Method and apparatus for producing mono-lower-alkylmonoalkanolamine
View Patent ↗An amine producing apparatus includes a reactor that reacts a mono-lower-alkylamine and an alkylene oxide, an unreacted-raw-material-recovery distillation column that separates unreacted raw materials by distillation from a product including unreacted raw materials obtained in the reactor, a non-aqueous distillation column that removes water and a light component by a distillation method from a reactive product from which unreacted raw material have been separated, and a purification and distillation column that separates by distillation a desired reactive product (mono-lower-alkylmonoalkanolamine) and residue (mono-lower-alkyldialkanolamine which is a dimer) from a reactive product from which the water and the light component have been removed.
1. A method for producing a mono-lower-alkylmonoalkanolamine by a reaction of a mono-lower-alkylamine and an alkylene oxide, the method comprising the steps of:
feeding the mono-lower-alkylamine in excess with respect to the amount of the alkylene oxide in a reactor for selectively obtaining the mono-lower-alkylmonoalkanolamine;
separating unreacted raw material by distillation from a product including unreacted raw materials obtained in the reactor, in an unreacted-raw-material-recovery distillation column downstream of the reactor; and
returning the unreacted raw material separated from the unreacted-raw-material-recovery distillation column to the mono-lower-alkylamine raw material;
wherein, in each step
reaction temperature is in a range of from 50 to 250° C.,
reaction pressure is in a range of from 0.1 to 10 megapascals, and
water content is in a range of from 1 to 40 wt %.
2. The method for producing a mono-lower-alkylmonoalkanolamine according to claim 1 , wherein ratio of an alkylene oxide raw material to a mono-lower-alkylamine raw material (alkylene oxide raw material/mono-lower-alkylamine raw material) is in a range of from 0.05 to 0.35.