Process for producing flexible polyurethane foam
View Patent ↗To provide a flexible polyurethane foam which is excellent in low resiliency and durability without using a plasticizer and which shows little change in hardness against a change in temperature and at the same time, has high air flow. A process for producing a flexible polyurethane foam, which comprises reacting a polyol mixture comprising the following polyol (A), the following polyol (B) and the following monool (D) with a polyisocyanate compound in the presence of a blowing agent and a foam stabilizer, at an isocyanate index of at least 90, wherein: Polyol (A) is a polyether polyol having an average of from 2 to 3 hydroxyl groups, a hydroxyl value of from 10 to 60 mgKOH/g and an oxyethylene group content of from 0 to 30 mass %, obtained by ring-opening polymerization of an alkylene oxide to an initiator using a phosphazene compound, a Lewis acid compound or an alkali metal compound catalyst; Polyol (B) is a polyether polyol having an average of from 2 to 3 hydroxyl groups and a hydroxyl value of from 70 to 250 mgKOH/g; and Monool (D) is a polyether monool having a hydroxyl value of from 10 to 200 mgKOH/g.
1. A process for producing a flexible polyurethane foam, which comprises reacting a polyol mixture with a polyisocyanate compound in the presence of an urethane-forming catalyst, a blowing agent and a foam stabilizer, characterized in that the polyol mixture comprises the following polyol (A), the following polyol (B) and the following monool (D), and the ratio of all active hydrogen-containing compounds in all materials other than the polyisocyanate compound to the polyisocyanate compound is at least 90 by isocyanate index, wherein:
Polyol (A) is a polyoxypropylene polyol having an average of from 2 to 3 hydroxyl groups, a hydroxyl value of from 10 to 60 mgKOH/g and is obtained by ring-opening polymerization of only propylene oxide to an initiator using a phosphazene compound, a Lewis acid compound or an alkali metal compound catalyst;
Polyol (B) is a polyoxypropylene polyol having an average of from 2 to 3 hydroxyl groups and a hydroxyl value of from 70 to 250 mgKOH/g and is obtained by ring-opening polymerization of only propylene oxide to an initiator; and
Monool (D) is a polyoxypropylene monool having a hydroxyl value of from 10 to 200 mgKOH/g and is obtained by ring-opening polymerization of only propylene oxide to an initiator, and
wherein from 50 to 100 mass % of the polyol (A) is a polyether diol having 2 hydroxyl groups,
wherein the monool (D) is present in an amount of 2-5 mass %, and
wherein the polyol (C) is present in the mixture in an amount up to 10 mass % of the following polyol (C), based on the entire polyol mixture:
Polyol (C) is a polyether polyol having an average of from 2 to 6 hydroxyl groups, a hydroxyl value of from 10 to 60 mgKOH/g and an oxyethylene group content of from 50 to 100 mass %.
2. The process for producing a flexible polyurethane foam according to claim 1 , wherein the proportion of the polyol (A) is from 5 to 50 mass %, based on the total of the polyol (A) and the polyol (B).
3. The process for producing a flexible polyurethane foam according to claim 1 , wherein the polyol mixture further contains at most 10 mass % of the following polyol (E), based on the entire polyol mixture:
Polyol (E) is a polyol having an average of from 2 to 6 hydroxyl groups and a hydroxyl value of from 300 to 1,830 mgKOH/g.
4. The process for producing a flexible polyurethane foam according to claim 1 , wherein the polyol (B) is a polyether polyol having an average of from 2 to 3 hydroxyl groups and a hydroxyl value of from 100 to 250 mgKOH/g.
5. The process for producing a flexible polyurethane foam according to claim 1 , wherein the flexible polyurethane foam formed by the reacting has an air flow of 70-100 L/min.
6. The process for producing a flexible polyurethane foam according to claim 1 , wherein the flexible polyurethane foam formed by the reacting has an air flow of 66.3-100 L/min.
7. The process for producing a flexible polyurethane foam according to claim 1 , wherein the flexible polyurethane foam formed by the reacting has an air flow of 40-100 L/min.
8. The process for producing a flexible polyurethane foam according to claim 1 , wherein Polyol (C) is present in an amount of at most 8 mass % based on 100 mass % of the polyol mixture.
9. The process for producing a flexible polyurethane foam according to claim 1 , wherein the oxyethylene group content of the flexible polyurethane foam is at most 4 mass % based on 100 mass % of the polyol mixture.
10. A process for producing a flexible polyurethane foam, comprising:
reacting a polyol mixture with a polyisocyanate compound in the presence of one or more urethane-forming catalysts, one or more blowing agents and one or more foam stabilizers,
wherein the polyol mixture comprises a polyol component that includes only a polyol (A), a polyol (B), a polyol (C) and a polyol (E), and a monool component that comprises a monool (D), and wherein the polyol component includes all of the polyols in the polyol mixture,
wherein the ratio of all active hydrogen-containing compounds in all materials other than the polyisocyanate compound to the polyisocyanate compound is at least 90 by isocyanate index,
wherein polyol (A) is a polyether polyol having an average of from 2 to 3 hydroxyl groups, a hydroxyl value of from 10 to 60 mgKOH/g and an oxyethylene group content of at most 30 mass %, obtained by ring-opening polymerization of an alkylene oxide to an initiator using a phosphazene compound, a Lewis acid compound or an alkali metal compound catalyst;
wherein polyol (B) is a polyether polyol having an average of from 2 to 3 hydroxyl groups and a hydroxyl value of from 70 to 250 mgKOH/g;
wherein polyol (C) is a polyether polyol having an average of from 2 to 6 hydroxyl groups, a hydroxyl value of from 10 to 60 mgKOH/g and an oxyethylene group content of from 50 to 100 mass %; and
polyol (E) is a polyol having an average of from 3 to 6 hydroxyl groups and a hydroxyl value of 300 to 1,830 mgKOH/g; and
monool (D) is a polyether monool having a hydroxyl value of from 10 to 200 mgKOH/g;
wherein the proportion of the polyol (A) is from 5 to 50 mass %, based on the total of the polyol (A) and the polyol (B).
11. The process for producing a flexible polyurethane foam according to claim 10 , wherein the proportion of the polyol (A) is from 5 to 50 mass %, based on the total of the polyol (A) and the polyol (B).
12. The process for producing a flexible polyurethane foam according to claim 10 , wherein the polyol mixture contains at most 10 mass % of the polyol (C) based on the entire polyol mixture.
13. The process for producing a flexible polyurethane foam according to claim 10 , wherein the monool (D) is a polyoxypropylene monool obtained by ring-opening polymerization of only propylene oxide to an initiator.
14. The process for producing a flexible polyurethane foam according to claim 10 , wherein the polyol mixture contains at most 10 mass % of the polyol (E) based on the entire polyol mixture.
15. The process for producing a flexible polyurethane foam according to claim 10 , wherein the polyol mixture comprises from 10 to 30 mass % of the polyol (A), from 50 to 80 mass % of the polyol (B), up to 8 mass % of the polyol (C), and up to 5 mass % of the polyol (E), based on 100 mass % of the polyol mixture.
16. The process for producing a flexible polyurethane foam according to claim 10 , wherein the amount of a triol in the polyol (B) contained in 100 mass % of the polyol mixture is at most 40 mass %.
17. The process for producing a flexible polyurethane foam according to claim 10 , wherein from 50 to 100 mass % of the polyol (A) is a polyether diol having 2 hydroxyl groups.
18. The process for producing a flexible polyurethane foam according to claim 10 , wherein the polyol (B) is a polyether polyol having an average of from 2 to 3 hydroxyl groups and a hydroxyl value of from 100 to 250 mgKOH/g.