Environmentally-friendly polylactic acid resin composition
An environmentally-friendly polylactic acid resin composition includes (A) a mixed resin including (a1) a polylactic acid (PLA) resin and (a2) a polycarbonate resin, and (B) a compatibilizer capable of forming a stereo-complex with the polylactic acid resin. According to the present invention, the polylactic acid resin composition is environmentally-friendly and has excellent appearance and improved welding impact strength, as well as improved mechanical strength and heat resistance. Accordingly, it can be used for manufacturing various molded products requiring heat resistance and mechanical strength, for example electronic parts, office machines, miscellaneous goods, and the like.
1. An environmentally-friendly polylactic acid resin composition comprising:
(A) a mixed resin comprising (a1) about 25 to about 80 wt % of a polylactic acid (PLA) resin and (a2) about 20 to about 75 wt % of a polycarbonate resin; and
(B) a compatibilizer capable of forming a stereo-complex with the polylactic acid (PLA) resin, wherein the compatibilizer is a copolymer of a polylactic acid resin that is an optical isomer of the polylactic acid resin (a1) of the mixed resin (A) and polycarbonate, wherein the compatibilizer is included in an amount of about 2 to about 10 parts by weight based on 100 parts by weight of the mixed resin.
2. The environmentally-friendly polylactic acid resin composition of claim 1 , wherein the polylactic acid resin (a1) of the mixed resin (A) is an L-isomer and the compatibilizer comprises a copolymer of a D-isomeric polylactic acid resin and polycarbonate.
3. The environmentally-friendly polylactic acid resin composition of claim 1 , wherein the polylactic acid resin (a1) of the mixed resin (A) is a D-isomer and the compatibilizer comprises a copolymer of an L-isomeric polylactic acid resin and polycarbonate.
4. The environmentally-friendly polylactic acid resin composition of claim 1 , wherein the polylactic acid resin (a1) of the mixed resin (A) has a weight average molecular weight (Mw) of about 90,000 to about 500,000, and the polycarbonate resin (a2) of the mixed resin (A) has a weight average molecular weight (Mw) of about 10,000 to about 200,000.
5. The environmentally-friendly polylactic acid resin composition of claim 2 , wherein the D-isomeric polylactic acid resin of the compatibilizer has a weight average molecular weight (Mw) of about 1000 to about 200,000, and the polycarbonate resin of the compatibilizer has a weight average molecular weight (Mw) of about 1000 to about 100,000.
6. The environmentally-friendly polylactic acid resin composition of claim 1 , wherein the polycarbonate resin comprises a linear polycarbonate resin, a branched polycarbonate resin, a polyester carbonate copolymer, or a mixture thereof.
7. The environmentally-friendly polylactic acid resin composition of claim 1 , wherein the environmentally-friendly polylactic acid resin composition further comprises an impact modifier.
8. The environmentally-friendly polylactic acid resin composition of claim 7 , comprising the impact modifier in an amount of about 0.01 to about 20 parts by weight based on 100 parts by weight of the mixed resin.
9. The environmentally-friendly polylactic acid resin composition of claim 7 , wherein the impact modifier is a core-shell type copolymer, a chain-shaped modifier, or a combination thereof.
10. The environmentally-friendly polylactic acid resin composition of claim 1 , wherein the environmentally-friendly polylactic acid resin composition further comprises an antioxidant, a weather-resistance agent, a release agent, a colorant, an ultraviolet (UV) blocker, a filler, a nucleus-forming agent, a plasticizer, an auxiliary agent for adhesion, an adhesive, or a mixture thereof.
11. A molded product made using the environmentally-friendly polylactic acid resin composition of claim 1 .