Process and apparatus for the catalytic oxidation of SO
View Patent ↗Process for the continuous catalytic complete or partial oxidation of a starting gas containing from 0.1 to 66% by volume of sulphur dioxide plus oxygen, in which the catalyst is kept active by means of pseudoisothermal process conditions with introduction or removal of energy; apparatus for the continuous catalytic complete or partial oxidation of a starting gas containing sulphur dioxide and oxygen having at least one tube contact apparatus in the form of an upright heat exchanger composed of at least one double-walled tube whose catalyst-filled inner tube forms a reaction tube, with heat being transferred in cocurrent around the reaction tube and an absorber for separating off SO 3 downstream of the tube contact apparatus; the reactivity of the catalyst being preset by mixing with inert material.
1. Process for the continuous catalytic, complete or partial oxidation of a starting gas containing sulphur dioxide and oxygen in a contact apparatus, the contact apparatus being an upright heat exchanger comprising at least a plurality of double-walled tubes which have an interior tube and an outer tube, with a catalyst being present in the interior tubes and heat transfer being effected around these interior tubes by means of a cooling medium which is conveyed in cocurrent through the intermediate space between interior and outer tubes in order to establish a temperature profile over the length of the reaction tube, at which the catalyst is kept active.
2. Process according to claim 1 , wherein the reactivity of the catalyst used is preset by mixing with the inert material in a ratio of from 1:100 to 100:1.
3. Process according to claim 1 wherein the starting gas has a sulphur dioxide content of from 0.1 to 66% by volume.
4. Process according to claim 1 , wherein air and/or technical-grade oxygen is introduced into the starting gas in an amount sufficient to form a volume ratio of O 2 to SO 2 in the gas of from 0.5 to 1.2.
5. Process according claim 1 , wherein the introduction or removal of energy to or from the reaction tubes is operated in cocurrent using a heat-transfer medium.
6. Process according to claim 1 , wherein the removal of energy is effected by air and a heat transfer number of from 20 to 80 W/m 2 K between interior tube and cooling medium is set.
7. Process according to claim 1 , wherein the starting gas having an SO 2 concentration of more than 13% is divided into two substreams, one of the substreams being fed through the contact apparatus and recombined with the other substream, and the substreams are divided in such a way, that the SO 2 concentration in the recombined substreams is less than 13%, and the recombined substreams are fed to at least one main contact in order to convert at least part of the remaining SO 2 to SO 3 .
8. Process according to claim 1 wherein, in a first step the starting gas having an SO 2 concentration of more than 13% is fed through the contact apparatus in order to convert part of the SO 2 to SO 3 , and in a second step the gas leaving the contact apparatus, after optionally being fed through a preasorber for removing SO 3 , is fed to a main contact in order to convert at least part of the remaining SO 2 to SO 3 .
9. Apparatus for the continuous catalytic complete or partial oxidation of a starting gas containing 0.1% to 66% sulphur dioxide and oxygen, having at least one tube contact apparatus which is an upright heat exchanger comprising at least one double-walled tube whose catalyst-filled interior tube forms a reaction tube, and is capable of transferring heat from as well as to the reaction tube by means of a cooling/heating medium.
10. Apparatus according to claim 9 , wherein the reaction tubes have a nominal diameter of from 25 mm to 150 mm at a tube length of from 1 m to 12 m.
11. Apparatus according to claim 9 or 10 , wherein the catalyst is mixed with inert material to optimize the removal of energy.
12. Apparatus according to claim 9 , wherein the heat is transferred around the reaction tubes by means of air as cooling medium and the double-walled construction enables a heat transfer number of from 20 to 80 W/m 2 K between interior tube and cooling medium.
13. Apparatus according to claim 9 , wherein the tube contact apparatus is followed by:
a. optionally a preabsorber,
b. one or more contact stages, optionally with one or more oleum/intermediate absorbers,
c. a final absorber, optionally an offgas purification plant.
14. Apparatus according to claim 9 , wherein the apparatus is installed in a bypass arrangement upstream of a conventional double contact plant, so that the starting gas can be divided by a choke flap into two substreams, one of the substreams can be fed through the apparatus and recombined with the other substream, and the recombined substreams can be fed to a main contact.
15. Apparatus according to claim 9 , wherein the apparatus comprises at least 100 tubes.
16. Apparatus according to claim 15 wherein the apparatus comprises more than 1000 tubes.