The invention provides for a cermet powder containing 75-90% by weight of at least one hard material powder, from 10 to 25% by weight of one or more matrix metal powders and up to 3% by weight of at least one modifier, wherein the matrix metal powder or powders contain from 0 to 38% by weight of cobalt, from 0 to 38% by weight of nickel, from 0 to 20% by weight of aluminum, from 0 to 90% by weight of iron and from 10 to 35% by weight of chromium and the sum of the contents of iron and chromium is in the range from 10 to 95% by weight and the sum of the contents of cobalt, nickel and iron is in the range from 65 to 95% by weight. The invention also relates to a cermet and a process to make the cermet containing the cermet powder and shaped article coated with the cermet powder and a process to make the shaped article.
1. An agglomerated and sintered cermet spraying powder having a particle size of from 10 to 100 μm comprising
75-90% by weight of at least one hard material powder having a particle size of less than 10 μm, from 10 to 25% by weight of one or more matrix metal powders having a particle size of less than 10 μm and
up to 3% by weight of at least one modifier,
wherein the matrix metal powder or powders contain
from 0 to 20% by weight of aluminum,
from 0 to 90% by weight of iron and
from 10 to 35% by weight of chromium
and
the sum of the contents of iron and chromium in the matrix powder or powders being at least 60% by weight and
wherein the powder is an agglomerated and sintered spray powder and
wherein the matrix powder or powders is/are cobalt- and nickel-free.
2. The agglomerated and sintered cermet spraying powder as claimed in claim 1 , which comprises
from 75-90% by weight of at least one hard material powder,
from 10 to 25% by weight of one or more matrix metal powders and
up to 3% by weight of modifiers,
wherein the matrix metal powder or powders contain
from 0 to 20% by weight of aluminum,
from 0 to 75% by weight of iron and
from 20 to 35% by weight of chromium
and
the sum of the contents of iron and chromium is in the range from 60 to 95% by weight.
3. The agglomerated and sintered cermet spraying powder as claimed in claim 1 , wherein the matrix metal powder contains from 0 to 75% by weight of iron.
4. The agglomerated and sintered cermet spraying powder as claimed in claim 1 , wherein the content of iron in the matrix powder or powders is at least 30% by weight.
5. The agglomerated and sintered cermet spraying powder as claimed in claim 1 , wherein the ratio of the sum of the contents of chromium and aluminum to the sum of the contents of iron and chromium in parts by weight is from 1:2.2 to 1:3.7.
6. The agglomerated and sintered cermet spraying powder as claimed in claim 1 , wherein the matrix powder has the composition: from 20 to 26% by weight of chromium, from 64 to 72% by weight of iron and from 5 to 16% by weight of aluminum.
7. The agglomerated and sintered cermet spraying powder as claimed in claim 1 , wherein the hard material powder is a powder selected from the group consisting of WC, Cr 3 C 2 , VC, Mo 2 C and mixtures thereof.
8. The agglomerated and sintered cermet spraying powder as claimed in claim 1 , wherein the modifier is selected from the group consisting of Mo, Nb, Si, W, Ta, V and mixtures thereof.
9. A process for coating a surface with comprises thermal spray coating the surface with the powder as claimed in claim 1 .
10. A process for producing a cermet which comprises providing the powder according to claim 1 in a form or preparation which is suitable for thermal spraying;
carrying out a thermal spraying process using this powder; and
obtaining the cermet.
11. A process for producing a shaped article which comprises providing the powder according to claim 1 in a form or preparation which is suitable for thermal spraying;
carrying out a thermal spraying process using this powder; and
obtaining the article.
12. A process for producing a cermet which comprises providing the powder according to claim 1 ;
shaping the powder under pressure to give a green body; and
heating the green body to give the cermet.
13. A cermet having the powder as claimed in claim 1 .
14. A shaped article which has a coating comprising the cermet as claimed in claim 13 .
15. A process for producing the article as claimed in claim 14 , which comprises the steps:
providing the powder according to claim 1 ;
shaping the powder under pressure to give a green body; and
heating the green body to give the article.
16. An agglomerated and sintered cermet spraying powder having a particle size of from 10 to 100 μm consisting essentially of
75-90% by weight of at least one hard material powder having a particle size of less than 10 μm, from 10 to 25% by weight of one or more matrix metal powders having a particle size of less than 10 μm and
up to 3% by weight of at least one modifier,
wherein the matrix metal powder or powders contain
from 0 to 20% by weight of aluminum,
from 0 to 90% by weight of iron and
from 10 to 35% by weight of chromium
and
the sum of the contents of iron and chromium in the matrix powder or powders being at least 60% by weight and
wherein the powder is an agglomerated and sintered spray powder and
wherein the matrix powder or powders is/are nickel and colbalt-free.