Process for the preparation of nanocrystalline metal oxides
View Patent ↗The present invention relates to a process for the preparation of nanocrystalline metal oxide particles comprising the steps of a) the introduction of a starting compound into a reaction chamber by means of a carrier fluid, b) the subjecting of the starting compound in a treatment zone to a pulsating thermal treatment, c) the forming of nanocrystalline metal oxide particles, d) the removal of the nanocrystalline metal oxide particles obtained in steps b) and c) from the reactor, wherein the starting compound is introduced into the reaction chamber in the form of a solution, slurry, suspension or in solid aggregate state. Further, the present compound relates to a catalyst material, obtainable by the process according to the invention, in particular a catalyst material for use in the preparation of methanol from carbon monoxide and hydrogen.
1. Process for the preparation of nanocrystalline metal oxide particles comprising the steps of
a) the introduction of a starting compound into a combustion chamber of a reactor by means of a carrier fluid, the reactor comprising the combustion chamber and a resonance tube, wherein the resonance tube is attached to an exhaust side of the combustion chamber,
b) the subjecting of the starting compound in a treatment zone of the combustion chamber to a thermal treatment of a pulsating flow at a temperature of 240 to 600° C., wherein the starting compound has a residence time in the treatment zone of 200 milliseconds to 2 seconds,
c) the forming of nanocrystalline metal oxide particles,
d) the removal of the nanocrystalline metal oxide particles obtained in steps b) and c) from the reactor,
characterized in that the starting compound is introduced into the combustion chamber in the form of a solution, slurry, suspension or in solid aggregate state.
2. Process according to claim 1 , characterized in that the carrier fluid is a gas.
3. Process according to claim 1 , characterized in that the starting compound is introduced into the combustion chamber in atomized form.
4. Process according to claim 1 , characterized in that one or more starting compounds are used which are identical to or different from one another.
5. Process according to claim 4 , characterized in that the pulsation of the pulsating flow is regular or irregular.
6. Process according to claim 1 , characterized in that after the thermal treatment in the treatment zone, the nanocrystalline metal particles that have formed are transferred into a colder zone of the reactor.
7. Process according to claim 6 , characterized in that a metal oxide is used as starting material.
8. Process according to claim 6 , characterized in that a soluble metal compound is used as starting compound.
9. Process according to claim 1 , characterized in that the process is carried out at a pressure between 15-40 bar.