Curable composition
View Patent ↗Disclosed is a curable composition which can be cured quickly by light. This curable composition is not left uncured even in portions which are not irradiated with light. A cured product of this curable composition is excellent in heat resistance, oil resistance and weather resistance. Specifically disclosed is a curable composition characterized by containing a vinyl polymer having at least one crosslinkable silyl group on average and a vinyl polymer having at least one photocrosslinkable group on average.
1. A curable composition comprising a vinyl polymer (I) having at least one crosslinkable functional group on average represented by the following general formula (1):
—[Si(R 1 ) 2-b (Y) b O] m —Si(R 2 ) 3-a (Y) a (1)
wherein, R 1 and R 2 are the same or different, and represent an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, or a triorganosiloxy group represented by (R′) 3 SiO—, wherein R′ represents a monovalent hydrocarbon group having 1 to 20 carbon atoms; R′ present in multiple number may be the same or different, and when R 1 or R 2 is each present in the number of 2 or more, R 1 and R 2 may be the same or different; Y represents a hydroxyl group or a hydrolyzable group, and when Y is present in the number of two or more, Y may be the same or different; a represents 0, 1, 2 or 3; b represents 0, 1, or 2; and m represents an integer of 0 to 19; and wherein, the relational expression of a+mb≧1 is satisfied,
a vinyl polymer (II) having at least one crosslinkable functional group on average represented by the following general formula (2):
—OC(O)C(R a )═CH 2 (2)
wherein, R a represents a hydrogen atom or an organic group having 1 to 20 carbon atoms, and
a photopolymerization initiator (III).
2. The curable composition according to claim 1 wherein the vinyl polymer (II) is produced by allowing a vinyl polymer having a halogen group at the end to react with a compound represented by the general formula (3):
M +− OC(O)C(R a )═CH 2 (3)
wherein, R a represents a hydrogen atom or an organic group having 1 to 20 carbon atoms; and M + represents an alkali metal ion or a quaternary ammonium ion.
3. The curable composition according to claim 2 wherein the vinyl polymer having a halogen group at the end has a group represented by the general formula (4):
—CR 3 R 4 X (4)
wherein, R 3 and R 4 represent a group bound to an ethylenic unsaturated group of the vinyl monomer; and X represents a chlorine atom, a bromine atom or an iodine atom.
4. The curable composition according to claim 1 wherein the vinyl polymer (I) and/or the vinyl polymer (II) have a molecular weight distribution of less than 1.8.
5. The curable composition according to claim 1 wherein the main chain of the vinyl polymer (I) and/or the vinyl polymer (II) is produced by polymerizing mainly a monomer selected from the group consisting of a (meth)acrylic monomer, an acrylonitrile monomer, an aromatic vinyl monomer, a fluorine-containing vinyl monomer and a silicon-containing vinyl monomer.
6. The curable composition according to claim 1 wherein the main chain of the vinyl polymer (I) and/or the vinyl polymer (II) is a (meth)acrylic polymer.
7. The curable composition according to claim 1 wherein the main chain of the vinyl polymer (I) and/or the vinyl polymer (II) is an acrylic polymer.
8. The curable composition according to claim 1 wherein the main chain of the vinyl polymer (I) and/or the vinyl polymer (II) is an acrylate ester polymer.
9. The curable composition according to claim 1 wherein the main chain of the vinyl polymer (I) and/or the vinyl polymer (II) is produced by a living radical polymerization process.
10. The curable composition according to claim 1 wherein the main chain of the vinyl polymer (I) and/or the vinyl polymer (II) is produced by an atom transfer radical polymerization process.
11. The curable composition according to claim 1 wherein the vinyl polymer (I) and/or the vinyl polymer (II) have at least one of the crosslinkable functional groups in the molecular chain at the end.
12. The curable composition according to claim 1 wherein the amount of the vinyl polymer (II) blended is no less than 20% and no greater than 80% of the total amount of the vinyl polymer (I) and the vinyl polymer (II) by weight ratio.
13. The curable composition according to claim 1 further comprising a polyether polymer (IV).
14. The curable composition according to claim 13 wherein the main chain of the polyether polymer (IV) is substantially polypropylene oxide.
15. The curable composition according to claim 13 wherein the polyether polymer (IV) has at least one crosslinkable silyl group on average.
16. The curable composition according to claim 1 further comprising a vinyl polymer (V) having a number average molecular weight of no greater than 5,000.
17. The curable composition according to claim 16 wherein the vinyl polymer (V) has a molecular weight distribution of less than 1.8.