Method of regenerating used catalyst
View Patent ↗[Problem] Provided is a method for regenerating a catalyst, the method decreasing the SO 2 oxidation rate, which has been increased by Fe and V compounds, of a spent denitration catalyst to an extremely low level, and improves the oxidation activity of the catalyst for metal mercury by the regeneration treatment. [Solving Means] A method for regenerating a catalyst, including steps of immersing a spent denitration catalyst composed mainly of titanium oxide in (a) a mixed aqueous solution containing phosphate ions and oxo-acid ions of one or more elements selected from vanadium (V), molybdenum (Mo), and tungsten (W), (b) a heteropoly acid compound aqueous solution containing phosphorus and one or more elements selected from V, M, and W, or (c) a mixed aqueous solution containing a phosphate compound and a vanadyl compound, and then drying the catalyst.
1. A method for regenerating a catalyst, consisting of the steps of:
impregnating a spent denitration catalyst composed mainly of titanium oxide and contaminated by iron compounds with a phosphoric acid aqueous solution so as to react the iron compounds on the catalyst with the phosphoric acid to form an iron phosphate and allow on-site regeneration of the catalyst without requiring any cleaning operation of the catalyst, and
then drying the catalyst.
2. The method for regenerating a catalyst according to claim 1 , wherein the concentration of the phosphate ion in the phosphate ion-containing aqueous solution is 5% by weight or more based on the weight of the aqueous solution.
3. The method for regenerating a catalyst according to claim 1 , wherein the phosphate ion-containing aqueous solution is a phosphoric acid aqueous solution.
4. A method for regenerating a catalyst, consisting of the steps of:
impregnating a spent denitration catalyst composed mainly of titanium oxide and contaminated by iron compounds in
(a) a mixed aqueous solution containing phosphoric acid and oxo-acid ions of one or more elements selected from vanadium (V), molybdenum (Mo), and tungsten (W), or
(b) a heteropoly acid compound aqueous solution containing phosphorus and one or more elements selected from V, Mo, and W, or
(c) a mixed aqueous solution containing a phosphoric acid and a vanadyl compound so as to react the iron compounds on the catalyst with the phosphoric acid to form an iron phosphate and allow on-site regeneration of the catalyst without requiring any cleaning operation of the catalyst, and
then drying the catalyst.
5. The method for regenerating a catalyst according to claim 4 , wherein the catalyst is impregnated in the mixed aqueous solution (a); and wherein the mixed aqueous solution (a) contains phosphoric acid or its ammonium salt and a compound expressed by a rational formula (NH 4 ) 3 Mo 2 V 3 O 15 .
6. The method for regenerating a catalyst according to claim 4 , wherein the catalyst comprises V 2 O 5 ; and wherein the phosphate ion carried by the catalyst is from about 1 to about 8% by weight based on the weight of V 2 O 5 in the catalyst.
7. The method for regenerating a catalyst according to claim 4 , wherein the catalyst is impregnated with the mixed aqueous solution (c); and wherein the mixed aqueous solution (c) contains phosphoric acid and vanadyl sulfate.