IP Library Granted Patent US 9,435,583
Granted Patent B2
US 9,435,583 · App. 12/442,042 · Granted Sep 6, 2016

Method and apparatus for liquefying a hydrocarbon stream

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,435,583
App. No.
12/442,042
Granted
Sep 6, 2016
Kind
B2
Abstract

A method and apparatus for liquefying a hydrocarbon stream such as natural gas from a feed stream. A feed stream is provided and passed through at least two cooling stages. Each cooling stage involves one or more heat exchangers. One of the heat exchangers involves a first refrigerant circuit having a first refrigerant stream, and a second of the heat exchangers involves a second refrigerant circuit having a second refrigerant stream. The liquefied hydrocarbon stream is expanded and a flash vapor is separated to provide a liquefied hydrocarbon product stream and a gaseous stream. The gaseous stream, at least a part of the first refrigerant stream, and at least a part of the second refrigerant stream are passed through a heat exchanger, for the gaseous stream to provide cooling to the first and second refrigerant streams.

Claims (29)

1. A method of liquefying a hydrocarbon stream from a feed stream, the method at least comprising the steps of:

(a) providing a feed stream;

(b) passing the feed stream through at least two cooling stages to provide a liquefied hydrocarbon stream, each cooling stage involving one or more heat exchangers, one of said heat exchangers involving a first refrigerant circuit having a first refrigerant stream of a first mixed refrigerant, and a second of said heat exchangers involving a second refrigerant circuit having a second refrigerant stream of a second mixed refrigerant;

(c) separating the first refrigerant stream into a first light refrigerant stream and a first heavy refrigerant stream, and separating the second refrigerant into a second light refrigerant stream and a second heavy refrigerant stream;

(d) expanding the liquefied hydrocarbon stream and separating flashed vapour from the liquefied hydrocarbon stream to provide a liquefied hydrocarbon product stream and a gaseous stream; and

(e) passing the gaseous stream, the first light refrigerant stream and the second light refrigerant stream through an end heat exchanger, for the gaseous stream to provide cooling to the first and second light refrigerant streams.

2. A method as claimed in claim 1 , wherein expanding the liquefied hydrocarbon stream, in step (d) comprises passing the liquefied hydrocarbon stream through one or more expansion stages.

3. A method as claimed in claim 1 , wherein the at least two cooling stages comprise a first cooling stage in the form of a pre-cooling stage followed by a second cooling stage in the form of a main cryogenic cooling stage.

4. A method as claimed in claim 3 , wherein the first cooling stage comprises two or more serial heat exchange steps.

5. A method as claimed in claim 3 , wherein the second cooling stage comprises two or more parallel heat exchange steps.

6. A method as claimed in claim 5 , wherein at least two of the heat exchangers of the second cooling stage involve separate refrigerant circuits, and at least part of the refrigerants of these separate refrigerant circuits provide the first and second light refrigerant streams of step (c).

7. A method as claimed in claim 5 , wherein the first cooling stage provides a pre-cooled hydrocarbon stream, which is divided between two or more part streams, and each part stream is separately liquefied in one or more cryogenic heat exchangers of the second cooling stage, each cryogenic heat exchanger providing a liquefied hydrocarbon part stream, which liquefied hydrocarbon part streams are combined to provide the liquefied hydrocarbon stream of step (b).

8. A method as claimed in claim 1 , wherein the mixed refrigerants of the first and second refrigerant circuits independently comprise two or more components selected from the group comprising nitrogen, methane, ethane, ethylene, propane, propylene, butane and pentane.

9. A method as claimed in claim 1 wherein the gaseous stream exits the end heat exchanger as a warmed gaseous stream, and further comprising a step (f) using the warmed gaseous stream exiting from the end heat exchanger as a fuel gas stream.

10. Apparatus for liquefying a hydrocarbon stream from a feed stream, the apparatus at least comprising:

two cooling stages to provide a liquefied hydrocarbon stream from the feed stream, each cooling stage involving one or more heat exchangers, one of said heat exchangers involving a first refrigerant circuit having a first refrigerant stream of first mixed refrigerant, and a second of said heat exchangers involving a second refrigerant circuit having a second refrigerant stream of a second mixed refrigerant;

a first separator in the first refrigerant circuit to separate the first mixed refrigerant stream into a first light refrigerant stream and a first heavy refrigerant stream and a second separator in the second refrigerant circuit to separate the second mixed refrigerant stream into a second light refrigerant stream and a second heavy refrigerant stream;

an end-flash system comprising a gas/liquid separator to receive the liquefied hydrocarbon stream and to provide a liquefied hydrocarbon product stream and a gaseous stream; and

an end heat exchanger arranged to receive the gaseous stream, the first light refrigerant stream and the second light refrigerant stream, and to allow the gaseous stream to provide cooling to the first and second light refrigerant streams.

11. The apparatus as claimed in claim 10 , wherein the end-flash system further comprises an expansion means.

12. A method as claimed in claim 2 , wherein the at least two cooling stages comprise a first cooling stage in the form of a pre-cooling stage followed by a second cooling stage in the form of a main cryogenic cooling stage.

13. A method as claimed in claim 12 , wherein the first cooling stage comprises two or more serial heat exchange steps.

14. A method as claimed in claim 4 , wherein the second cooling stage comprises two or more parallel heat exchange steps.

15. A method as claimed in claim 12 , wherein the second cooling stage comprises two or more parallel heat exchange steps.

16. A method as claimed in claim 13 , wherein the second cooling stage comprises two or more parallel heat exchange steps.

17. A method as claimed in claim 14 , wherein at least two of the heat exchangers of the second cooling stage involve separate refrigerant circuits, and at least part of the refrigerants of these separate refrigerant circuits provide the first and second light refrigerant streams of step (c).

18. A method as claimed in claim 15 , wherein at least two of the heat exchangers of the second cooling stage involve separate refrigerant circuits, and at least part of the refrigerants of these separate refrigerant circuits provide the first and second light refrigerant streams of step (c).

19. A method as claimed in claim 16 , wherein at least two of the heat exchangers of the second cooling stage involve separate refrigerant circuits, and at least part of the refrigerants of these separate refrigerant circuits provide the first and second light refrigerant streams of step (c).

20. A method as claimed in claim 6 , wherein the first cooling stage provides a pre-cooled hydrocarbon stream, which is divided between two or more part streams, and each part stream is separately liquefied in one or more cryogenic heat exchangers of the second cooling stage, each cryogenic heat exchanger providing a liquefied hydrocarbon part stream, which liquefied hydrocarbon part streams are combined to provide the liquefied hydrocarbon stream of step (b).

Assignments (2)
CHANGE OF NAME Recorded Mar 7, 2022
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 059694/0819 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 11, 2009
From: DAM, WILLEM; KONG, MING TECK; ZOETEMEIJER, LEENDERT JOHANNES ARIE
To: SHELL OIL COMPANY
Reel/Frame 022810/0980 →