High melt flow propylene impact copolymer and method
View Patent ↗The present disclosure provides a polymerization process for the production of a high melt flow propylene impact copolymer. The process includes contacting an active propylene-based polymer having a melt flow rate greater than about 100 g/10 min with one or more olefins in a polymerization reactor to form the propylene impact copolymer with a melt flow rate greater than about 60 g/10 min. The production of the high melt flow propylene impact copolymer may occur in one or more polymerization reactors, utilizing standard hydrogen concentration, and no visbreaking.
1. A polymerization process comprising:
gas phase polymerizing, in a first polymerization reactor, an active propylene-based polymer having a melt flow rate greater than 100 g/10 min as measured in accordance with ASTM D1238-01 (230° C., 2.16 kg);
introducing the active propylene-based polymer into a second polymerization reactor;
contacting the active propylene-based polymer with at least one olefin in a second reactor under polymerization conditions; and
forming a propylene impact copolymer having a melt flow rate greater than 60 g/10 min.
2. The process of claim 1 comprising contacting propylene and optionally at least one other olefin with a catalyst composition in the first polymerization reactor, the catalyst composition comprising a procatalyst, a cocatalyst and a mixed external electron donor (M-EED) comprising a first selectivity control agent (SCA1), a second selectivity control agent (SCA2), and an activity limiting agent (ALA).
3. The process of claim 1 comprising maintaining a H 2 /C 3 mole ratio of less than 0.3 in a member selected from the group consisting of the first polymerization reactor, the second polymerization reactor, and combinations thereof.
4. The process of claim 1 comprising maintaining a H 2 /C 3 mole ratio of less than 0.1 in the second polymerization reactor.
5. The process of claim 1 comprising introducing, into the second reactor, a component selected from the group consisting of a mixed external electron donor (M-EED), a first selectivity control agent (SCA1), a second selectivity control agent (SCA2), an activity limiting agent (ALA), and combinations thereof.
6. The process of claim 1 comprising contacting the active propylene-based polymer with propylene and ethylene and forming a propylene impact copolymer having an Fc value from about 5 wt % to about 50 wt % and an Ec value from about 20 wt % about 90 wt %.
7. The process of claim 1 comprising forming a propylene impact copolymer having a volatiles content of less than 65 μg/g as measured in accordance with VW standard PV3341.
8. The process of claim 1 comprising self-limiting the polymerization with the catalyst composition when the temperature is greater than 100° C. in a reactor selected from the group consisting of the first polymerization reactor, the second polymerization reactor, and combinations thereof.
9. A polymerization process comprising:
contacting, in a polymerization reactor under polymerization conditions, at least one olefin with an active propylene-based polymer having a melt flow rate greater than 100 g/10 min as measured in accordance with ASTM D-1238-01 (230° C., 2.16 kg); and
forming a propylene impact copolymer having a melt flow rate greater than 85 g/10 min.
10. The process of claim 9 comprising contacting the at least one olefin with the active propylene-based polymer in a gas phase polymerization reactor.
11. The process of claim 9 comprising maintaining a H 2 /C 3 mole ratio less than 0.20.
12. The process of claim 9 wherein the active propylene-based polymer comprises a self-liming catalyst composition, the process comprising self-limiting the polymerization when the temperature in the polymerization reactor is greater than 100° C.
13. The process of claim 9 comprising contacting propylene and ethylene with the active propylene-based polymer; and forming a propylene impact copolymer with an Fc value from about 5 wt % to about 50 wt %, and an Ec value from about 20 wt % to about 90 wt %.
14. The process of claim 9 comprising forming a propylene impact copolymer having a volatiles content of less than 65 μg/g as measured in accordance with VW standard PV3341.
15. A propylene impact copolymer comprising:
a propylene-based polymer having a melt flow rate (MFR) greater than 100 g/10 min as measured in accordance with ASTM D-1238-01 (230° C., 2.16 kg);
a propylene/ethylene copolymer dispersed within the propylene-based polymer; and
the propylene impact copolymer having a melt flow rate greater than 60 g/10 min, an Fc value from about 5 wt % to about 50 wt %, an Ec value from about 20 wt % to about 90 wt %.
16. The propylene impact copolymer of claim 15 wherein the MFR of the propylene-based polymer is greater than 160 g/10 min and the MFR of the propylene impact copolymer is greater than 85 g/10 min.
17. The propylene impact copolymer of claim 15 wherein the propylene-based polymer has a property selected from the group consisting of a xylene solubles content less than about 4%, a T MF greater than about 170° C., and combinations thereof.
18. The propylene impact copolymer of claim 15 wherein the propylene-based polymer is uncracked.
19. The propylene impact copolymer of claim 15 comprising a volatiles content less than 65 μg/g as measured in accordance with VW standard PV3341.
20. The propylene impact copolymer of claim 15 comprising at least 5 ppm of an activity limiting agent.