Process and apparatus for the production of yarn
View Patent ↗The present invention concerns a process and apparatus for spinning polymer filaments comprising extruding a polymer solution to form one or more filaments into an air gap above a coagulation liquid, where the filaments are subject to strain; forming a downward stream of liquid and filaments by contacting the polymer solution with a coagulation liquid; passing the filaments and liquid through a quench tube; contacting the liquid with a surface such that the downward force of gravity on the liquid does not increase the strain of the filaments in the air gap; and separating the liquid from the filaments.
1. A process for spinning polymer filaments comprising:
a) extruding a polymer solution to form one or more dope filaments into an air gap above a liquid coagulation bath having a quench tube and containing a coagulation liquid, where the dope filaments are subject to strain;
b) introducing the dope filaments into the liquid coagulation bath;
c) forming a downward stream of liquid and coagulated filaments;
through the quench tube;
d) contacting the liquid with a surface after the exit of the quench tube and prior to separating the liquid from the coagulated filaments, such that the downward force of gravity on the liquid does not increase the strain on the dope filaments in the air gap, and wherein the coagulated filaments are coupled with the liquid in contact with the surface to increase fluid exchange; and
e) separating the liquid from the coagulated filaments.
2. A process for spinning polymer filaments comprising:
a) extruding a polymer solution into dope filaments in an air gap between a spinneret and a liquid coagulation bath having a quench tube and containing a coagulating liquid, the dope filaments having a certain strain in the air gap imparted by one or more pull rolls,
b) introducing the dope filaments into the liquid coagulation bath;
c) forming a downward stream of liquid and coagulated filaments through the quench tube,
d) contacting the liquid with a surface after the exit of the quench tube and prior to separating the liquid from the filaments, such that the downward force of gravity on the liquid does not increase the strain on the dope filaments in the air gap, and wherein the coagulated filaments are coupled with the liquid in contact with the surface to increase fluid exchange;
e) separating the liquid from the coagulated filaments, and
f) forwarding the coagulated filaments by the use of one or more pull roll.
3. The process of claim 2 , wherein the surface comprises a plate.
4. The process of claim 2 , wherein the surface comprises a plurality of plates.
5. The process of claim 3 , wherein the surface comprises two parallel plates.
6. The process of claim 3 , wherein the plate is formed into a structure comprising a least one curved surface.
7. The process of claim 3 , wherein the plate is curved.
8. The process of claim 2 , further comprising collecting the coagulated filaments.
9. The process of claim 8 , wherein the coagulated filaments are collected by winding the filaments on a tube.
10. The process of claim 9 , wherein the coagulated filaments are wound at a speed of at least 500 meters per minute.
11. The process of claim 9 , wherein the coagulated filaments are wound at a speed of at least 800 meters per minute.
12. The process of claim 2 wherein the polymer comprises an aramid.
13. The process of claim 12 , wherein the aramid is para-aramid.
14. The process of claim 13 , wherein the aramid is poly(p-phenylene terephthalamide).
15. The process of claim 2 , wherein the polymer comprises a polyareneazole.
16. The process of claim 15 , wherein the polyareneazole is polybenzoxazole or polybenzothiazole.
17. The process of claim 2 , wherein the polymer comprises poly{2,6-diimidazo[4,5-b4′,5′-e]pyridinylene-1,4(2,5-dihydroxy)phenylene}.