Heat transfer system comprising brazed aluminum, method, heat transfer fluid, and additive package
View Patent ↗Disclosed herein is heat transfer system, comprising a brazed aluminum component, and a heat transfer fluid in fluid communication with the brazed aluminum component, wherein the heat transfer fluid comprises a liquid coolant, an oxy-anion of molybdenum, tungsten, vanadium, phosphorus, antimony, or a combination thereof, and a corrosion inhibitor. Also disclosed is a method of preventing corrosion in the heat transfer system, and a heat transfer fluid and additive package for use in the heat transfer system.
1. A heat transfer system, comprising:
a brazed aluminum component; and
a heat transfer fluid in fluid communication with a brazed aluminum surface of the brazed aluminum component;
wherein the heat transfer fluid consists of:
a) a liquid coolant;
b) an oxy-anion selected from the group consisting of molybdenum, tungsten, vanadium, phosphorus, antimony, and a combination thereof;
c) a corrosion inhibitor selected from the group consisting of azole-based corrosion inhibitors, siloxane-based corrosion inhibitors, colloidal silica, carboxylates, tall oil fatty acids, alkali or alkaline earth metal, and combinations thereof; and
d) optionally, additives selected from the group consisting of colorants, antifoam agents, wetting agents, biocides, bitterants, dispersants, and combinations thereof.
2. The heat transfer system of claim 1 , wherein the liquid coolant is an alcohol, water, or a combination thereof.
3. The heat transfer system of claim 2 , wherein the liquid coolant is about 0.1 to about 90 percent by weight water, based on the total weight of the heat transfer fluid.
4. The heat transfer system of claim 2 , wherein the liquid coolant is about 1 to about 99.9 percent by weight of the alcohol, based on the total weight of the heat transfer fluid.
5. The heat transfer system of claim 2 , wherein the alcohol is a monohydric alcohol, polyhydric alcohol, or a combination thereof.
6. The heat transfer system of claim 2 , wherein the alcohol is selected from the group consisting of methanol, ethanol, propanol, butanol, tetrahydrofurfuryl alcohol, ethoxylated furfuryl alcohol, alkoxy alkanol, ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, dipropylene glycol, butylene glycol, glycerol, glycerol-1,2-dimethyl ether, glycerol-1,3 dimethyl ether, monoethylether of glycerol, sorbitol, 1,2,6-hexanetriol, trimethylol propane, and a combination thereof.
7. The heat transfer system of claim 1 , wherein the oxy-anion of molybdenum, tungsten, vanadium, phosphorus, antimony, or combination thereof is a water soluble salt selected from the group consisting of an alkali metal, alkaline earth metal, ammonium, and amine salt of a molybdate, a tungstate, a metatungstate, a vanadate, a metavanadate, an ortho phosphate, a pyro-phosphate, a hexametaphosphate, a polyphosphate, a phosphoric acid, an antimony tartrates, an antimonate, a hydroxyantimonate, or a combination thereof.
8. The heat transfer system of claim 1 , wherein the heat transfer fluid is about 0.01 to about 10 percent by weight of the oxy-anion of molybdenum, tungsten, vanadium, phosphorus, antimony, or combination thereof, based on the total amount of the heat transfer fluid.
9. The heat transfer system of claim 1 , wherein the oxy-anion of molybdenum, tungsten, vanadium, phosphorus, antimony, or combination thereof is an oxy-anion of phosphorus, and further comprises an oxy-anion of molybdenum, tungsten, vanadium, antimony, or a combination thereof.
10. The heat transfer system of claim 9 , wherein the heat transfer fluid is about 0.01 to about 3 percent by weight of the oxy-anion of phosphorus, and is about 0.01 to about 3 percent by weight of the oxy-anion of molybdenum, tungsten, vanadium, antimony, or combination thereof, based on the total weight of the heat transfer fluid.
11. The heat transfer system of claim 1 , wherein the corrosion inhibitor is an azole-based corrosion inhibitor, a siloxane-based corrosion inhibitor, colloidal silica, a silicate, a carboxylate, a tall oil fatty acid, a borate, a nitrate, a nitrite, an alkali or alkaline earth metal salt thereof, an ammonium salt thereof, an amine salt thereof, or a combination thereof.
12. The heat transfer system of claim 1 , wherein the corrosion inhibitor is a carboxylate selected from the group consisting of C 5 -C 24 aromatic and aliphatic, mono-, di- and tri carboxylic acids and carboxylic acid salts, and a combination thereof.
13. The heat transfer system of claim 1 , wherein the corrosion inhibitor is a combination of two or more selected from the group consisting of an azole-based corrosion inhibitor, a siloxane-based corrosion inhibitor, colloidal silica, a silicate, a carboxylate, a tall oil fatty acid, a borate, a nitrate, a nitrite, an alkali or alkaline earth metal salt thereof, an ammonium salt thereof, an amine salt thereof.
14. A method of preventing corrosion in a heat transfer system, comprising: contacting the heat transfer system with a heat transfer fluid; wherein the heat transfer system comprises:
a brazed aluminum component; and
a heat transfer fluid in fluid communication with a brazed aluminum surface of the brazed aluminum component;
and wherein the heat transfer fluid consists of:
a) a liquid coolant;
b) an oxy-anion selected from the group consisting of molybdenum, tungsten, vanadium, phosphorus, antimony, and a combination thereof;
c) a corrosion inhibitor selected from the group consisting of azole-based corrosion inhibitors, siloxane-based corrosion inhibitors, colloidal silica, carboxylates, tall oil fatty acids, alkali or alkaline earth metal, and combinations thereof; and
d) optionally, additives selected from the group consisting of colorants, antifoam agents, wetting agents, biocides, bitterants, dispersants, and combinations thereof.