Process for manufacturing steel blanks
View Patent ↗The invention relates to a manufacturing process for steel blanks. The invention relates in particular to a manufacturing process of a steel blank comprising electroslag remelting (ESR—ElectroSlag Remelting) or vacuum arc remelting (VAR—Vacuum Arc Remelting) to obtain very good mechanical properties. The blanks obtained can be used especially in the field of the manufacture of pressurised equipment elements and especially cannon tubes.
1. A manufacturing process for a steel blank comprising electroslag remelting (ESR—ElectroSlag Remelting) of an electrode, said blank having a composition comprising, after ESR:
Carbon: 0.35-0.43,
Manganese: <0.20,
Silicon: <0.20,
Nickel: greater than 3.00 and less than or equal to 4.00,
Chrome: 1.30-1.80,
Molybdenum: 0.70-1.00,
Vanadium: 0.20-0.35,
Iron: balance
in percentages by weight of the total composition, and including dinitrogen, dioxygen and dihydrogen,
wherein the composition of the slag for ESR comprises:
CaF 2 : 60-70;
Al 2 O 3 : 10-20;
CaO: 10-20;
SiO 2 : 5-10;
in percentages by weight of the total composition of the slag.
2. The process as claimed in claim 1 , wherein said blank composition comprises, after ESR:
Carbon: 0.37-0.42,
Manganese: <0.15,
Silicon: <0.100,
Nickel: 3.50-3.80,
Chrome: 1.50-1.70,
Molybdenum: 0.70-1.00,
Vanadium: 0.25-0.30,
Iron: balance
in percentages by weight of the total composition, and includes dinitrogen at <70 ppm, dioxygen at <30 ppm and dihydrogen at <1.8 ppm.
3. The process as claimed in claim 2 , further comprising continuous deoxidation of the slag by addition of aluminium.
4. The process as claimed in claim 2 , further comprising performing the ESR remelting in an inert atmosphere.
5. The process as claimed in claim 1 , further comprising performing VAD type (Vacuum Arc Degassing) prior to the ESR.
6. The process as claimed in claim 5 , further comprising transferring of metal without bringing in slag from an electric oven, prior to the working of the VAD type.
7. The process as claimed in claim 6 , further comprising an electric arc oven processing prior to transferring of metal without bringing in slag from the electric oven.
8. The process as claimed claim 5 , wherein said VAD step comprises VCD processing (Vacuum Carbon Deoxidation) comprising measuring oxygen activity, addition of a complement of slag for adjusting the composition of the electrode before ESR to ensure silicon contents of less than 0.050%, aluminium of less than 0.012%, at the same time ensuring dioxygen activity content of less than 10 ppm, the final degassing to obtain dihydrogen content<1.2 ppm, and final decantation to ensure elimination of metallic inclusions.
9. The process as claimed in claim 1 , further comprising annealing comprising at least maintaining temperature for an adequate period to ensure essentially completely martensitic transformation of the blank composition obtained after ESR.
10. The process as claimed in claim 9 , further comprising transformation of the blanks by forging, followed by thermal processing to obtain steel having essentially a fully martensitic structure after annealing.
11. The process of claim 1 , wherein said blank is further processed to prepare a pressurized equipment element.
12. A manufacturing process for a steel blank comprising electroslag remelting (ESR—ElectroSlag Remelting) of an electrode, said blank having a composition comprising, after ESR:
Carbon: 0.37-0.42,
Manganese: 0.060-0.130,
Silicon: 0.040-0.120,
Nickel: greater than 3.00 and less than or equal to 4.00,
Chrome: 1.30-1.80,
Molybdenum: 0.70-1.00
Vanadium: 0.25-0.30,
Aluminium: ≦0.015,
in percentages by weight of the total composition, and includes dinitrogen at <70 ppm, dioxygen at <30 ppm and dihydrogen at <1.8 ppm,
wherein the composition of the slag for ESR comprises:
CaF 2 : 60-70;
Al2O 3 : 10-20;
CaO: 10-20
SiO 2 : 5-10;
in percentages by weight of the total composition of the slag.
13. The process of claim 12 , wherein said blank is further processed to prepare a pressurized equipment element.