Bulk light diffuser composition
View Patent ↗The present invention is a bulk light diffuser material based upon a hydrogenated block copolymer, but including a particulate light diffusing component. The material may be in the form of a film, a sheet or a molded article. When present as a sheet having a thickness of 2 millimeters, the sheet has a percent total transmittance of at least 50% and a haze of at least 70%, measured according to the American Society for Testing and Materials (ASTM) standard D 1003.
1. A bulk light diffuser material comprising from 80 percent by weight to 99.9 percent by weight of a rigid, substantially fully hydrogenated block copolymer and from 0.1 percent by weight to 20 percent by weight of light diffusing particles that have a refractive index that differs from that of the hydrogenated block copolymer matrix by greater than or equal to 0.02, each weight percentage being based upon total weight of hydrogenated block copolymer and light diffusing particles, the block copolymer constituting a continuous polymer phase and the light diffusing particles constituting a disperse phase within the continuous polymer phase, the block copolymer comprising at least two distinct blocks of hydrogenated vinyl aromatic polymer, and at least one block of hydrogenated conjugated diene polymer, whereby a two millimeter thick sheet comprising the bulk light diffuser material has a percent total transmittance of at least 50% and a percent haze (ASTM D-1003) of at least 70%.
2. The bulk light diffuser material of claim 1 , wherein the percent haze is less than or equal to 100 percent.
3. The bulk light diffuser material of claim 1 , wherein the substantially fully hydrogenated block copolymer comprises alternating styrenic polymer blocks and conjugated diene polymer blocks.
4. The bulk light diffuser material of claim 3 , wherein the substantially fully hydrogenated block copolymer is at least one of a hydrogenated styrene-isoprene-styrene block copolymer, a hydrogenated styrene-isoprene-styrene-isoprene block copolymer, a hydrogenated styrene-isoprene-styrene-isoprene-styrene block copolymer, a hydrogenated styrene-butadiene-styrene block copolymer, a hydrogenated styrene-butadiene-styrene-butadiene block copolymer, a hydrogenated styrene-butadiene-styrene-butadiene-styrene block copolymer, a hydrogenated styrene-butadiene-styrene-isoprene block copolymer and a hydrogenated styrene-butadiene-styrene-isoprene-styrene block copolymer.
5. A polymeric film comprising the bulk light diffuser material of claims 1 , the film having a thickness of less than 20 mils (0.5 millimeters).
6. A polymeric sheet comprising the bulk light diffuser material of claim 1 , the sheet having a thickness of at least 20 mils (0.5 millimeters).
7. The bulk light diffuser material of claim 1 , wherein the light diffusing particle is an inorganic material.
8. The bulk light diffuser material of claim 1 , wherein the light diffusing particle is a crosslinked polymeric particle.
9. The bulk light diffuser material of claim 1 , wherein the light diffusing particles have a refractive index that differs from that of the hydrogenated block copolymer matrix by greater than or equal to 0.03.
10. The bulk light diffuser material of claim 1 , wherein the light diffusing particles have an average particle size within a range of from 0.1 micrometer to 100 micrometers.
11. A backlight display device that comprises an optical source for generating light; an optional light guide for guiding the light therealong including a reflective surface for reflecting the light out of the light guide; and a film or sheet that comprises the bulk light diffuser material of claim 1 and is receptive to light either directly from the optical source or indirectly from the light guide.