Biodegradable resin composition and molded article of the same
View Patent ↗An object of the invention is to provide a resin composition which is particularly excellent in impact resistance, tensile elongation characteristics, heat resistance, surface properties, moldability and the like accompanied by less time dependent alteration of these properties and which is produced by mixing a certain plasticizer with a biodegradable polymer of plant origin, and to provide a molded product of the composition. The present invention can provide a resin composition comprising a biodegradable 3-hydroxyalkanoate copolymer (A) and a plasticizer (B), wherein: the biodegradable 3-hydroxyalkanoate copolymer (A) has a recurring unit represented by the structure formula (1): [—CHR—CH 2 —CO—O—] (wherein, R represents an alkyl group represented by C n H 2n+1 ; and n is an integer of 1 to 15); the plasticizer (B) is based upon a polyglycerol acetic acid ester having an acetylation degree of no less than 50% ester.
1. A resin composition comprising a biodegradable 3-hydroxyalkanoate copolymer (A) and a plasticizer (B), wherein:
the biodegradable 3-hydroxyalkanoate copolymer (A) has a recurring unit represented by the structure formula (1): [—CHR—CH 2 —CO—O—] (wherein, R represents an alkyl group represented by C n H 2n+1 ; and n is an integer of 1 to 15) and the copolymer (A) is constituted with poly[3-hydroxybutyrate-co-3-hydroxyhexanoate] having a recurring unit of 3-hydroxybutyrate and a recurring unit of 3-hydroxyhexanoate as a principal component;
the plasticizer (B) is constituted with 100 to 50% by weight of a polyglycerol acetic acid ester having an acetylation degree of no less than 50%, and 0 to 50% by weight of a monoglycerol ester; and
the resin composition comprises 0.1 to 50 parts by weight of the plasticizer (B) based on 100 parts by weight of the copolymer (A).
2. The resin composition according to claim 1 further comprising (C) a biodegradable poly 3-hydroxyalkanoate having a melting temperature Tm2 higher than the melting temperature Tm1 of the copolymer (A), wherein:
the melting temperature Tm2 of the biodegradable poly 3-hydroxyalkanoate (C) satisfies the relational expression of Tm2≧Tm1+5° C. and wherein the melting temperatures Tm1and Tm2 is determined on the basis of a peak of the endothermic curve drawn along with melting of 1 to 10 mg of a sample of the copolymer (A) or the biodegradable poly 3-hydroxyalkanoate (C) by elevating the temperature from 30° C. at a rate of 10° C/min until being raised to 30 to 40° C. higher than the temperature at which each sample is sufficiently melted, then lowering the temperature at a rate of 10° C/min to 30° C., and again elevating the temperature at a rate of 10° C/min until being raised to 30 to 40° C. higher than the temperature at which each sample is sufficiently melted, using a differential scanning calorimeter; and
the resin composition contains 0.1 to 30 parts by weight of the biodegradable poly 3-hydroxyalkanoate (C) based on 100 parts by weight of the copolymer (A).
3. The resin composition according to claim 1 wherein the copolymer (A) has a weight average molecular weight of 300,000 to 3,000,000.
4. The resin composition according to claim 1 wherein the component ratio of the recurring units of the poly[3-hydroxybutyrate-co-3-hydroxyhexanoate] in terms of 3-hydroxybutyrate unit/3-hydroxyhexanoate unit is 99/1 to 80/20 (mol/mol).
5. The resin composition according to claim 1 wherein the polyglycerol acetic acid ester having an acetylation degree of no less than 50% is at least one selected from the group consisting of a diglycerol acetic acid ester and a triglycerol acetic acid ester having an acetylation degree of no less than 50%.
6. The resin composition according to claim 1 wherein the monoglycerol ester is diacetylmonoacylglycerol with a constitutive fatty acid having no less than 8 carbon atoms.
7. The resin composition according to claim 2 wherein the biodegradable poly 3-hydroxyalkanoate (C) is poly 3-hydroxybutyrate.