IP Library Granted Patent US 8,211,952
Granted Patent B2
US 8,211,952 · App. 12/377,109 · Granted Jul 3, 2012

Curable sealing method and foamed composition

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Quick Facts
Patent No.
US 8,211,952
App. No.
12/377,109
Granted
Jul 3, 2012
Kind
B2
Abstract

A foamed composition adapted to seal to a substrate is provided. The foamed composition includes a radiation curable rubber, a photoinitiator, a blowing agent, a styrene-ethylene/butylene block copolymer, a light mineral oil, rheology modifier, a tackifier, and one of a radiation curable monomer and radiation curable oligomer, and wherein the composition is foamed upon application to the substrate.

Claims (19)

1. An article adapted to seal to a substrate, the article comprising:

a composition comprising a radiation curable rubber, a photoinitiator, a styrene-ethylene/butylene block copolymer, a light mineral oil, a rheology modifier, a tackifier, and at least one of a radiation curable monomer and radiation curable oligomer; and

a blowing agent blended with the composition prior to application on the substrate.

2. The article of claim 1 wherein the radiation curable rubber comprises a styrene-butadiene-styrene block copolymer.

3. The article of claim 2 wherein the radiation curable rubber is curable by ultra-violet radiation.

4. The article of claim 3 wherein the blowing agent is gaseous nitrogen.

5. The article of claim 3 wherein the blowing agent is a hydrofluorocarbon.

6. The article of claim 4 wherein one of the radiation curable monomer and radiation curable oligomer is a polybutadiene diacrylate.

7. The article of claim 6 wherein the rheology modifier is fumed silica.

8. The article of claim 7 further comprising one or more fillers, pigments, antioxidants, and wetting agents.

9. A foamed composition adapted to seal to a substrate, the foamed composition comprising:

from about 10 to 25% of a radiation curable styrene-butadiene-styrene block copolymer, from about 40 to 75% by weight of a mineral oil, from about 1 to 10% by weight of a tackifier, from about 10 to 25% by weight of a styrene-isoprene-styrene block copolymer, from about 1 to 3% by weight of a fumed silica, from about 0.5 to 1.5% by weight of a photoinitiator, and from about 1 to 3% by weight of a polybutadiene diacrylate.

10. A method for sealing a composition to a substrate comprising the steps of:

mixing a composition with a blowing agent, the composition comprising a radiation curable rubber, a photoinitiator, a blowing agent, a styrene-ethylene/butylene block copolymer, a light mineral oil, a rheology modifier, a tackifier, and one of a radiation curable monomer and radiation curable oligomer;

applying the mixed composition and blowing agent to a substrate; and

curing the mixed composition and blowing agent with a radiation source after the mixed composition and blowing agent has foamed on the substrate.

11. The method of claim 10 wherein the step of curing the mixed composition and blowing agent includes curing the mixed composition and blowing agent with ultra-violet radiation.

12. The method of claim 10 wherein mixing the composition with the blowing agent includes mixing the composition with nitrogen.

13. The method of claim 10 wherein mixing the composition with the blowing agent includes mixing the composition with a hydrofluorocarbon.

Assignments (14)
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS (TERM LOAN) Recorded Feb 15, 2023
From: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
To: H.B. FULLER COMPANY; H.B. FULLER CONSTRUCTION PRODUCTS INC.; ROYAL ADHESIVES AND SEALANTS, LLC; ADCO PRODUCTS, LLC
Reel/Frame 062761/0884 →
TERM LOAN SECURITY AGREEMENT Recorded Oct 25, 2017
From: H.B. FULLER COMPANY; H.B. FULLER CONSTRUCTION PRODUCTS INC.; ROYAL ADHESIVES AND SEALANTS, LLC; ADCO PRODUCTS, LLC
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 044616/0671 →
RCF SECURITY AGREEMENT Recorded Oct 25, 2017
From: H.B. FULLER COMPANY; H.B. FULLER CONSTRUCTION PRODUCTS INC.; ROYAL ADHESIVES AND SEALANTS, LLC; ADCO PRODUCTS, LLC
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 044616/0700 →
RELEASE OF SECURITY INTEREST IN PATENT COLLATERAL AT REEL/FRAME NO. 36018/0518 (FIRST LIEN) Recorded Oct 20, 2017
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: ADCO PRODUCTS, LLC
Reel/Frame 044568/0878 →
RELEASE OF SECURITY INTEREST IN PATENT COLLATERAL AT REEL/FRAME NO. 036018/0710 (SECOND LIEN) Recorded Oct 20, 2017
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: ADCO PRODUCTS, LLC
Reel/Frame 044570/0064 →
FIRST LIEN PATENT SECURITY AGREEMENT Recorded Jun 24, 2015
From: ADCO PRODUCTS, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 036018/0518 →
SECOND LIEN PATENT SECURITY AGREEMENT Recorded Jun 24, 2015
From: ADCO PRODUCTS, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 036018/0710 →
RELEASE OF SECURITY INTEREST IN PATENTS (RELEASES RF 030948/0689) Recorded Jun 23, 2015
From: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
To: ROYAL ADHESIVES AND SEALANTS, LLC; ADCO PRODUCTS, LLC (F/K/A ADCO PRODUCTS, INC.); ETERNABOND, LLC (F/K/A ETERNABOND, INC.); MILLENNIUM ADHESIVE PRODUCTS, LLC (F/K/A MILLENNIUM ADHESIVE PRODUCTS, INC.)
Reel/Frame 036009/0276 →
RELEASE OF SECURITY INTEREST IN PATENTS (RELEASES RF 030956/0529 Recorded Jun 23, 2015
From: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
To: ROYAL ADHESIVES AND SEALANTS, LLC; ADCO PRODUCTS, LLC (F/K/A ADCO PRODUCTS, INC.); ETERNABOND, LLC (F/K/A ETERNABOND, INC.); MILLENNIUM ADHESIVE PRODUCTS, LLC (F/K/A MILLENNIUM ADHESIVE PRODUCTS, INC.)
Reel/Frame 036007/0771 →
CONVERSION Recorded Oct 21, 2014
From: ADCO PRODUCTS, INC.
To: ADCO PRODUCTS, LLC
Reel/Frame 034029/0660 →
SECOND LIEN PATENT SECURITY AGREEMENT Recorded Aug 7, 2013
From: ROYAL ADHESIVES AND SEALANTS, LLC; ADCO PRODUCTS, INC.; MILLENNIUM ADHESIVE PRODUCTS, INC.; ETERNABOND, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
Reel/Frame 030956/0529 →
FIRST LIEN PATENT SECURITY AGREEMENT Recorded Aug 6, 2013
From: ROYAL ADHESIVES AND SEALANTS, LLC; ADCO PRODUCTS, INC.; MILLENNIUM ADHESIVE PRODUCTS, INC.; ETERNABOND, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
Reel/Frame 030948/0689 →
RELEASE OF SECURITY INTEREST Recorded Aug 5, 2013
From: GENERAL ELECTRIC CAPITAL CORPORATION
To: ADCO PRODUCTS, INC.; MILLENNIUM ADHESIVE PRODUCTS, INC.; WTT SYSTEMS, LLC; ETERNABOND, INC.
Reel/Frame 030961/0432 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 23, 2009
From: KENDRA, ELI; BOOTH, DENNIS; SNOWWHITE, PAUL
To: ADCO PRODUCTS, INC.
Reel/Frame 023413/0909 →