Processes for producing 2,3,3,3-tetrafluoropropene, a process for producing 1-chloro-2,3,3,3-pentafluoropropane and azeotropic compositions of 1-chloro-2,3,3,3-tetrafluoropropene with HF
View Patent ↗A process is disclosed for making CH 2 ═CFCF 3 . The process involves contacting CH 2 ClCF 2 CF 3 with H 2 in a reaction zone in the presence of a catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina, to produce CH 2 ═CFCF 3 . The mole ratio of H 2 to the CH 2 ClCF 2 CF 3 fed to the reaction zone is between about 1:1 and about 4:1. Also disclosed is another process for making CH 2 ═CFCF 3 that involves (a) reacting CH 2 ClCF 2 CF 3 with H 2 in the presence of a catalytically effective amount of hydrogenation catalyst to form CH 3 CF 2 CF 3 ; and (b) dehydrofluorinating CH 3 CF 2 CF 3 from (a) to form CH 2 ═CFCF 3 ; and another process for making CH 2 ═CFCF 3 that involves (1) dehydrofluorinating CH 2 ClCF 2 CF 3 in the presence of a catalytically effective amount of dehydrofluorination catalyst to form CHCl═CFCF 3 ; and (2) hydrogenating CHCl═CFCF 3 from (1) in the presence of a hydrogenation catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina to form CH 2 ═CFCF 3 . Also disclosed is a process for making CH 2 ClCF 2 CF 5 . This process involves reacting CH 2 ClF with CF 2 ═CF 2 in a reaction zone in the presence of a catalytically effective amount of an aluminum halide composition having a bulk formula of AlCl x Br y F 3-x-y wherein the average value of x is 0 to 3, the average value of y is 0 to 3-x, provided that the average values of x and y are not both 0. Also disclosed is an azeotropic composition including CF 3 CF═CHCl and HF.
1. A process for making CH 2 ClCF 2 CF 3 , comprising:
reacting CH 2 ClF with CF 2 ═CF 2 in a reaction zone in the presence of a catalytically effective amount of an aluminum halide composition having a bulk formula of AlCl x Br y F 3-x-y wherein the average value of x is 0 to 3, the average value of y is 0 to 3-x, provided that the average values of x and y are not both 0.
2. A composition comprising:
(a) CF 3 CF═CHCl; and
(b) HF; wherein the HF is present in an effective amount to form an azeotropic combination with CF 3 CF═CHCl.
3. The azeotropic composition of claim 2 , comprising from about 22 to about 46 mole percent CF 3 CF═CHCl and HF.
4. The azeotropic composition of claim 2 , comprising from about 22 to about 46 mole percent CF 3 CF═CHCl and HF, wherein the vapor pressure is from about 4 psia to about 295 psi at a temperature of from about −25° C. to about 100° C.
5. The azeotropic composition of claim 2 , wherein said composition consists essentially of from about 22 to about 46 mole percent CF 3 CF═CHCl and HF, wherein the vapor pressure is from about 4 psia to about 25 psi at a temperature of from about −25° C. to about 100° C.
6. The process of claim 1 , x is from 0.1 to 3.0 and y is 0.
7. The process of claim 1 , wherein the mole ratio of CF 2 ═CF 2 to CH 2 CFCl is 1.5 or less.
8. The process of claim 7 , wherein the mole ratio of CF 2 ═CF 2 to CH 2 CFCl is from about 0.3:1 to about 1.1:1.