COPPER CONTAINING POLYESTER-POLYAMIDE COMPOSITIONS
The specification claims the unexpected result that copper containing compounds can be used to impart thermal stability to a polyester polyamide mixture, when the mixture contains an ionic compatibilizer such as sulfoisophthalic acid.
1 . A resin composition comprising a polyester, a polyamide, an ionic compatibilizer and a copper compound.
2 . The composition of claim 1 wherein the copper compound is present in the range of about 5 to 500 ppm by the weight of copper to the weight of the polyamide.
3 . The composition of claim 1 , wherein the copper compound is cupric stearate, copper iodide, copper (I) bromide or copper (II) bromide.
4 . The composition of claim 2 , wherein the copper compound is cupric stearate, copper (I) bromide or copper (II) bromide.
5 . The composition of claim 3 , wherein the composition further comprises a halogenated compound.
6 . The composition of claim 4 , wherein the composition further comprises a halogenated compound.
7 . The composition claim 2 , wherein the polyamide is MXD6 nylon.
8 . The composition claim 4 , wherein the polyamide is MXD6 nylon.
9 . The composition claim 6 , wherein the polyamide is MXD6 nylon.
10 . An article of manufacture comprising the resin composition of claim 1 , wherein the article is selected from the group consisting of container walls and preforms for the manufacturing of the wall of a container.
11 . An article of manufacture comprising the resin composition of claim 2 , wherein the article is selected from the group consisting of container walls and preforms for the manufacturing of the wall of a container.
12 . An article of manufacture comprising the resin composition of claim 4 , wherein the article is selected from the group consisting of container walls and preforms for the manufacturing of the wall of a container.
13 . An article of manufacture comprising the resin composition of claim 6 , wherein the article is selected from the group consisting of container walls and preforms for the manufacturing of the wall of a container.
14 . An article of manufacture comprising the resin composition of claim 9 , wherein the article is selected from the group consisting of container walls and preforms for the manufacturing of the wall of a container.
15 . A process for thermally treating a resin pellet comprising a polyester, an ionic compatibilizer, a polyamide, a copper compound and water wherein the process comprises exposing the resin pellet to a temperature in the range of 70° C. and 1° C. less than the temperature at which the resin pellet becomes liquid for a period of time where the period of time is selected from the group consisting of time sufficient to remove 25% of the water from the resin pellet, time sufficient to increase the crystallinity of the polyester by at least about 5% or time sufficient to increase the Intrinsic Viscosity of the polyester in the resin pellet by at least about 0.05 dl/g.
16 . The process of claim 15 , wherein the copper compound is cupric stearate, copper iodide, copper (I) bromide or copper (II) bromide.
17 . The process of claim 16 , wherein the resin pellet further comprises an iodide compound.
18 . The process of claim 15 , wherein the resin pellet further comprises a halogenated compound.
19 . The process claim 15 , wherein the polyamide is MXD6 nylon.
20 . The process claim 16 , wherein the polyamide is MXD6 nylon.