Volume hologram optical recording medium, composition for volume hologram recording layer formation, and volume hologram recording material
View Patent ↗This invention provides, for example, a highly stable and reliable volume hologram optical recording medium which can suppress an intensity variation, for example, in diffraction efficiency after signal recording and can stably develop a high S/N ratio. The volume hologram optical recording medium includes a recording layer containing at least one compound selected from compounds (A1) having a terpenoid structure, compounds (A2) represented by a formula (I), and cyclic or noncyclic compounds (A3) having at least two double bonds two of these double bonds are located at 1,4-position relatively, wherein R1 and R2 each independently represent an organic group having 1 to 20 carbon atoms, and R1 and R2 may combine to form a cyclic structure.
1. A volume hologram optical recording medium comprising
a recording layer comprising at least one compound selected from the group consisting of a compound (A1) having a terpenoid structure; a compound (A2) represented by a formula (I):
wherein R 1 and R 2 each represent an organic group having 1 to 20 carbon atoms, and R 1 and R 2 may combine to form a ring structure; and a cyclic or non-cyclic compound (A3) having at least two double bonds and two of these double bonds being present at 1 and 4 positions relatively,
a polymerizable photoactive compound (B), and
a resin matrix (C) having a glass transition temperature of Tg of which is in the range of −45° C. or higher, wherein the resin matrix is a three dimensionally cross-linked resin, and
wherein upon volume hologram optical recording, the optical recording medium exhibits a ratio R1 of diffraction efficiency five minutes after a recording with a light irradiation of 10-10,000 pulses of 0.2-0.4 mW of recording light when the light irradiation is ceased to diffraction efficiency one minute after the recording when the light irradiation is ceased, wherein R1 is from 0.1 to 2.1.
2. The volume hologram optical recording medium according to claim 1 , wherein the ratio R2 of the diffraction efficiency one day after the recording to the diffraction efficiency one minute after the recording is in a range of 0.7 or more and 4 or less.
3. The volume hologram optical recording medium according to claim 1 , wherein the compound (A1) having a terpenoid structure is selected from the group consisting of terpinolene, α-terpinene, β-terpinene and γ-terpinene.
4. The volume hologram optical recording medium according to claim 1 , wherein the cyclic or non-cyclic compound (A3) having at least two double bonds and two of these double bonds being present at 1 and 4 positions relatively is selected from the group consisting of 1,4 -cyclohexadiene, 1,4 -cycloheptadiene, linoleic acid or the derivatives thereof, and linolenic acid or the derivatives thereof.
5. The volume hologram optical recording medium according to claim 1 , wherein the recording layer comprises a monoterpene selected from the group consisting of camphor, menthol, limonene, terpinerol, geraniol, nerol, and citronellol.
6. The volume hologram optical recording medium according to claim 1 , wherein the recording layer comprises a compound (A3) selected from the group consisting of 1,2-dimethyl-1,4-cyclohexadiene, 1-ethyl-1,4-cyclohexadiene, 1-propyl-1,4-cyclohexadiene, 1-phenyl-1,4-cyclohexadiene, 1-methoxy-1,4-cyclohexadiene, 1-aceto-1,4-cyclohexadiene, 1-chloro-1,4-cyclohexadiene, 1-bromo-1,4-cyclohexadiene, 4,7-dihydroindane, 1,2,3,4,5,8-hexahydronaphthalene, 1,4-cycloheptadiene, 1,4-cyclooctadiene, 1,4-heptadiene, 1,4-hexadiene, 2-methyl-1,4-pentadiene, 3,6-nonanediene-1-ol, 9,12-octadecadienol, linolenic acid, γ-linolenic acid, linoleic acid, eicosapentaenoic acid, docosahexaenoic acid and derivatives thereof.
7. The volume hologram optical recording medium according to claim 1 , wherein the recording layer comprises a compound (A2) selected from the group consisting of 2,3,4-trimethyl-2-pentene, 2,3-dimethyl-2-butene, 6,6-dimethyl fulvene, isopropylidene malonic acid diethyl ester, and 5-methyl-2-(1-methylethylidene)-cyclohexanone.
8. A composition for volume hologram recording layer formation for use in a volume hologram optical recording medium, comprising:
a polymerizable photoactive compound (B) comprising a system capable of forming an optical image;
a resin matrix (C) having a glass transition temperature of Tg of which is in the range of −45° C. or higher, wherein the resin matrix is a three dimensionally cross-linked resin; and
at least one compound that is added to the system, and that is selected from the group consisting of a compound (A1) having a terpenoid structure, a compound (A2) represented by a formula (I):
wherein R 1 and R 2 each represent an organic group having 1 to 20 carbon atoms, and R 1 and R 2 may combine to form a ring structure; and a cyclic or non-cyclic compound (A3) having at least two double bonds, two of these double bonds being present at 1 and 4 positions relatively, wherein upon volume hologram optical recording, the optical recording medium exhibits a ratio R1 of diffraction efficiency five minutes after a recording with a light irradiation of 10-10,000 pulses of 0.2-0.4 mW of recording light when the light irradiation is ceased to diffraction efficiency one minute after the recording when the light irradiation is ceased, wherein R1 is from 0.1 to 2.1.
9. The composition for the volume hologram recording layer formation according to claim 8 , wherein the compound (A1) having a terpenoid structure is selected from the group consisting of terpinolene, α-terpinene, β-terpinene and γ-terpinene.
10. The composition for the volume hologram recording layer formation according to claim 8 , wherein the cyclic or non-cyclic compound (A3) having at least two double bonds and two of these double bonds being present at 1 and 4 positions relatively is selected from the group consisting of 1,4-cyclohexadiene, and 1,4-cycloheptadiene.
11. The composition for the volume hologram recording layer formation according to claim 8 , further comprising:
a photopolymerization initiator (D).
12. The composition for the volume hologram recording layer formation according to claim 8 , wherein the polymerizable photoactive compound (B) is a radical polymerizable monomer.
13. A volume hologram recording material, comprising: the composition for the volume hologram recording layer formation according to claim 8 .
14. A volume hologram optical recording medium, comprising:
a layer comprising the volume hologram recording material according to claim 13 .
15. The composition for the volume hologram recording layer formation according to claim 8 , wherein the composition comprises a monoterpene selected from the group consisting of camphor, menthol, limonene, terpinerol, geraniol, nerol, and citronellol.
16. The composition for the volume hologram recording layer formation according to claim 8 , wherein the composition comprises a compound (A3) selected from the group consisting of 1,2-dimethyl-1,4-cyclohexadiene, 1-ethyl-1,4-cyclohexadiene, 1-propyl-1,4-cyclohexadiene, 1-phenyl-1,4-cyclohexadiene, 1-methoxy-1,4-cyclohexadiene, 1-aceto-1,4-cyclohexadiene, 1-chloro-1,4-cyclohexadiene, 1-bromo-1,4-cyclohexadiene, 4,7-dihydroindane, 1,2,3,4,5,8-hexahydronaphthalene, 1,4-cycloheptadiene, 1,4-cyclooctadiene, 1,4-heptadiene, 1,4-hexadiene, 2-methyl-1,4-pentadiene, 3,6-nonanediene-1-ol, 9,12-octadecadienol, linolenic acid, γ-linolenic acid, linoleic acid, eicosapentaenoic acid, docosahexaenoic acid and derivatives thereof.
17. The composition for the volume hologram recording layer formation according to claim 8 , wherein the composition comprises a compound (A2) selected from the group consisting of 2,3,4-trimethyl-2-pentene, 2,3-dimethyl-2-butene, 6,6-dimethyl fulvene, isopropylidene malonic acid diethyl ester, and 5-methyl-2-(1-methylethylidene)-cyclohexanone.