IP Library Granted Patent US 8,084,398
Granted Patent B2
US 8,084,398 · App. 12/444,554 · Granted Dec 27, 2011

Benzoylpyrazoles and herbicide

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Quick Facts
Patent No.
US 8,084,398
App. No.
12/444,554
Granted
Dec 27, 2011
Kind
B2
Abstract

Benzoylpyrazoles represented by the following formula (I), and use thereof as herbicides. R 1 represents alkyl; R 2 represents alkyl or cycloalkyl; R 3 represents hydrogen, alkyl, alkenyl, alkynyl, aralkyl, alkylsulfonyl, optionally substituted phenylsulfonyl, acyl or acylalkyl; X represents halogen or alkyl; Y represents halogen; n represents 2 or 3, and T represents the above group T1 or T2, wherein R 4 represents hydrogen, alkyl, alkoxy or alkylthio.

Claims (55)

1. Benzoylpyrazoles represented by the formula (I):

wherein

R 1 represents alkyl;

R 2 represents alkyl or cycloalkyl;

R 3 represents hydrogen, alkyl, alkenyl, alkynyl, aralkyl, alkylsulfonyl, optionally substituted phenylsulfonyl, acyl or acylalkyl;

X represents halogen or alkyl;

Y represents halogen;

n represents 2 or 3, and

T represents a group T1:

or a group T2:

wherein R 4 represents hydrogen, alkyl, alkoxy or alkylthio.

2. The compound according to claim 1 , wherein

R 1 represents C 1-6 alkyl;

R 2 represents C 1-6 alkyl or C 3-7 -cycloalkyl;

R 3 represents hydrogen, C 1-6 alkyl, C 3-7 alkenyl, C 3-7 alkynyl, C 7-12 aralkyl, C 1-6 alkylsulfonyl, optionally C 1-6 alkyl-substituted phenylsulfonyl, C 1-6 alkylcarbonyl, benzoyl or benzoyl-C 1-6 alkyl;

X represents halogen or C 1-6 alkyl;

Y represents halogen;

n represents 2 or 3; and

T represents a group T1:

or a group T2:

wherein R 4 represents hydrogen, C 1-6 alkyl, C 1-6 alkoxy or C 1-6 alkylthio.

3. The compound according to claim 1 , wherein

R 1 represents methyl or ethyl;

R 2 represents methyl, ethyl or cyclopropyl;

R 3 represents hydrogen, methyl, allyl, propargyl, benzyl, methanesulfonyl, n-propanesulfonyl, optionally methyl-substituted phenylsulfonyl, acyl, benzoyl or phenacyl;

X represents chlorine, bromine or methyl;

Y represents chlorine or bromine;

n represents 2 or 3; and

T represents a group T1:

or a group T2:

wherein R 4 represents hydrogen, methyl, ethyl, methoxy or methylthio.

4. A herbicide comprising, as an effective ingredient, the compound according to claim 1 .

5. The compound represented by the formula (II):

Wherein

X represents halogen or alkyl;

Y represents halogen;

n represents 2 or 3, and

T represents a group T1:

or a group T2:

wherein R 4 represents hydrogen, alkyl, alkoxy or alkylthio, and Z represents a group:

Wherein R 1 represents alkyl;

R 2 represents alkyl or cycloalkyl.

6. A herbicide comprising, as an effective ingredient, the compound according to claim 2 .

7. A herbicide comprising, as an effective ingredient, the compound according to claim 3 .

8. A method for preparing a compound of claim 1 , comprising using a compound of formula II

wherein

X represents halogen or alkyl;

Y represents halogen;

n represents 2 or 3, and

T represents a group T1:

or a group T2:

wherein R 4 represents hydrogen, alkyl, alkoxy or alkylthio and Z represents a group:

wherein

R 1 represents alkyl;

R 2 represents alkyl or cycloalkyl, as an intermediate in said method.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE ADDRESS PREVIOUSLY RECORDED AT REEL: 034891 FRAME: 0140. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Feb 19, 2015
From: BAYER CROPSCIENCE AG
To: BAYER INTELLECTUAL PROPERTY GMBH
Reel/Frame 035046/0921 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2015
From: BAYER CROPSCIENCE AG
To: BAYER INTELLECTUAL PROPERTY GMBH
Reel/Frame 034891/0140 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 30, 2009
From: NARABU, SHINICHI; YONETA, YASUSHI; YANAGI, AKIHIKO; SHIRAKURA, SHINICHI; UKAWA, SEIJI; ICHIHARA, TERUYUKI; NAKAMURA, SHIN; HILLS, MARTIN; KEHNE, HEINZ; DITTGEN, JAN; FEUCHT, DIETER; ROSINGER, CHRISTOPHER
To: BAYER CROPSCIENCE AG-F
Reel/Frame 023027/0041 →