Benzoylpyrazoles and herbicide
View Patent ↗Benzoylpyrazoles represented by the following formula (I), and use thereof as herbicides. R 1 represents alkyl; R 2 represents alkyl or cycloalkyl; R 3 represents hydrogen, alkyl, alkenyl, alkynyl, aralkyl, alkylsulfonyl, optionally substituted phenylsulfonyl, acyl or acylalkyl; X represents halogen or alkyl; Y represents halogen; n represents 2 or 3, and T represents the above group T1 or T2, wherein R 4 represents hydrogen, alkyl, alkoxy or alkylthio.
1. Benzoylpyrazoles represented by the formula (I):
wherein
R 1 represents alkyl;
R 2 represents alkyl or cycloalkyl;
R 3 represents hydrogen, alkyl, alkenyl, alkynyl, aralkyl, alkylsulfonyl, optionally substituted phenylsulfonyl, acyl or acylalkyl;
X represents halogen or alkyl;
Y represents halogen;
n represents 2 or 3, and
T represents a group T1:
or a group T2:
wherein R 4 represents hydrogen, alkyl, alkoxy or alkylthio.
2. The compound according to claim 1 , wherein
R 1 represents C 1-6 alkyl;
R 2 represents C 1-6 alkyl or C 3-7 -cycloalkyl;
R 3 represents hydrogen, C 1-6 alkyl, C 3-7 alkenyl, C 3-7 alkynyl, C 7-12 aralkyl, C 1-6 alkylsulfonyl, optionally C 1-6 alkyl-substituted phenylsulfonyl, C 1-6 alkylcarbonyl, benzoyl or benzoyl-C 1-6 alkyl;
X represents halogen or C 1-6 alkyl;
Y represents halogen;
n represents 2 or 3; and
T represents a group T1:
or a group T2:
wherein R 4 represents hydrogen, C 1-6 alkyl, C 1-6 alkoxy or C 1-6 alkylthio.
3. The compound according to claim 1 , wherein
R 1 represents methyl or ethyl;
R 2 represents methyl, ethyl or cyclopropyl;
R 3 represents hydrogen, methyl, allyl, propargyl, benzyl, methanesulfonyl, n-propanesulfonyl, optionally methyl-substituted phenylsulfonyl, acyl, benzoyl or phenacyl;
X represents chlorine, bromine or methyl;
Y represents chlorine or bromine;
n represents 2 or 3; and
T represents a group T1:
or a group T2:
wherein R 4 represents hydrogen, methyl, ethyl, methoxy or methylthio.
4. A herbicide comprising, as an effective ingredient, the compound according to claim 1 .
5. The compound represented by the formula (II):
Wherein
X represents halogen or alkyl;
Y represents halogen;
n represents 2 or 3, and
T represents a group T1:
or a group T2:
wherein R 4 represents hydrogen, alkyl, alkoxy or alkylthio, and Z represents a group:
Wherein R 1 represents alkyl;
R 2 represents alkyl or cycloalkyl.
6. A herbicide comprising, as an effective ingredient, the compound according to claim 2 .
7. A herbicide comprising, as an effective ingredient, the compound according to claim 3 .
8. A method for preparing a compound of claim 1 , comprising using a compound of formula II
wherein
X represents halogen or alkyl;
Y represents halogen;
n represents 2 or 3, and
T represents a group T1:
or a group T2:
wherein R 4 represents hydrogen, alkyl, alkoxy or alkylthio and Z represents a group:
wherein
R 1 represents alkyl;
R 2 represents alkyl or cycloalkyl, as an intermediate in said method.