β-type titanium alloy
View Patent ↗The present invention provides a β-type titanium alloy keeping the content of the relatively expensive β-stabilizing elements such as V or Mo down to a total of 10 mass % or less and reducing the effects of composition segregation of Fe and Cr and thereby able to keep the Young's modulus and density relatively low. The β-type titanium alloy of the present invention comprises, by mass %, when Al: 2 to 5%, 1) Fe: 2 to 4%, Cr: 6.2 to 11%, and V: 4 to 10%, 2) Fe: 2 to 4%, Cr: 5 to 11%, and Mo: 4 to 10%, or 3) Fe: 2 to 4%, Cr: 5.5 to 11%, and Mo+V (total of Mo and V): 4 to 10% in range, and a balance of substantially Ti. These include Zr added in amounts of 1 to 4 mass %. Furthermore, by making the oxygen equivalent Q 0.15 to 0.30 or leaving the alloy in the work hardened state or by applying both, the tensile strength before aging heat treatment can be further increased. Due to this, it is possible to obtain the required strength even if the amount of precipitation of the α phase with the high Young's modulus is small.
1. A β-type titanium alloy, which will consist of an α phase and a β phase after aging, containing, by mass %, Al: 2 to 5%, Fe: 2.6 to 4%, Cr: 6.2 to 9%, Zr: 1 to 4%, and V: 4 to 10% in ranges and having a balance of Ti and unavoidable impurities;
wherein:
when Vicker's hardness is randomly measured at six points in each of three L-cross-sections, a difference between a maximum value and a minimum value thereof is in a range from 10 to 20, and
a tensile strength of the β-type titanium alloy before aging is 920 MPa or more,
the α a phase is substantially uniformly precipitated after solution treatment, drawing and aging.
2. A worked product obtained by work hardening a β-type titanium alloy as set forth in claim 1 .
3. A β-type titanium alloy, which will consist of an α a phase and a β phase after aging, containing, by mass %, Al: 2 to 5%, Fe: 2.6 to 4%, Cr: 5 to 9%, Zr: 1 to 4%, and Mo: 4 to 10% in ranges and having a balance of Ti and unavoidable impurities;
wherein:
when Vicker's hardness is randomly measured at six points in each of three L-cross-sections, a difference between a maximum value and a minimum value thereof is in a range from 10 to 20, and
a tensile strength of the β-type titanium alloy before aging is 920 MPa or more,
the α phase is substantially uniformly precipitated after solution treatment, drawing and aging.
4. A β-type titanium alloy, which will consist of an α phase and a β phase after aging, containing, by mass %, Al: 2 to 5%, Fe: 2.6 to 4%, Cr: 5.5 to 9%, Zr: 1 to 4%, and Mo+V (total of Mo and V): 4 to 10% by Mo: 0.5% or more and V: 0.5% or more in ranges and having a balance of Ti and unavoidable impurities;
wherein:
when Vicker's hardness is randomly measured at six points in each of three L-cross-sections, a difference between a maximum value and a minimum value thereof is in a range from 10 to 20, and
a tensile strength of the β-type titanium alloy before aging is 920 MPa or more,
the α phase is substantially uniformly precipitated after solution treatment, drawing and aging.
5. The β-type titanium alloy as set forth in claim 1 , characterized in that an oxygen equivalent Q of formula [1] is 0.15 to 0.30:
Oxygen equivalent Q=[O]+2.77 [N] formula [1]
where, [O] is O (oxygen) content (mass %) and [N] is N content (mass %).
6. The β-type titanium alloy as set forth in claim 1 , characterized in that an oxygen equivalent Q of formula [1] is 0.21 to 0.30:
Oxygen equivalent Q=[O]+2.77[N] formula [1]
where, [O] is O (oxygen) content (mass %) and [N] is N content (mass %), and [O] is more than 0.2 mass %.
7. The β-type titanium alloy as set forth in claim 1 , wherein when the Vicker's hardness is randomly measured at six points in each of three L-cross-sections, the difference between a maximum value and a minimum value thereof is in a range from 10 to 20.
8. The β-type titanium alloy as set forth in claim 3 , wherein when the Vicker's hardness is randomly measured at six points in each of three L-cross-sections, the difference between a maximum value and a minimum value thereof is in a range from 10 to 20.
9. The β-type titanium alloy as set forth in claim 4 , wherein when the Vicker's hardness is randomly measured at six points in each of three L-cross-sections, the difference between a maximum value and a minimum value thereof is in a range from 10 to 20.