Articles comprising nonpolar polyolefin and polyurethane, and methods for their preparation and use
View Patent ↗The adhesion between a low surface energy (i.e., nonpolar) material, e.g., a polyolefin such as polyethylene, and a high surface energy (i.e., polar) material, e.g., a polyester, polyurethane, polycarbonate or polylactic acid, is promoted by blending with the nonpolar material typically from 15 to less than 50 wt % of a diol-based thermoplastic polyurethane (d-TPU), e.g., a polydiene diol-based TPU, based on the combined weight of the nonpolar material and the d-TPU. The promoted adhesion allows for the effective painting, printing, over-molding or HF-welding of a nonpolar substrate, e.g., a polyolefin film, with a polar coating, e.g., a paint, ink, etc. Aqueous dispersions can also be made from the blend of nonpolar material and d-TPU.
1. An article comprising a first structural component and a second structural component, the first structural component comprising a polar material and the second structural component comprising a blend of 55 to 77 weight percent (wt %) homogeneously branched linear or homogeneously branched substantially linear ethylene α-olefin interpolymer and 45 to 23 wt % thermoplastic polydiene-based polyurethane and wherein the blend has a surface energy greater than, or equal to, 34 dyne/cm.
2. The article of claim 1 in which the polydiene-based polyurethane is a polydiene diol-based polyurethane (pd-TPU).
3. The article of claim 1 in which the ethylene α-olefin interpolymer has a molecular weight distribution from 1.5 to 4.5.
4. The article of claim 2 in which the ethylene α-olefin interpolymer is substantially linear.
5. The article of claim 3 in which the ethylene α-olefin interpolymer is an ethylene/α-olefin random interpolymer and the diisocyanate component of the polydiene-based polyurethane is an aliphatic diisocyanate.
6. The article of claim 4 in which the ethylene α-olefin interpolymer is an ethylene/α-olefin random interpolymer, the diol component of the polydiene diol polyurethane is at least partially hydrogenated, and the diisocyanate component of the polydiene diol polyurethane is an aliphatic diisocyanate.
7. A blend comprising (i) 55 to 77 weight percent (wt %) ethylene α-olefin multi-block copolymer, and (ii) 45 to 23 wt % thermoplastic polydiene-based polyurethane and wherein the blend has a surface energy greater than, or equal to, 34 dyne/cm.
8. The blend of claim 7 in which the polydiene-based polyurethane is polydiene diol-based polyurethane.
9. The blend of claim 7 in which the ethylene multi-block copolymer has a molecular weight distribution from 1.5 to 4.5.
10. The blend of claim 9 in which the diisocyanate component of the polydiene-based polyurethane is an aliphatic diisocyanate.
11. The blend of claim 9 in which the diol component of the polydiene diol-based polyurethane is at least partially hydrogenated, and the diisocyanate component of the polydiene diol-based polyurethane is an aliphatic diisocyanate.
12. An aqueous dispersion comprising water and from 30 to 70 wt % solids, based on the total weight of the dispersion, the solids comprising a blend of a homogeneously branched linear or homogeneously branched substantially linear ethylene α-olefin interpolymer and thermoplastic polydiene-based polyurethane, the blend comprising from 55 to 77 weight percent (wt %) of the homogeneously branched or substantially linear homogeneously branched ethylene α-olefin interpolymer and from 45 to 23 wt % of the polydiene-based polyurethane, the solids having an average particle size of from 0.4 to 2.5 microns and wherein the dispersion has a surface energy greater than, or equal to, 34 dyne/cm when measured as a film.
13. The dispersion of claim 12 in which the polydiene-based polyurethane is a polydiene diol-based polyurethane.
14. The dispersion of claim 12 in which the homogeneously branched linear or homogeneously branched substantially linear ethylene α-olefin interpolymer has a molecular weight distribution from 1.5 to 4.5.
15. The dispersion of claim 14 in which the diisocyanate component of the polydiene-based polyurethane is an aliphatic diisocyanate.
16. The dispersion of claim 13 in which the diol component of the polydiene diol-based polyurethane is at least partially hydrogenated, and the diisocyanate component of the polydiene diol-based polyurethane is an aliphatic diisocyanate.
17. An article comprising a first structural component and a second structural component, the first structural component comprising a polar material and the second structural component comprising a blend of a olefin multi-block interpolymer and a thermoplastic polydiene-based polyurethane wherein the blend comprises from 55 to 77 weight percent (wt %) of the olefin multi-block interpolymer and from 45 to 23 wt % of the polydiene-based polyurethane and wherein the blend has a surface energy greater than, or equal to, 34 dyne/cm.