Method for producing composite member of metal member and resin member
View Patent ↗The invention discloses an injection molding method for manufacture of a metal-resin composite member; wherein the resin composition used in the method includes a plurality of metal particles having one or more metal melting points between about 200° C. and 400° C.; the resin composition is heated to a temperature higher than the resin melting point and higher than one or more metal melting points to provide a heated resin composition; and wherein injecting the heated resin into a mold results in contact of the heated resin with one or more disposed heated metal member(s) to provide a composite member.
1. A method for producing a composite member having a metal member and a resin member, the method comprising the steps of:
a) providing a resin composition comprising (i) thermoplastic resin having a resin melting point and/or a glass transition, and a solidification point; and (ii) a plurality of metal particles having one or more metal melting points between about 130° C. and 400° C.;
b) disposing one or more metal member(s) in a mold cavity, each said metal member(s) having at least one exposed surface, and said mold cavity, optionally, having at least one mold cavity exposed surface;
c) heating the one or more metal member(s) to a temperature equal or higher than at least one of the melting points of the plurality of metal particles to provide one or more heated metal member(s);
d) heating the resin composition to a temperature higher than the resin melting point and higher than one or more metal melting points to provide a heated resin;
e) injecting the heated resin into the mold to contact each heated metal member(s) exposed surface to provide a heated composite member;
f) cooling said heated composite member below the resin solidification point; and
g) removing the composite member from the mold cavity;
to provide said composite member having an interfacial junction strength between said metal member(s) and said resin member of at least 3 MPa.
2. The method of claim 1 , wherein heating the metal member is performed in the mold by induction heating.
3. The method of claim 1 , wherein the metal particles are a Sn alloy or Li alloy.
4. The method of claim 1 , wherein the metal particles are selected from the group consisting of Sn—Cu alloys, Sn—Sb alloys, Sn—Al alloys, Sn—Zn alloys, Sn—Pt alloys, Sn—Mn alloys, Sn—Ag alloys, Sn—Ag—Cu alloys, Sn—Ag—Cu—Bi alloys, Sn—Ag—Cu—Sb alloys, Sn—Au alloys, Al—Li alloys, and Zn—Li alloys.
5. The method of claim 1 , wherein part, or all of, at least one mold cavity exposed surface is treated to inhibit adhesion with the metal particles.
6. The method of claim 1 , wherein the metal member and resin member have an interfacial junction strength of at least 10 MPa.
7. The method of claim 1 , wherein the metal particles in the resin composition are in a molten state in step e).
8. The method of claim 1 , wherein the metal particles in the resin composition are in a molten state in step d).
9. The method of claim 1 comprising 1 to 10 vol. % of the metal particles.
10. The method of claim 1 comprising 3 to 10 vol. % of the metal particles.
11. The method of claim 1 comprising 1 to 7 vol. % of the metal particles.
12. The method of claim 1 comprising 3 to 7 vol. % of the metal particles.
13. The method of claim 1 , wherein the resin composition is a polyimide resin.
14. The method of claim 1 , wherein the resin composition is a copolyamide, the copolyamide comprising terephthalic acid, adipic acid, and hexamethylene diamine.