Azeotropic compositions of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf), 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb), and hydrogen fluoride (HF)

1. A ternary azeotropic or azeotrope-like composition consisting essentially of hydrogen fluoride, 2-chloro-3,3,3-trifluoropropene, and 2-chloro-1,1,1,2-tetrafluoropropane.

2. An azeotropic or azeotrope-like composition which consists essentially of from about 1 to about 50 weight percent hydrogen fluoride, from about 50 to about 99 weight percent of an organic portion consisting essentially of 2-chloro-3,3,3-trifluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane, wherein the 2-chloro-3,3,3-trifluoropropene in the organic portion of the mixture is present in the amount from about 50 to about 90 weight percent of the organic portion, and the 2-chloro-1,1,1,2-tetrafluoropropane in the organic portion of the mixture is present in the amount from about 10 to about 50 weight percent of the organic portion, and the azeotropic composition has a boiling point of from about 0° C. to about 61° C. at a pressure of from about 15 psia to about 108 psia.

3. The composition of claim 2 which consists of hydrogen fluoride, 2-chloro-3,3,3-trifluoropropene, and 2-chloro-1,1,1,2-tetrafluoropropane.

4. The composition of claim 2 wherein the hydrogen fluoride is present in the amount from about 5 to about 40 weight percent.

5. The composition of claim 2 wherein the organic portion is present in the amount from about 60 to about 95 weight percent.

6. The composition of claim 2 wherein the 2-chloro-3,3,3-trifluoropropene in the organic portion is present in the amount from about 51.5 to about 86.5 weight percent of the organic portion.

7. The composition of claim 2 wherein the 2-chloro-1,1,1,2-tetrafluoropropane in the organic portion of the azeotrope is present in the amount from about 13.5 to about 48.5 weight percent of the organic portion.

8. The composition of claim 2 having a boiling point of about 23° C. at a pressure of about 37 psia; or a boiling point of about 0° C. at a pressure of about 15 psia; or a boiling point of about 61° C. at a pressure of about 108 psia.

9. A method of forming an azeotropic or azeotrope-like composition which comprises forming a blend consisting essentially of from about 1 to about 50 weight percent hydrogen fluoride, from about 50 to about 99 weight percent of an organic portion consisting essentially of 2-chloro-3,3,3-trifluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane, wherein the 2-chloro-3,3,3-trifluoropropene in the organic portion of the mixture is present in the amount from about 50 to about 90 weight percent of the organic portion, and the 2-chloro-1,1,1,2-tetrafluoropropane in the organic portion of the mixture is present in the amount from about 10 to about 50 weight percent of the organic portion to thereby form an azeotropic or azeotrpic-like composition having a boiling point of from about 0° C. to about 61° C. at a pressure of from about 15 psia to about 108 psia.

10. The method of claim 9 wherein the azeotropic or azeotrope-like composition consists of hydrogen fluoride, 2-chloro-3,3,3-trifluoropropene, and 2-chloro-1,1,1,2-tetrafluoropropane.

11. The method of claim 9 wherein the hydrogen fluoride is present in the amount from about 5 to about 40 weight percent.

12. The method of claim 9 wherein the organic portion is present in the amount from about 60 to about 95 weight percent.

13. The method of claim 9 wherein the 2-chloro-3,3,3-trifluoropropene in the organic portion is present in the amount from about 51.5 to about 86.5 weight percent of the organic portion.

14. The method of claim 9 wherein the 2-chloro-1,1,1,2-tetrafluoropropane in the organic portion of the azeotrope is present in the amount from about 13.5 to about 48.5 weight percent of the organic portion.

15. The method of claim 9 wherein the azeotropic or azeotrope-like composition has a boiling point of about 23° C. at a pressure of about 37 psia; or a boiling point of about 0° C. at a pressure of about 15 psia; or a boiling point of about 61° C. at a pressure of about 108 psia.

16. The method of claim 9 further comprising the step of feeding the azeotropic or azeotropic-like composition of 2-chloro-3,3,3-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane and hydrogen fluoride to a fluorination reactor.

17. The method of claim 9 further comprising the step of separating 2-chloro-3,3,3-trifluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane from an azeotropic or azeotropic-like composition of hydrogen fluoride, 2-chloro-3,3,3-trifluoropropene, and 2-chloro-1,1,1,2-tetrafluoropropane by pressure swing distillation.

18. A method for removing 2-chloro-3,3,3-trifluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane from a mixture containing 2-chloro-3,3,3-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane and at least one other component, which comprises adding hydrogen fluoride to the mixture in an amount sufficient to form a ternary azeotropic or azeotrope-like composition of the hydrogen fluoride, 2-chloro-3,3,3-trifluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane and thereafter separating the ternary azeotropic composition from the at least one other component.

19. The method of claim 18 wherein the at least one other component does not form an azeotropic mixture with 2-chloro-3,3,3-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane, hydrogen fluoride or a mixture of 2-chloro-3,3,3-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane, and hydrogen fluoride.

20. The method of claim 18 wherein the at least one other component does form an azeotropic mixture with 2-chloro-3,3,3-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane, hydrogen fluoride or a mixture of 2-chloro-3,3,3-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane, and hydrogen fluoride.

21. The method of claim 18 wherein the at least one other component comprises a halocarbon.

22. The method of claim 18 wherein the at least one other component comprises one or more of 1,1,1,2,3-pentachloropropane; 1,1,2,3-tetrachloropropene; 2,3,3,3-tetrafluoropropene; 2,3-dichloro-3,3-difluoropropene; 1,1,1,2,2-pentafluoropropane; and 1,2-dichloro-3,3,3-trifluoropropene.

23. The method of claim 18 wherein the separating is conducted by distillation.

24. The method of claim 18 wherein the azeotropic composition consists essentially of from about 1 to about 50 weight percent hydrogen fluoride, and from about 50 to about 99 weight percent of an organic portion consisting essentially of a mixture of 2-chloro-3,3,3-trifluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane, wherein the 2-chloro-3,3,3-trifluoropropene in the organic portion of the mixture is present in the amount from about 50 to about 90 weight percent of the organic portion, and the 2-chloro-1,1,1,2-tetrafluoropropane in the organic portion of the mixture is present in the amount from about 10 to about 50 weight percent of the organic portion.

25. The method of claim 18 wherein the azeotropic composition consists essentially of from about 5 to about 40 weight percent hydrogen fluoride, and from about 60 to about 95 weight percent of the organic portion, and the 2-chloro-3,3,3-trifluoropropene in the organic portion of the mixture is present in an amount from about 51.5 to about 86.5 weight percent of the organic portion, and the 2-chloro-1,1,1,2-tetrafluoropropane in the organic portion of the mixture is present in the amount from about 13.5 to about 48.5 weight percent of the organic portion.