Method for producing phenol and acetone
View Patent ↗A method for producing phenol and acetone in a multi-stage process at an elevated temperature from a cumene hydroperoxide mixture comprising cumene, comprises the steps of: a) distilling an amount of cumene from the cumene hydroperoxide mixture until the cumene mass % is 0 to 7 mass % relative to the total mass of the cumene hydroperoxide mixture, b) reacting the cumene hydroperoxide mixture with an acid catalyst form to a second mixture comprising phenol, acetone and dicumyl peroxide in a first stage, and c) decomposing the second mixture in a second stage to produce phenol and acetone, wherein an amount of phenol approximately equal to the amount of distilled from the cumene hydroperoxide mixture is added to the cumene hydroperoxide mixture before the reacting step b). The amount of hydroxyacetone is reduced, thereby, improving the quality of commercial-grade phenol and the products made from the phenol.
1. A method for producing phenol and acetone in a multi-stage process at an elevated temperature from a cumene hydroperoxide mixture comprising cumene, the method comprising the steps of:
a) distilling an amount of cumene from the cumene hydroperoxide mixture until the cumene mass % is 0 to 7 mass % relative to the total mass of the cumene hydroperoxide mixture,
b) reacting the cumene hydroperoxide mixture with an acid catalyst form to a second mixture comprising phenol, acetone and dicumyl peroxide in a first stage, and
c) decomposing the second mixture in a second stage to produce phenol and acetone,
wherein an amount of phenol, approximately equal to the amount of cumene distilled from the cumene hydroperoxide mixture, is added to the cumene hydroperoxide mixture before the reacting step b).
2. The method of claim 1 , wherein the reacting in the first stage is at a temperature of from 47 to 50° C., and the decomposing in the second stage is at a temperature of from 120 to 140° C.
3. The method of claim 1 , wherein the acid catalyst is sulfuric acid.
4. The method of claim 1 , wherein the cumene hydroperoxide mixture comprises between 50 mass % and 92 mass % cumene hydroperoxide relative to the total mass of the cumene hydroperoxide mixture.
5. The method of claim 1 , wherein the cumene hydroperoxide mixture comprises between 65 mass % and 85 mass % cumene hydroperoxide relative to the total mass of the cumene hydroperoxide mixture.
6. The method of claim 1 , wherein the cumene hydroperoxide mixture comprises between 80 mass % and 84 mass % cumene hydroperoxide relative to the total mass of the cumene hydroperoxide mixture.
7. The method of claim 1 , wherein the step of reacting the cumene hydroperoxide is in at least two serially connected reactors.
8. A method for producing phenol and acetone from a cumene hydroperoxide mixture in a multi-stage process at an elevated temperature, the method comprising the steps of:
a) adding an amount of phenol to the cumene hydroperoxide mixture and distilling the cumene from the cumene hydroperoxide mixture until the cumene mass % is 0 to 7 mass % relative to the total mass of the cumene hydroperoxide mixture,
b) reacting the cumene hydroperoxide mixture with an acid catalyst to form a second mixture comprising dicumyl peroxide in a first stage, and
c) decomposing the second mixture in a second stage to produce phenol and acetone.
9. The method of claim 8 , wherein the reacting in the first stage is at a temperature of from 47 to 50° C., and the decomposing in the second stage is at a temperature of from 120 to 140° C.
10. The method of claim 8 , wherein the acid catalyst is sulfuric acid.
11. The method of claim 8 , wherein the step of reacting the cumene hydroperoxide is in at least two serially connected reactors.
12. A method for producing phenol and acetone in a multi-stage process at an elevated temperature from a cumene hydroperoxide mixture comprising cumene, the method comprising the steps of:
a) distilling an amount of cumene from the cumene hydroperoxide mixture,
b) reacting the cumene hydroperoxide mixture with an acid catalyst to form a second mixture comprising dicumyl peroxide in a first stage, and
c) decomposing the second mixture in a second stage to produce a third mixture comprising phenol, acetone, and hydroxyacetone,
wherein an amount of phenol approximately equal to the amount of cumene distilled from the cumene hydroperoxide mixture is added to the cumene hydroperoxide mixture before the reacting step b),
and wherein the amount of hydroxyacetone in the third mixture is less than or equal to 300 ppm.
13. The method of claim 12 , wherein the reacting in the first stage is at a temperature of from 47 to 50° C., and the decomposing in the second stage is at a temperature of from 120 to 140° C.
14. The method of claim 12 , wherein the amount of hydroxyacetone in the third mixture is less than or equal to 200 ppm.
15. The method of claim 12 , wherein the cumene mass % in the cumene hydroperoxide is reduced in the distilling step to 0 to 7 mass % relative to the total mass of the cumene hydroperoxide mixture.