Miscibility of otherwise immiscible compounds
View Patent ↗The present invention relates to a novel method for compatibilizing, i.e. improving miscibility of, otherwise immiscible organic materials highly useful in the fibers industry, as well as the compatibilized product of the method. These compatibilized products are stable in the liquid phase at temperatures ranging from about 40° C. to about 200° C. The method involves use of a glycol derived from polymerization of alkylene oxide and tetrahydrofuran, the alkylene oxide having from 2 to 4 carbon atoms, i.e. poly(tetramethylene-co-alkyleneether) glycol, in the mixture.
1. A method for manufacturing a stable compatibilized mixture of two or more immiscible organic compounds, the method consisting of steps (1) combining the two or more immiscible organic compounds with from about 10 to about 80 wt. % glycol derived from polymerization of alkylene oxide having from 2 to 4 carbon atoms and tetrahydrofuran, (2) heating the combination of step (1) at a temperature of from about 35° C. to about 65° C., and (3) recovering a compatibilized product mixture stable in the liquid phase at a temperature of from about 40° C. to about 200° C., said compatibilized product mixture consisting of the two or more immiscible organic compounds and the glycol derived from polymerization of alkylene oxide having from 2 to 4 carbon atoms and tetrahydrofuran.
2. The method of claim 1 wherein said immiscible organic compounds are a first organic compound selected from the group consisting of short chain glycols, polyethers and mixtures thereof, and a second organic compound selected from the group consisting of long chain polyols, polyesters and mixtures thereof.
3. The method of claim 1 wherein said compatibilized product mixture of step (3) is stable in the liquid phase at a temperature of from about 50° C. to about 100° C.
4. The method of claim 2 wherein said first organic compound is selected from the group consisting of ethylene glycol, polyethylene glycol, polypropylene glycol, butanediol and mixtures thereof, and said second organic compound is a polyether polyol.
5. The method of claim 2 wherein said first organic compound is selected from the group consisting of ethylene glycol, butanediol and mixtures thereof, and said second organic compound is selected from the group consisting of polytetramethylene ether glycol, polypropylene glycol, polycaprolactone glycol or a mixture thereof.
6. The method of claim 2 wherein said first organic compound is polyethylene glycol, and said second organic compound is selected from the group consisting of polytetramethylene ether glycol, polypropylene glycol or a mixture thereof.
7. The method of claim 1 wherein said combination of step (1) consists of from about 10 to about 45 wt. % of one or a mixture of first organic compounds, and from about 10 to about 45 wt. % of one or a mixture of second organic compounds generally immiscible with said first organic compounds.
8. The method of claim 7 wherein said first organic compound is selected from the group consisting of short chain glycols, polyethers and mixtures thereof, and said second organic compound is selected from the group consisting of long chain polyols, polyesters and mixtures thereof.
9. The method of claim 7 wherein said compatibilized product mixture of step (3) is stable in the liquid phase at a temperature of from about 50° C. to about 100° C.
10. The method of claim 8 wherein said first organic compound is selected from the group consisting of ethylene glycol, polyethylene glycol, polypropylene glycol, butanediol and mixtures thereof, and said second organic compound is a polyether polyol.
11. The method of claim 7 wherein said first organic compound is selected from the group consisting of ethylene glycol, butanediol and mixtures thereof, and said second organic compound is selected from the group consisting of polytetramethylene ether glycol, polypropylene glycol, polycaprolactone glycol or a mixture thereof.
12. The method of claim 7 wherein said first organic compound is polyethylene glycol, and said second organic compound is selected from the group consisting of polytetramethylene ether glycol, polypropylene glycol or a mixture thereof.