Golf ball layer having reduced surface hardness and method of making same
View Patent ↗A golf ball comprising a core and a cover, wherein the core comprises a thermoset rubber composition, a geometric center and a treated outer surface, the treated outer surface having a first hardness and the geometric center having a second hardness, the treated outer surface being treated with a surface-softening material comprising at least one fatty acid and/or fatty acid salt plasticizer composition such that the second hardness is greater than the first hardness to define a negative hardness gradient. In another emobodiment, the golf ball comprises a thermoset rubber composition core and a cover, said core comprising a treated outer surface and a geometric center, the treated outer surface comprising a fatty acid and/or fatty acid salt plasticizer composition and extending inward from the surface from about 0.001 inches to about 0.100 inches, the treated outer surface further having a first hardness and the geometric center having a second hardness, wherein the first hardness is less than the second hardness to define a negative hardness gradient.
1. A golf ball comprising a core and a cover, wherein the core comprises a thermoset rubber composition, a geometric center and a treated outer surface, the treated outer surface having a first hardness and the geometric center having a second hardness, the treated outer surface being treated with a surface-softening material comprising at least one fatty acid and/or fatty acid salt plasticizer composition such that the second hardness is greater than the first hardness to define a negative hardness gradient.
2. The golf ball of claim 1 , wherein the thermoset rubber composition comprises a polybutadiene material having a surface hardness of at least about 50 Shore C.
3. The golf ball of claim 2 , wherein the polybutadiene material is at least partially crosslinked.
4. The golf ball of claim 1 , wherein the at least one fatty acid and/or fatty acid salt plasticizer composition comprises oleic acid, palmitic acid, stearic acid, behenic acid, pelargonic acid, linoleic acid, linolenic acid, arachidonic acid, caproic acid, caprylic acid, capric acid, lauric acid, erucic acid, myristic acid, benzoic acid, phenylacetic acid, or naphthalenoic acid.
5. The golf ball of claim 4 , wherein the at least one fatty acid and/or fatty acid salt plasticizer composition comprises a cation selected from the group comprising barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin and calcium.
6. The golf ball of claim 1 , wherein the at least one fatty acid and/or fatty acid salt plasticizer composition further comprises antioxidants, sulfur-bearing compounds, zinc methacrylate, zinc dimethacrylate, softening acrylate monomers or oligomers, soft powdered thermoplastic resins, phenol-comprising antioxidants, or hydroquinones.
7. The golf ball of claim 6 , wherein the soft powdered thermoplastic resins comprise polyethylene vinyl acetate, polyethylene butyl acrylate, polyethylene methyl acrylate, or very-low-modulus ionomer.
8. The golf ball of claim 1 , further comprising an outer core layer disposed about the core to form a dual core comprising an untreated outer surface having a hardness.
9. The golf ball of claim 1 , further comprising an intermediate layer disposed about the core and between the core and the cover layer.
10. A golf ball comprising a thermoset rubber composition core and a cover, said core comprising a treated outer surface and a geometric center, the treated outer surface comprising a fatty acid and/or fatty acid salt plasticizer composition and extending inward from the surface from about 0.001 inches to about 0.100 inches, the treated outer surface further having a first hardness and the geometric center having a second hardness, wherein the first hardness is less than the second hardness to define a negative hardness gradient.