Magnetic recording medium with controlled grain diameters
View Patent ↗In order to provide a magnetic recording medium having excellent electromagnetic conversion characteristics, a magnetic recording medium ( 10 ) is provided with a substrate ( 12 ), and a magnetic recording layer ( 20 ) formed on the substrate ( 12 ). The magnetic recording layer ( 20 ) is provided with a granular layer ( 32 ), i.e., a magnetic layer, including magnetic grains and a nonmagnetic material surrounding the magnetic grains in a section parallel to the main surface of the substrate. The ratio of the long diameter to the short diameter of each magnetic grain contained in the granular layer ( 32 ) is calculated in the section. In the histogram of such ratio, a half width at half maximum of the histogram is 0.6 or less and the variance of grain diameters of the magnetic grains in the section is 20% or less of the average grain diameter of the magnetic grains.
1. A magnetic recording medium comprising a substrate and a perpendicular magnetic recording layer formed over said substrate, wherein in said magnetic recording medium:
said perpendicular magnetic recording layer comprises a magnetic layer containing magnetic grains and a nonmagnetic substance surrounding said magnetic grains in a section parallel to a main surface of said substrate,
said magnetic layer is configured such that when, in said section, a ratio between a long diameter and a short diameter of each of said magnetic grains contained in said magnetic layer is calculated to derive a histogram of said ratios, a half width at half maximum of said histogram is 0.1 to 0.6,
a variance of grain diameters of said magnetic grains in said section is 5 to 20% of an average grain diameter of said magnetic grains, and
said nonmagnetic substance has a density of 4.0 g/cm 3 or more.
2. A magnetic recording medium according to claim 1 , wherein the average grain diameter of said magnetic grains in said section is 3 to 8 nm.
3. A magnetic recording medium according to claim 1 , wherein said magnetic recording layer contains said magnetic grains at the rate of 100 to 150 grains per region of 100 nm×100 nm in said section.
4. A magnetic recording medium according to claim 1 , wherein a width of a region occupied by said nonmagnetic substance between said magnetic grains is 0.8 to 1.3 nm.
5. A magnetic recording medium according to claim 1 , wherein:
said perpendicular magnetic recording layer further comprises a first magnetic layer which forms said magnetic layer containing said magnetic grains and said nonmagnetic substance surrounding said magnetic grains and a second magnetic layer containing magnetic grains with grain boundaries each having a width of less than 0.8 nm.
6. A magnetic recording medium according to claim 1 , wherein the nonmagnetic substance is selected from the group consisting of ZnO, BaO, Bi 2 O 3 , Cr 3 O 4 , CuO, HfO 2 , MoO 2 , NbO 2 , ReO 2 , RuO 2 , Ta 2 O 5 , and WO 2 .
7. A magnetic recording medium according to claim 1 , wherein the variance of grain diameters of said magnetic grains in said section is 7 to 15% of an average grain diameter of said magnetic grains.
8. A magnetic recording medium according to claim 1 , wherein the half width at half maximum of said histogram is 0.2 to 0.5.
9. A magnetic recording medium according to claim 1 , wherein the half width at half maximum of said histogram is 0.3 to 0.4.