Rubber composition for vulcanization
View Patent ↗The present invention provides a vulcanized rubber material having improved heat resistance while maintaining ozone resistance of an epihalohydrin rubber, and a rubber composition for vulcanization for producing the same. The invention further provides a vulcanized rubber material and a rubber composition for vulcanization, that can achieve the above objects without using an organonickel compound having a concern about toxicity, or if used, using the same as less as possible. The present invention relates to a rubber composition for vulcanization comprising (a) 100 parts by weight of an epihalohydrin rubber, (b) 0.01 to 0.5 part by weight of a copper salt of dithiocarbamic acid, (c) an acid acceptor, and (d) a polythiol type vulcanizing agent or a polyol type vulcanizing agent, a vulcanized rubber material obtained by vulcanizing the composition, and an automotive rubber part comprising the vulcanized rubber material.
1. A rubber composition for vulcanization comprising (a) 100 parts by weight of an epihalohydrin rubber as a rubber component, (b) 0.01 to 0.5 part by weight of a copper salt of dithiocarbamic acid, (c) an acid acceptor, (d) a quinoxaline type vulcanizing agent, and (g) a vulcanization accelerator being either alkali metal salts of fatty acid or 1,8-diazabicyclo(5,4,0)undecene-7 salts.
2. The rubber composition for vulcanization as claimed in claim 1 , wherein the quinoxaline type vulcanizing agent (d) is 6-methylquinoxaline-2,3-thiocarbonate.
3. The rubber composition for vulcanization as claimed in claim 1 , further comprising a benzimidazole type antioxidant (e).
4. The rubber composition for vulcanization as claimed in claim 1 , further comprising a hindered amine light stabilizer (f).
5. The rubber composition for vulcanization as claimed in claim 1 , wherein an adding amount of the copper salt of dithiocarbamic acid (b) is from 0.01 to 0.3 part by weight per 100 parts by weight of the epihalohydrin rubber (a).
6. The rubber composition for vulcanization as claimed in claim 5 , wherein the adding amount of the copper salt of dithiocarbamic acid (b) is from 0.05 to 0.1 part by weight per 100 parts by weight of the epihalohydrin rubber (a).
7. The rubber composition for vulcanization as claimed in claim 1 , wherein the acid acceptor (c) is sodium carbonate.
8. The rubber composition for vulcanization as claimed in claim 1 , wherein the acid acceptor is a metal compound and/or inorganic microporous crystal.
9. The rubber composition for vulcanization as claimed in claim 1 , wherein the acid acceptor (c) is inorganic microporous crystal selected from the group consisting of synthetic hydrotalcite, Li—Al clathrate compound and synthetic zeolite, or a mixture of the inorganic microporous crystal and a metal compound.
10. The rubber composition for vulcanization as claimed in claim 9 , wherein the acid acceptor (c) is synthetic hydrotalcite or a mixture of synthetic hydrotalcite and a metal compound.
11. The rubber composition for vulcanization as claimed in claim 1 , wherein the vulcanization accelerator (g) is a sodium salt of fatty acid and/or a potassium salt of fatty acid, and the acid acceptor (c) is inorganic microporous crystal selected from the group consisting of synthetic hydrotalcite, Li—Al clathrate compound and synthetic zeolite.
12. The rubber composition for vulcanization as claimed in claim 11 , wherein the vulcanization accelerator (g) is a sodium salt of fatty acid and/or a potassium salt of fatty acid, and the acid acceptor (c) is synthetic hydrotalcite.
13. The rubber composition for vulcanization as claimed in claim 1 , wherein the epihalohydrin rubber (a) is an epichlorohydrin homopolymer or a blend of an epichlorohydrin homopolymer and other epihalohydrin rubber, and the blend contains the epichlorohydrin homopolymer in an amount of 70 parts by weight or more.
14. The rubber composition for vulcanization as claimed in claim 1 , which does not contain a nickel compound.
15. A vulcanizate obtained by vulcanizing the rubber composition for vulcanization as claimed in claim 1 .
16. An automotive rubber part comprising the vulcanizate as claimed in claim 15 .
17. The rubber composition for vulcanization as claimed in claim 1 , wherein the vulcanization accelerator (g) is 1,8-diazabicyclo(5,4,0)undecene-7 salts.