Seamless steel tube for an airbag accumulator and process for its manufacture
View Patent ↗A seamless steel tube for an airbag accumulator which can be manufactured by heat treatment of normalizing without quenching and tempering and which has a tensile strength of at least 850 MPa and resistance to bursting at −20° C. has a stee; composition comprising, in mass %, C: 0.08-0.20%, Si: 0.1-1.0%, Mn: 0.6-2.0%, P: at most 0.025%, S: at most 0.010%, Cr: 0.05-1.0%, Mo: 0.05-1.0%, Al: 0.002-0.10%, at least one of Ca: 0.0003-0.01%, Mg: 0.0003-0.01%, and REM (rare earth metals): 0.0003-0.01%, at least one of Ti: 0.002-0.1% and Nb: 0.002-0.1%, with Ceq which is defined by the following Equation (1) being in the range of 0.45-0.63, with the metallurgical structure being a mixed structure of ferrite+bainite: Ceq=C+Si/24+Mn/6+(Cr+Mo)/5+(Ni+Cu)/15 (1) wherein the symbol for each element in Equation (1) indicates the number expressing the mass percent of the element.
1. A seamless steel tube for an airbag accumulator characterized by having a steel composition consisting essentially, in mass %, of C: 0.08-0.20%, Si: 0.1-1.0%, Mn: 0.6-1.6%, P: at most 0.025%, S: at most 0.010%, Cr: 0.05-0.8%, Mo: 0.05-1.0%, Al: 0.002-0.10%, at least one of Ca: 0.0003-0.01%, Mg: 0.0003-0.01%, and REM (rare earth metals): 0.0003-0.01%, at least one of Ti: 0.002-0.1% and Nb: 0.002-0.1%, with Ceq which is defined by the following Equation (1) being in the range of 0.45-0.63, and a remainder of Fe and impurities, with the metallurgical structure being a mixed structure of ferrite+bainite having an area fraction of bainite of at least 10%, and having a tensile strength of 850 MPa or more and a vTrs 100 value of −20° C. or less:
Ceq =C+Si/24+Mn/6+(Cr+Mo)/5+(Ni+Cu)/15 (1)
wherein the symbol for each element in Equation (1) indicates the number expressing the mass percent of the element.
2. A seamless steel tube for an airbag accumulator as set forth in claim 1 wherein a portion of Fe in the steel composition is replaced by one or more of Cu: 0.05-0.5% and Ni: 0.05-1.5%.
3. A process of manufacturing a seamless steel tube for an airbag accumulator comprising a step of forming a seamless steel tube having a steel composition as set forth in claim 1 or 2 and a step of subjecting the steel tube to finishing cold working so as to provide it with prescribed dimensions, characterized in that the process comprising a step of performing normalizing heat treatment on the steel tube prior to the finishing cold working step by heating the steel tube to a temperature in the range from the Ac 3 transformation point to 1,000° C. followed by air cooling.
4. A process of manufacturing a seamless steel tube for an airbag accumulator as set forth in claim 3 wherein the finishing cold working step is performed by cold drawing.
5. A process of manufacturing a seamless steel tube for an airbag accumulator as set forth in claim 3 which further comprises a step of performing stress relief annealing on the steel tube at a temperature of 450-650° C. after the finishing cold working step.
6. A process of manufacturing a seamless steel tube for an airbag accumulator as set forth in claim 3 which further comprises a step of performing rough working by cold working on the steel tube before the normalizing heat treatment step.
7. An airbag accumulator comprising a seamless steel tube having a steel composition consisting essentially, in mass %, of C: 0.08-0.20%, Si: 0.1-1.0%, Mn: 0.6-1.6%, P: at most 0.025%, S: at most 0.010%, Cr: 0.05-0.8%, Mo: 0.05-1.0%, Al: 0.002-0.10%, at least one of Ca: 0.0003-0.01%, Mg: 0.0003-0.01%, and REM (rare earth metals): 0.0003-0.01%, at least one of Ti: 0.002-0.1% and Nb: 0.002-0.1%, with Ceq which is defined by the following Equation (1) being in the range of 0.45-0.63, and a remainder of Fe and impurities, with the metallurgical structure being a mixed structure of ferrite+bainite having an area fraction of bainite of at least 10%, and having a tensile strength of 850 MPa or more and a vTrs100 value of −20° C. or less:
Ceq =C+Si/24+Mn/6+(Cr+Mo)/5+(Ni+Cu)/15 (1)
wherein the symbol for each element in Equation (1) indicates the number expressing the mass percent of the element.
8. An airbag accumulator as set forth in claim 7 wherein a portion of Fe in the steel composition of the seamless steel tube is replaced by one or more of Cu: 0.05-0.5% and Ni: 0.05-1.5%.