polyurea prepolymer includes an isocyanate and an amine-terminated compound, and wherein the curing agent includes a hydroxy-terminated curing agent, amine-terminated curing agent, or a mixture thereof.
1. A golf ball comprising a core, an intermediate layer, and a cover, wherein at least one layer comprises a composition comprising:
a prepolymer comprising a reaction product of an isocyanate and an amine-terminated component, wherein the amine-terminated component is selected from the group consisting of amine-terminated hydrocarbons, amine-terminated polyethers, amine-terminated polyesters, amine-terminated polycaprolactones, amine-terminated polycarbonates, amine-terminated polyamides, and mixtures thereof; and
a curative blend comprising amine-terminated curing agents.
2. The golf ball of claim 1 , wherein the curative blend comprises 3,5-dimethylthio-2,4-toluenediamine, 3,5-dimethylthio-2,6-toluenediamine, 3,5-diethylthio-2,4-toluenediamine, 3,5-diethylthio-2,6-toluenediamine, and mixtures thereof.
3. The golf ball of claim 1 , wherein the curative blend comprises trimethyleneglycol-di-p-aminobenzoate; polytetramethyleneoxide-di-p-aminobenzoate, and mixtures thereof.
4. The golf ball of claim 1 , wherein curative blend comprises N,N′-dialkylamino-diphenylmethane.
5. The golf ball of claim 1 , wherein the isocyanate is selected from the group consisting of 2,2′-, 2,4′-, and 4,4′-diphenylmethane diisocyanate (MDI), 3,3′-dimethyl-4,4′-biphenyl diisocyanate (TODI), toluene diisocyanate (TDI), polymeric MDI, carbodimide-modified liquid 4,4′-diphenylmethane diisocyanate, para-phenylene diisocyanate (PPDI), meta-phenylene diisocyanate (MPDI), triphenylmethane-4,4′-, and triphenylmethane-4,4″-triisocyanate, napthylene-1,5,-diisocyanate, 2,4′-, 4,4′-, and 2,2-biphenyl diisocyanate, polyphenyl polymethylene polyisocyanate (PMDI), and mixtures thereof.
6. A golf ball comprising a core, an inner cover layer, and an outer cover layer, wherein the outer cover layer is formed of a composition comprising:
a prepolymer, wherein the prepolymer comprises an isocyanate and an amine-terminated component, wherein the amine-terminated component is selected from the group consisting of amine-terminated hydrocarbons, amine-terminated polyethers, amine-terminated polyesters, amine-terminated polycaprolactones, amine-terminated polycarbonates, amine-terminated polyamides, and mixtures thereof; and
a curative blend.
7. The golf ball of claim 6 , wherein the inner cover layer comprises a thermoplastic material.
8. The golf ball of claim 6 , wherein the thermoplastic material comprises an ionomer resin.
9. The golf ball of claim 6 , wherein the curative blend comprises 3,5-dimethylthio-2,4-toluenediamine, 3,5-dimethylthio-2,6-toluenediamine, 3,5-diethylthio-2,4-toluenediamine, 3,5-diethylthio-2,6-toluenediamine, and mixtures thereof.
10. The golf ball of claim 6 , wherein the curative blend comprises trimethyleneglycol-di-p-aminobenzoate; polytetramethyleneoxide-di-p-aminobenzoate, and mixtures thereof.
11. The golf ball of claim 6 , wherein the curative blend comprises N,N′-dialkylamino-diphenylmethane.
12. A golf ball comprising a core and a cover, wherein at least one layer comprises a composition comprising:
a polyurea prepolymer comprising a reaction product of an isocyanate and an amine-terminated component, wherein the amine-terminated component is selected from the group consisting of amine-terminated hydrocarbons, amine-terminated polyethers, amine-terminated polyesters, amine-terminated polycaprolactones, amine-terminated polycarbonates, amine-terminated polyamides, and mixtures thereof; and
an amine-terminated curing agent.
13. The golf ball of claim 12 , wherein the at least one layer is a cover layer.
14. The golf ball of claim 12 , wherein the cover comprises an inner cover layer and an outer cover layer, and wherein the outer cover layer comprises the composition.
15. The golf ball of claim 14 , wherein the inner cover layer comprises an ionomer resin.
16. The golf ball of claim 12 , wherein the amine-terminated curing agent comprises 3,5-dimethylthio-2,4-toluenediamine, 3,5-dimethylthio-2,6-toluenediamine, 3,5-diethylthio-2,4-toluenediamine, 3,5-diethylthio-2,6-toluenediamine, and mixtures thereof.
17. The golf ball of claim 12 , wherein the amine-terminated curing agent comprises trimethyleneglycol-di-p-aminobenzoate; polytetramethyleneoxide-di-p-aminobenzoate, and mixtures thereof.
18. The golf ball of claim 12 , wherein the amine-terminated curing agent comprises N,N′-dialkylamino-diphenylmethane.
19. The golf ball of claim 12 , wherein the composition further comprises a pigment.
20. The golf ball of claim 12 , wherein the at least one layer is a cover cast from the composition.