Molded product and method for manufacturing same
View Patent ↗A molded product having a phase separation structure formed by photopolymerization of a photopolymerizable composition and imparting a sharp diffraction spot at a high diffraction efficiency, and a method for manufacturing same are provided. The molded product ( 1 ) comprises a matrix ( 2 ) and a multiple columnar structures ( 3 ) disposed within the matrix ( 2 ) and having an index of refraction different from the matrix ( 2 ), wherein the half width of a diffraction spot is 0.6° or less and diffraction efficiency is 10% or greater in an angular spectrum obtained by irradiation with a laser beam having an intensity distribution of standard normal distribution and a half width of the intensity distribution of 0.5°. The multiple columnar structures ( 3 ) are oriented in approximately the same direction, and are aligned in a regular lattice on a plane perpendicular to said orientation direction.
1. A method for manufacturing a molded product having a phase structure, comprising a matrix formed of a photopolymerizable composition, and multiple columnar structures disposed within said matrix and having an index of refraction different from said matrix, comprising:
a step for injecting the photopolymerizable composition containing a photopolymerizable monomer or oligomer and a photoinitiator into a mold;
a step for disposing a photomask having light-transmissive regions and a light non-transmissive region between the mold and a light source;
a first light irradiation step for irradiating parallel light from the light source with a wavelength full width at half maximum of 100 nm or less and an essentially uniform light intensity distribution through the photomask toward the photopolymerizable composition within the mold to polymerize those sites within the photopolymerizable composition which are irradiated with parallel light into an incompletely polymerized state; and
a second light irradiation step for irradiating parallel light with a wavelength full width at half maximum of 100 nm or less and an essentially uniform light intensity distribution toward the photopolymerizable composition within the mold after removing the photomask to complete the polymerization of the photopolymerizable composition,
wherein in the photomask, many of the light-transmissive regions are disposed in a regular lattice in the light non-transmissive region.
2. A method for manufacturing the molded product in claim 1 , whereby in the first light irradiation step, the photopolymerizable composition is polymerized to a polymerization degree of 10% or greater and 80% or less.