Fluorescent lamp made of glass and having particular composition
View Patent ↗An object of the present invention is to provide fluorescent lamps used as a light source for liquid crystal display devices, which have excellent characteristics in terms of preventing solarization, the properties for blocking ultraviolet rays, and the physical and thermal strength, and preventing scratching. The present invention provides fluorescent lamps made of glass containing 55.0% to 75.0% of SiO 2 ; 10.0% to 25.0% of B 2 O 3 ; 1.0% to 10.0% of Al 2 O 3 ; 0% to 3.8% of Na 2 O; 0% to 3.0% of Li 2 O; 3.0% to 10.0% of K 2 O; 3.2% to 16.0% of Na 2 O+Li 2 O+K 2 O; 0.5% to 8% of TiO 2 ; 0.1% to 5% of CeO 2 ; 0.6% to 8.1% of TiO 2 +CeO 2 ; 0.001% to 0.05% of Fe 2 O 3 ; 0% to 0.7% of Sb 2 O 3 ; 0.1% to 3.0% of SnO 2 ; and 0.5% to 10.0% of at least one rare earth element selected from the group consisting of Gd, Y, La, Yb and Lu by weight, and is characterized in that the coefficient of linear expansion in a temperature range of 30° C. to 380° C. is 34×10 −7 /° C. to 58×10 −7 /° C.
1. A fluorescent lamp made of glass, comprising:
55.0-75.0 weight % of SiO 2 ;
10.0-25.0 weight % of B 2 O 3 ;
1.0-10.0 weight % of Al 2 O 3 ;
0-3.8 weight % of Na 2 O;
0-3.0 weight % of Li 2 O;
3.0-10.0 weight % of K 2 O;
3.2-16.0 weight % of Na 2 O+Li 2 O+K 2 O;
0.5-8.0 weight % of TiO 2 ;
0.1-5.0 weight % of CeO 2 ;
0.6-8.1 weight % of TiO 2 +CeO 2 ; and
0.5-10.0% of an oxide of at least one rare earth element selected from the group consisting of Gd, Y, La, Yb and Lu as calculated as an oxide Ln 2 O 3 (Ln: rare earth element), wherein
the coefficient of linear expansion of the glass in a temperature range of 30-380° C. is 34×10 −7 /° C. to 58×10 −7 /° C.
2. The fluorescent lamp according to claim 1 , further comprising:
0.001-0.05 weight % of Fe 2 O 3 ;
0-0.7 weight % of Sb 2 O 3 ; and
0.1-3.0 weight % of SnO 2 .
3. The fluorescent lamp according to claim 1 , wherein
microscopic particles are dispersed in the glass, and the microscopic particles include said rare earth element.
4. The fluorescent lamp according to claim 1 , further comprising:
0.5-10.0% of Gd as a rare earth element as calculated as an oxide Gd 2 O 3 .
5. The fluorescent lamp according to claim 1 , wherein the glass is in tube form.
6. The fluorescent lamp according to claim 1 , wherein the glass is in tube form with an outer diameter of 1.8-8.0 mm and a thickness of 0.2-0.6 mm.
7. A fluorescent lamp made of glass, comprising:
55.0-75.0 weight % of SiO 2 ;
10.0-25.0 weight % of B 2 O 3 ;
1.0-10.0 weight % of Al 2 O 3 ;
0-3.8 weight % of Na 2 O;
0-3.0 weight % of Li 2 O;
3.0-10.0 weight % of K 2 O;
6.0-16.0 weight % of Na 2 O+Li 2 O+K 2 O;
0.5-8.0 weight % of TiO 2 ;
0.1-5.0 weight % of CeO 2 ;
0.6-8.1 weight % of TiO 2 +CeO 2 ; and
0.5-10.0% of an oxide of at least one rare earth element selected from the group consisting of Gd, Y, La, Yb and Lu as calculated as an oxide Ln 2 O 3 (Ln: rare earth element), wherein
the coefficient of linear expansion of the glass in a temperature range of 30-380° C. is 46×10 −7 /° C. to 58×10 −7 /° C.
8. The fluorescent lamp according to claim 7 , further comprising:
0.001-0.05 weight % of Fe 2 O 3 ;
0-0.7 weight % of Sb 2 O 3 ; and
0.1-3.0 weight % of SnO 2 .
9. The fluorescent lamp according to claim 7 , wherein
microscopic particles are dispersed in the glass, and the microscopic particles include said rare earth element.
10. The fluorescent lamp according to claim 7 , further comprising:
0.5-10.0% of Gd as a rare earth element as calculated as an oxide Gd 2 O 3 .
11. The fluorescent lamp according to claim 7 , wherein the glass is in tube form.
12. The fluorescent lamp according to claim 7 , wherein the glass is in tube form with an outer diameter of 1.8-8.0 mm and a thickness of 0.2-0.6 mm.
13. A fluorescent lamp made of glass, comprising:
55.0-75.0 weight % of SiO 2 ;
10.0-25.0 weight % of B 2 O 3 ;
1.0-10.0 weight % of Al 2 O 3 ;
0-3.8 weight % of Na 2 O;
0-3.0 weight % of Li 2 O;
3.0-10.0 weight % of K 2 O;
3.2-6.0 weight % of Na 2 O+Li 2 O+K 2 O;
0.5-8 weight % of TiO 2 ;
0.1-5 weight % of CeO 2 ;
0.6-8.1 weight % of TiO 2 +CeO 2 ; and
0.5-10.0% of an oxide of at least one rare earth element selected from the group consisting of Gd, Y, La, Yb and Lu as calculated as an oxide Ln 2 O 3 (Ln: rare earth element), wherein
the coefficient of linear expansion of the glass in a temperature range of 30-380° C. is 34×10 −7 /° C. to 46×10 −7 /° C.
14. The fluorescent lamp according to claim 13 , further comprising:
0.001-0.05 weight % of Fe 2 O 3 ;
0-0.7 weight % of Sb 2 O 3 ; and
0.1-3.0 weight % of SnO 2 .
15. The fluorescent lamp according to claim 13 , wherein
microscopic particles are dispersed in the glass, and the microscopic particles include said rare earth element.
16. The fluorescent lamp according to claim 13 , further comprising:
0.5-10.0% of Gd as a rare earth element as calculated as an oxide Gd 2 O 3 .
17. The fluorescent lamp according to claim 13 , wherein the glass is in tube form.
18. The fluorescent lamp according to claim 13 , wherein the glass is in tube form with an outer diameter of 1.8-8.0 mm and a thickness of 0.2-0.6 mm.