Thermally-stable polycrystalline diamond element and compact, and applications therefor such as drill bits
View Patent ↗Embodiments of the invention relate to thermally-stable polycrystalline diamond (“PCD”) elements, polycrystalline diamond compacts (“PDCs”), and methods of fabricating such PCD elements and PDCs. In an embodiment, a PCD element includes a PCD body comprising bonded diamond grains defining a plurality of interstitial regions. The PCD body includes a first volume having a first portion of the interstitial regions and a second volume having a second portion of the interstitial regions. The PCD body further includes an infiltrant that is disposed in the first portion of the interstitial regions and the second portion of the interstitial regions is substantially free of the infiltrant. The infiltrant comprises a glass, a glass-ceramic, silicone, a thermal decomposition reaction product of silicone, a ceramic having a negative coefficient of thermal expansion, or combinations thereof.
1. A polycrystalline diamond element, comprising:
a polycrystalline diamond body including bonded diamond grains defining a plurality of interstitial regions, the polycrystalline diamond body including a first volume having a first portion of the interstitial regions and a second volume having a second portion of the interstitial regions, the first volume including an infiltrant disposed in the first portion of the interstitial regions thereof and the second volume being substantially free of the infiltrant; and
wherein the infiltrant comprises at least one member selected from the group consisting of a glass, a glass-ceramic, silicone, a thermal decomposition reaction product of silicone, and a ceramic having a negative coefficient of thermal expansion.
2. The polycrystalline diamond element of claim 1 wherein:
the polycrystalline diamond body comprises an upper surface and an opposing back surface; and
the infiltrant infiltrated into the polycrystalline diamond body from the upper surface thereof generally to an intermediate location therewithin.
3. The polycrystalline diamond element of claim 1 wherein the second portion of the interstitial regions comprises a metal-solvent catalyst disposed therein.
4. The polycrystalline diamond element of claim 3 wherein the metal-solvent catalyst is selected from the group consisting of iron, nickel, cobalt, and alloys thereof.
5. The polycrystalline diamond element of claim 1 wherein the second portion of the interstitial regions comprises a braze alloy disposed therein.
6. The polycrystalline diamond element of claim 1 wherein the at least one member is a glass, and further wherein the glass comprises ceramic particles dispersed therethrough.
7. The polycrystalline diamond element of claim 6 wherein the ceramic particles are selected from the group consisting of boron nitride particles, titanium diboride particles, zirconium oxide particles, and combinations thereof.
8. The polycrystalline diamond element of claim 1 wherein the at least one member is a glass, and further wherein the glass is selected from the group consisting of a silicate, a borate, a borosilicate, and combinations thereof.
9. The polycrystalline diamond element of claim 1 wherein the at least one member is a thermal decomposition reaction product of silicone.
10. The polycrystalline diamond element of claim 1 wherein the at least one member is a ceramic having a negative coefficient of thermal expansion, and further wherein the ceramic is selected from zirconium tungstate, beta spodumene, beta eucryptite, and combinations thereof.
11. The polycrystalline diamond element of claim 1 wherein the first volume of the polycrystalline diamond body comprises a substantially planar upper surface.
12. A polycrystalline diamond compact, comprising:
a substrate;
a polycrystalline diamond table bonded to the substrate, the polycrystalline diamond table including bonded diamond grains defining a plurality of interstitial regions, the polycrystalline diamond table including a first volume remote from the substrate having an infiltrant disposed interstitially between the bonded diamond grains thereof and a second volume adjacent to the substrate having metal-solvent catalyst disposed interstitially between the bonded diamond grains thereof; and
wherein the infiltrant comprises at least one member selected from the group consisting of a glass, a glass-ceramic, silicone, a thermal decomposition reaction product of silicone, and a ceramic having a negative coefficient of thermal expansion.
13. The polycrystalline diamond compact of claim 12 wherein:
the polycrystalline diamond table comprises an upper surface and an opposing interfacial surface bonded to the substrate; and
the infiltrant infiltrated into the polycrystalline diamond table from the upper surface thereof to no further than an intermediate location therewithin.
14. The polycrystalline diamond compact of claim 12 wherein the at least one member is a glass, and further wherein the glass comprises ceramic particles dispersed therethrough.
15. The polycrystalline diamond compact of claim 14 wherein the ceramic particles are selected from the group consisting of boron nitride particles, titanium diboride particles, zirconium oxide particles, and combinations thereof.
16. The polycrystalline diamond compact of claim 12 wherein the at least one member is a glass, and further wherein the glass is selected from the group consisting of a silicate, a borate, a borosilicate, and combinations thereof.
17. The polycrystalline diamond compact of claim 12 wherein the at least one member is a thermal decomposition reaction product of silicone.
18. The polycrystalline diamond compact of claim 12 wherein the at least one member is a ceramic having a negative coefficient of thermal expansion, and further wherein the ceramic is selected from zirconium tungstate, beta spodumene, beta eucryptite, and combinations thereof.
19. The polycrystalline diamond compact of claim 12 wherein the first volume of the polycrystalline diamond table comprises a substantially planar upper surface.
20. The polycrystalline diamond compact of claim 12 wherein the metal-solvent catalyst is selected from the group consisting of iron, nickel, cobalt, and alloys thereof.
21. The polycrystalline diamond compact of claim 12 wherein the polycrystalline diamond table is integrally formed with the substrate.
22. The polycrystalline diamond compact of claim 12 wherein the polycrystalline diamond table is a pre-sintered polycrystalline diamond table.
23. A rotary drill bit, comprising:
a bit body configured to engage a subterranean formation; and
a plurality of polycrystalline diamond cutting elements affixed to the bit body, at least one of the polycrystalline diamond cutting elements including:
a polycrystalline diamond body including bonded diamond grains defining a plurality of interstitial regions, the polycrystalline diamond body including a first volume having a first portion of the interstitial regions and a second volume having a second portion of the interstitial regions, the first volume including an infiltrant disposed in the first portion of the interstitial regions thereof and the second volume being substantially free of the infiltrant; and
wherein the infiltrant comprises at least one member selected from the group consisting of a glass, a glass-ceramic, silicone, a thermal decomposition reaction product of silicone, and a ceramic having a negative coefficient of thermal expansion.
24. The rotary drill bit of claim 23 wherein the second volume of the polycrystalline diamond body of the at least one polycrystalline diamond cutting element is infiltrated with a braze alloy that bonds the second volume to the bit body.
25. The rotary drill bit of claim 23 wherein the polycrystalline diamond body of the at least one polycrystalline diamond cutting element is configured as a polycrystalline diamond table that is bonded to a substrate.