Low migration polyolefin composition
View Patent ↗The present invention relates to a composition comprising: a) a polyolefin (A); b) a compound (B) according to formula (I), wherein R and R′ each is the same or different residue and comprising at least 6 C-atoms; c) a phenolic compound (C), having the formula (II) wherein R is an non-substituted or substituted aliphatic or aromatic hydrocarbyl radical which may comprise heteroatoms, or R is an heteroatom; X is H, OH, and/or R′; whereby R′ is a hydrocarbyl radical or hydrogen, and n is 1 to 4; and d) optionally, an UV-light stabilizer (D), wherein for the composition the total amount of migrated compounds (B), (C) and, if present, (D), as well as their decomposition products is equal to or less than 1.8 microgram per liter with a ratio S/V dm −1 of 11.70 to 12.30, to the use of said composition for the production of a pipe and to a pipe comprising said composition.
1. A method for the production of a pipe, comprising forming a drinking water supply system pipe from a composition comprising:
a) a polyolefin (A);
b) a compound (B) which is Bis (2,4-dicumylphenyl)pentaerythritol-di-phosphite;
c) a phenolic compound (C), having the formula (II)
wherein R is an non-substituted or substituted aliphatic or aromatic hydrocarbyl radical which may comprise heteroatoms, or R is an heteroatom; X 1 to X 5 each is H, OH, and/or R′, wherein at least one of which is OH; wherein R′ is a hydrocarbyl radical or hydrogen, and n is 1 to 4; and
d) optionally, an UV-light stabilizer (D),
wherein for the composition a total amount of migrated compounds (B), (C) and, if present, (D), as well as their decomposition products is equal to or less than 1.8 microgram per liter with a ratio S/V dm −1 of 11.70 to 12.30.
2. The method according to claim 1 , wherein the UV-light stabilizer (D) comprises a sterically hindered amine.
3. The method according to claim 2 , wherein the sterically hindered amine comprises one or more groups of the following formula
wherein G′ and G″ are the same or different alkyl residues, Z′ and Z″ are the same or different alkyl residues, or Z′ and Z″ together form a linking moiety which may additionally be substituted by an ester, ether, amide, amino, carboxy or urethane group, E is an oxyl, hydroxyl, alkoxy, cycloalkoxy, aryloxy or alkyl residue or hydrogen.
4. The method according to claim 1 , wherein the phenolic compound (C) has the formula (II a)
wherein R is a non-substituted or substituted aliphatic or aromatic hydrocarbyl radical which may comprise heteroatoms, or R is a heteroatom; R′ is a hydrocarbyl radical or hydrogen, R″ is a hydrocarbyl radical or hydrogen, X 1 , X 2 and X 3 is the same or different H or OH, wherein at least X 1 , X 2 or X 3 is OH, and n is 1 to 4.
5. The method according to claim 1 , wherein the amount of compound (B) is equal to or less than 0.2 wt %, based on the total composition.
6. The method according to claim 1 , wherein the amount of the phenolic compound (C) is 0.05 wt % or more, based on the total composition.
7. The method according to claim 1 , wherein the UV-light stabilizer is used in an amount of 0.01 to 1.0 wt %, based on the total composition.
8. The method according to claim 1 , wherein the composition further comprises carbon black.
9. The method according to claim 1 , wherein the polyolefin is an ethylene homo- or copolymer or a propylene homo- or copolymer or a mixture thereof.