Flat alkaline primary battery
An object of the invention is to provide a flat alkaline primary battery that is inexpensive and has excellent battery capacity and capacity retention. A flat alkaline primary battery has a positive electrode can and a negative electrode can. The negative electrode can is fitted, from its opening side equipped with a gasket, into an opening of the positive electrode can. The opening of the positive electrode can is caulked against the gasket and thus sealed, thereby creating an enclosed space between the positive electrode can and the negative electrode can. The enclosed space has disposed therein a positive electrode mixture, a separator, and a negative electrode mixture. With the separator in between, the positive electrode mixture is placed on the positive electrode can side, and the negative electrode mixture is placed on the negative electrode can side. The enclosed space is filled with an alkaline electrolyte. Zinc or zinc alloy powder is used as a negative electrode active material, and nickel oxyhydroxide is used as a positive electrode active material. The negative electrode mixture at least contains, as active material stabilizers, a highly cross-linked polyacrylic acid, a non-cross-linked polyacrylic acid, and carboxymethylcellulose.
1 . A flat alkaline primary battery comprising:
a positive electrode comprising a positive electrode active material containing nickel oxyhydroxide;
a negative electrode comprising a negative electrode active material containing zinc or zinc alloy;
an active material stabilizer in the negative electrode containing highly cross-linked polyacrylic acid, non-cross-linked polyacrylic acid, and
carboxymethylcellulose.
2 . A flat alkaline primary battery according to claim 1 , wherein the highly cross-linked polyacrylic acid is present in the negative electrode in a proportion of 0.05% or more and 3% or less.
3 . A flat alkaline primary battery according to claim 1 , wherein the non-cross-linked polyacrylic acid is present in the negative electrode in a proportion of 0.05% or more and 1% or less.
4 . A flat alkaline primary battery according to claim 2 , wherein the non-cross-linked polyacrylic acid is present in the negative electrode in a proportion of 0.05% or more and 1% or less.
5 . A flat alkaline primary battery according to claim 1 , wherein the carboxymethylcellulose is present as an active in the negative electrode in a proportion of 0.5% or more and 3% or less.
6 . A flat alkaline primary battery according to claim 2 , wherein the carboxymethylcellulose is present as an active in the negative electrode in a proportion of 0.5% or more and 3% or less.
7 . A flat alkaline primary battery according to claim 3 , wherein the carboxymethylcellulose is present in the negative electrode in a proportion of 0.5% or more and 3% or less.