Antistatic poly(hydroxyalkanoic acid) compositions
View Patent ↗Disclosed are toughened, antistatic resin composition and an article comprising the composition wherein the composition comprises or consists essentially of poly(hydroxyalkanoic acid), such as polylactic acid; an impact modifier comprising an ethylene copolymer; and an ion conducting polymer.
1. A composition comprising or produced from, based on the total weight of the composition, about 40 to about 94% of poly(hydroxyalkanoic acid), about 3 to about 30% of an impact modifier, and about 3 to about 30% of an ion conductive polymer wherein
the impact modifier is an ethylene copolymer derived from copolymerizing ethylene, carbon monoxide, and a comonomer selected from the group consisting of glycidyl (meth)acrylate, alkyl (meth)acrylate, vinyl ester, and combinations thereof; and
the ion conductive polymer is selected from the group consisting of polyamide/polyether block amide, polyether block amide, polyether ester amide, or combinations of two or more thereof, each comprising 10 to 5000 ppm, based on the weight of the ion conductive polymer of an alkali metal compound, alkaline earth metal compound, salt of the alkali metal compound, or salt of the alkali earth metal compound.
2. The composition of claim 1 wherein the poly(hydroxyalkanoic acid) is 6-hydroxyhexanoic acid, 3-hydroxyhexanoic acid, 4-hydroxyhexanoic acid 3-hydroxyheptanoic acid, or combinations of two or more thereof; and
the alkyl (meth)acrylate is selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, butyl acrylate, and butyl methacrylate, and combinations of two or more thereof.
3. The composition of claim 2 wherein the poly(hydroxyalkanoic acid) has five or fewer carbon atoms and the impact modifier is ethylene vinyl acetate carbon monoxide terpolymer, ethylene butyl acrylate carbon monoxide terpolymer, and combinations thereof.
4. The composition of claim 3 wherein the poly(hydroxyalkanoic acid) comprises glycolic acid, lactic acid, 3-hydroxypropionic acid, 2-hydroxybutyric acid, 3-hydroxybutyric acid, 4-hydroxybutyric acid, 3-hydroxyvaleric acid, 4-hydroxyvaleric acid, 5-hydroxyvaleric acid, or combinations of two or more thereof.
5. The composition of claim 4 wherein the poly(hydroxyalkanoic acid) comprises poly(glycolic acid, poly(lactic acid), polyhydroxy-butyric acid, polyhydroxybutyrate-hydroxyvalerate copolymer, copolymer of glycolic acid and lactic acid, or combinations of two or more thereof.
6. The composition of claim 5 wherein the poly(hydroxyalkanoic acid) is poly(lactic acid) and the impact modifier is the ethylene butyl acrylate carbon monoxide terpolymer.
7. The composition of claim 6 wherein the ion conducting polymer is the polyether ester amide.
8. The composition of claim 7 wherein the alkali metal compound or salt comprises sodium.
9. The composition of claim 8 wherein the impact modifier is present in about 10 to about 20 weight % and the ion conductive polymer is present in about 10 to about 20 weight %, of the composition.
10. The composition of claim 1 wherein the poly(hydroxyalkanoic acid) is poly(lactic acid); the ion conductive polymer comprises sodium; and the glycidyl (meth)acrylate present in the impact modifier is about 3 to about 25 weight % of the ethylene copolymer.
11. The composition of claim 10 wherein the impact modifier is ethylene butyl acrylate carbon monoxide terpolymer.
12. The composition of claim 8 wherein the alkyl (meth)acrylate present in the impact modifier is about 20 to about 35 weight %.
13. The composition of claim 12 wherein the glycidyl (meth)acrylate is glycidyl methacrylate and the alkyl (meth)acrylate is butyl acrylate.
14. The composition of claim 1 wherein the poly(hydroxyalkanoic acid) is poly(lactic acid); the ion conductive polymer comprises sodium; and the modifier is derived from ethylene, about 20 to about 35 wt % of the alkyl (meth)acrylate, and about 3 to about 20 wt % of the carbon monoxide.
15. The composition of claim 1 wherein the poly(hydroxyalkanoic acid) is poly(lactic acid); the ion conductive polymer comprises sodium; and the modifier is derived from ethylene, about 20 to about 35 weight % of the vinyl ester, and about 3 to about 20 wt % of the carbon monoxide.
16. An article comprising a composition wherein the article is a molded article, extruded article, thermoformed article, multilayer structure, or combination of two or more thereof and the composition is as recited in claim 1 .
17. The article of claim 16 wherein the poly(hydroxyalkanoic acid) is poly(lactic acid); the impact modifier is selected from the group consisting of ethylene butyl acrylate carbon monoxide terpolymer, and ethylene vinyl acetate carbon monoxide terpolymer.
18. The article of claim 16 wherein the ion conducting polymer is the polyether ester amide.
19. The article of claim 18 wherein the article is the multilayer structure comprising at least one layer of the composition and at least one other layer comprising one or more thermoplastic resins, non-thermoplastic substrates, or both.
20. The article of claim 19 wherein the article is a molded article, film, sheet, fiber, or filament.