Sodium nitrite oxidation of hydrogen sulfide
View Patent ↗A method for treating hydrogen sulfide in a solution includes providing the solution containing hydrogen sulfide. The method also includes adding sodium nitrite to the solution in an amount suitable to react with the hydrogen sulfide and treat the hydrogen sulfide.
1. A method for removing hydrogen sulfide from water, wherein the water comprises hydrogen sulfide, comprising:
adding sodium nitrite to the water in an amount suitable to react with the hydrogen sulfide in the water and remove hydrogen sulfide from the water; and
adding a pH buffer periodically to the water to maintain the pH of the water between about 7.0 to about 9.0 and to remove free ammonia from the water.
2. The method of claim 1 , wherein the water comprises from about 2,000 mg/liter to about 25,000 mg/liter hydrogen sulfide.
3. The method of claim 1 , wherein the water comprises from about 5,000 mg/liter to about 25,000 mg/liter hydrogen sulfide.
4. The method of claim 1 , wherein the water comprises from about 10,000 mg/liter to about 25,000 mg/liter hydrogen sulfide.
5. The method of claim 1 , wherein the sodium nitrite is added at a weight ratio to hydrogen sulfide from about 0.676:1 to about 5.0:1.
6. The method of claim 1 , wherein the sodium nitrite is added at a weight ratio to hydrogen sulfide from about 0.676:1 to about 1.353:1.
7. The method of claim 1 , wherein the pH buffer comprises an acidic buffering chemical.
8. The method of claim 1 , wherein the pH buffer comprises citric acid, phosphoric acid, boric acid, or any combinations thereof.
9. The method of claim 1 , wherein the pH buffer comprises citric acid, phosphoric acid, or any combinations thereof.
10. The method of claim 1 , wherein the pH buffer comprises phosphoric acid.
11. The method of claim 1 , wherein the reaction between the sodium nitrite and the hydrogen sulfide is carried out at between about 40° C. and about 70° C.
12. The method of claim 1 , wherein the reaction between the sodium nitrite and the hydrogen sulfide is carried out at between about 40° C. and about 50° C.
13. The method of claim 1 , wherein the reaction between the sodium nitrite and the hydrogen sulfide produces ammonia, the method further comprises blowing an ammonia-removal gas to remove the produced ammonia.
14. The method of claim 13 , wherein the ammonia-removal gas is blown by a compressor.