Coating composition for antireflection with resistance and antireflection characteristic and antireflection film prepared by using the same
A coating composition for antireflection that includes a low refraction-thermosetting resin having a refractive index of 1.2 to 1.45, a high refraction-ultraviolet curable resin having a refractive index of 1.46 to 2, and an ultraviolet absorber; an antireflection film manufactured using the coating composition; and a method of manufacturing the antireflection film. The antireflection film has excellent abrasion resistance and antireflection characteristic. Further, since the antireflection film can be manufactured in one coating process, it is possible to reduce manufacturing cost.
1. A coating composition for an antireflection single coating layer comprising:
a low refraction-thermosetting resin having a refractive index of 1.2 to 1.45;
a high refraction-ultraviolet curable resin having a refractive index of 1.46 to 2; and
an ultraviolet absorber,
wherein the high refraction-ultraviolet curable resin has a continuous concentration gradient in a thickness direction of the single coating layer,
wherein the single coating layer is manufactured by a curing process that involves radiating ultraviolet light and thermosetting,
wherein the low refraction-thermosetting resin includes one or more compounds selected from the group consisting of a silicon alkoxide reactant that cause a sol-gel reaction, a urethane reactive group compound, a urea reactive group compound, and an esterification reactant, and
wherein the high refraction-ultraviolet curable resin includes one or more monomers selected from the group consisting of acrylate monomer, urethane acrylate oligomer, epoxy acrylate oligomer, and ester acrylate oligomer.
2. The coating composition for an antireflection single coating layer according to claim 1 further comprising 1 to 20 parts by weight of a photoinitiator based on 100 parts by weight of the high refraction-ultraviolet curable resin.
3. The coating composition for an antireflection single coating layer according to claim 1 , wherein the content of the low refraction-thermosetting resin is 5 to 80 parts by weight, the content of the high refraction-ultraviolet curable resin is 10 to 90 parts by weight, and the content of the ultraviolet absorber is 0.05 to 30 parts by weight, based on 100 parts by weight of the entire solid composition.
4. The coating composition for an antireflection single coating layer according to claim 1 further comprising a solvent.
5. An antireflection film comprising:
a single coating layer, the single coating layer including a low refraction-thermosetting resin having a refractive index of 1.2 to 1.45; a high refraction-ultraviolet curable resin having a refractive index of 1.46 to 2; and an ultraviolet absorber,
wherein the high refraction-ultraviolet curable resin has a continuous concentration gradient in a thickness direction of the single coating layer,
wherein the single coating layer is manufactured by a curing process that involves radiating ultraviolet light and thermosetting,
wherein the low refraction-thermosetting resin includes one or more compounds selected from the group consisting of a silicon alkoxide reactant that cause a sol-gel reaction, a urethane reactive group compound, a urea reactive group compound, and an esterification reactant, and
wherein the high refraction-ultraviolet curable resin includes one or more monomers selected from the group consisting of acrylate monomer, urethane acrylate oligomer, epoxy acrylate oligomer, and ester acrylate oligomer.
6. The antireflection film according to claim 5 , wherein the weight of the high refraction-ultraviolet curable resin, which is included in a region corresponding to 50% of the thickness in the thickness direction from the surface of the single coating layer facing the substrate, is 70% or more of the total weight of the high refraction-ultraviolet curable resin.
7. The antireflection film according to claim 5 , wherein reflectance is lower than 3%.
8. The antireflection film according to claim 5 , wherein the antireflection film is formed by a method of manufacturing an antireflection film including: i) preparing a coating composition for antireflection that contains a low refraction-thermosetting resin having a refractive index of 1.2 to 1.45, a high refraction-ultraviolet curable resin having a refractive index of 1.46 to 2, and an ultraviolet absorber; ii) forming a coating layer by applying the coating composition on a substrate; iii) radiating ultraviolet light in order to cure the high refraction-ultraviolet curable resin so that the high refraction-ultraviolet curable resin has a concentration gradient in a thickness direction of the coating layer; and iv) curing the low refraction-thermosetting resin.
9. The antireflection film according to claim 8 , wherein Step iii) includes iiia) radiating ultraviolet light on the side of the coating layer facing the substrate, iiib) diffusing and moving an unreacted high refraction-ultraviolet curable resin toward the side of the coating layer facing the substrate and the low refraction-thermosetting resin toward the side of the coating layer coming in contact with air, and iiic) radiating ultraviolet light on both sides of the coating layer.
10. A polarizing plate comprising:
a) a polarizing film; and
b) the antireflection film according to claim 5 that is provided on at least one side of the polarizing film.
11. The polarizing plate according to claim 10 further comprising a protection film that is provided between the polarizing film and the antireflection film.
12. The polarizing plate according to claim 10 , wherein the antireflection film includes a substrate layered on a single coating layer, and the substrate is provided between the polarizing film and the single coating layer.
13. A display comprising the antireflection film according to claim 5 .