Carbon dioxide rich off-gas from a two stage gasification process

1. A non-catalytic two-stage process for gasification of a carbonaceous material, which process comprises the steps of:

(a) combusting in a first reaction zone a stream comprising an oxygen-containing gas and a first feedstock comprising of a slurry of particulate carbonaceous material in a liquid carrier at a temperature of between 2400° F. (1316° C.) and 3000° F. (1649° C.) and at a pressure of from 50 psig (345 kPa gage) to 600 psig (4137 kPa gage), thereby evolving heat and forming a first reaction product comprising liquid, molten slag and a gaseous products stream and entrained byproduct sticky, molten slag particles;

(b) separating out and removing said liquid and molten slag;

(c) combusting, in a second reaction zone a stream comprising an oxygen-containing gas, and a second feedstock comprising that portion of said first reaction product which comprises said gaseous products stream and said entrained byproduct sticky, molten slag particles and a second increment of a slurry of particulate carbonaceous material in a liquid carrier, at a temperature of between 2400° F. (1316° C.) and 3000° F. (1649° C.) and at a pressure of from 50 psig (345 kPa gage) to 600 psig (4137 kPa gage), thereby evolving heat and forming a second reaction product comprising liquid, molten slag and a gaseous products stream and entrained byproduct sticky, molten slag particles, and a stream of predominately carbon dioxide;

(d) recovering a second portion of the heat from said gaseous products stream of the second reaction product in a high temperature heat recovery system, including a fire-tube boiler, whereby the gaseous products are cooled to a temperature of about 450° F. to about 550° F. (232° C. to 288.7° C.); and

(e) recovering said stream of predominately carbon dioxide.

2. The process of claim 1 wherein the carrier liquid is water.

3. The process of claim 1 wherein said slurry of said steps (a) and (c) have a solids concentration from 30 to 70 percent by weight.

4. The process of claim 1 wherein the oxygen-containing gas selected from the group consisting of oxygen, oxygen-enriched air, and mixtures thereof.

5. The process of claim 1 wherein the oxygen-containing gas is oxygen-enriched air and the initial atomic ratio of free elemental oxygen to carbon in the reactor is between 1.5:1 and 2.5:1.

6. The process of claim 5 in which the solids content is from about 45 to about 55 percent by weight in both step (a) and step (b).

7. The process of claim 1 wherein said carbonaceous material is coal or lignite.

8. The process of claim 1 wherein said second reaction zone is connected to the top of said first reaction zone.

9. The process of claim 1 wherein said stream of predominately carbon dioxide is cooled and recycled into the first reaction zone.

10. The process of claim 1 wherein said stream said stream of predominately carbon dioxide is sequestered.