Copolyether glycol manufacturing process

1. A continuous process for manufacturing copolyether glycol having a high molar incorporation of alkylene oxide of at least about 50 mol %, a mean molecular weight of from about 650 dalton to about 4000 dalton and a viscosity of from about 80 cP to about 4000 cP comprising the steps of:

a′) polymerizing in a continually stirred tank reactor from about 15 to about 90 parts feedstock comprising from about 10 to about 90 wt % tetrahydrofuran and from about 10 to about 90 wt % of at least one alkylene oxide, in the presence of from about 0.1 to about 5 wt % of at least one compound containing reactive hydrogen atoms, from 10 to about 40 wt % of inert diluent or solvent, and an acid polymeric catalyst containing sulfonic acid groups at a temperature of from about 30° C. to about 80° C. to produce a polymerization product mixture comprising OCE, copolyether glycol having a high molar incorporation of alkylene oxide of at least about 50 mol %, a mean molecular weight of from about 650 dalton to about 4000 dalton and a viscosity of from about 80 cP to about 4000 cP, at least one dimer of the alkylene oxide, linear short chain copolyether glycol and tetrahydrofuran;

b′) separating a majority of the tetrahydrofuran and the dimer of the alkylene oxide from the polymerization product mixture of step a′) to produce a crude product mixture comprising OCE, copolyether glycol having a high molar incorporation of alkylene oxide of at least about 50 mol %, a mean molecular weight of from about 650 dalton to about 4000 dalton and a viscosity of from about 80 cP to about 4000 cP, and linear short chain copolyether glycol;

c′) separating at least a portion of the OCE and linear short chain copolyether glycol from the crude product mixture of step b′) to produce an OCE stream comprising OCE and linear short chain copolyether glycol, and a product stream comprising copolyether glycol having a high molar incorporation of alkylene oxide of at least about 50 mol %, a mean molecular weight of from about 650 dalton to about 4000 dalton and a viscosity of from about 80 cP to about 4000 cP;

d′) optionally recycling at least a portion of the OCE stream of step c′) to the polymerization step a′); and

further comprising filtering the polymerization product mixture of step a′) prior to step b′), and filtering the crude product mixture of step b′) prior to step c′).

2. The process of claim 1 wherein the alkylene oxide is selected from the group consisting of ethylene oxide; 1,2-propylene oxide; 1,3-propylene oxide; 1,2-butylene oxide; 2,3-butylene oxide; 1,3-butylene oxide; and combinations thereof.

3. The process of claim 1 wherein the compound containing reactive hydrogen atoms is selected from the group consisting of water, ethylene glycol, 1,4-butanediol, poly(tetramethylene ether) glycol having a molecular weight of from about 130 dalton to about 400 dalton, copolyether glycol having a molecular weight of from about 130 dalton to about 400 dalton, and combinations thereof.

4. The process of claim 1 wherein the tetrahydrofuran further comprises at least one alkyltetrahydrofuran selected from the group consisting of 2-methyltetrahydrofuran, 3-methyltetrahydrofuran, 3-ethyltetrahydrofuran and combinations thereof.

5. The process of claim 1 wherein the diluent or solvent is selected from the group consisting one or a combination of linear or branched short chain hydrocarbons of from 5 to 8 carbon atoms, cyclic hydrocarbons of from 5 to 8 carbon atoms, stable oxygenates and substituted or unsubstituted aromatic hydrocarbons, said diluent or solvent having a boiling point of from about 40° C. to about 150° C.

6. The process of claim 5 wherein the diluent or solvent comprises hexane, heptane, cyclohexane, 1,4-dioxane, toluene, xylene or combinations thereof.

7. The process of claim 1 wherein the polymeric catalyst comprises a perfluorosulfonic acid resin.

8. The process of claim 1 wherein the alkylene oxide comprises ethylene oxide and the dimer of the alkylene oxide comprises 1,4-dioxane.

9. The process of claim 1 further comprising separating at least a portion of the dimer of the alkylene oxide obtained in step b′) from the tetrahydrofuran obtained in step b′), and optionally recycling to polymerization step a′) at least a portion of the tetrahydrofuran so obtained.