Polypropylene composition with low surface energy
View Patent ↗Polypropylene composition comprising a) an isotactic polypropylene (iPP) produced in the presence of a single-site catalyst and said isotactic polypropylene (iPP) has a mean isotactic block length between two structural chain defects, as a statistical average, greater than 70, and b) an atactic polypropylene (aPP) with an absorbance ratio of the absorption band at 998 cm −1 to the absorption band at 973 cm −1 [A 998 /A 973 ] below 0.80 wherein the weight ratio of said atactic polypropylene to the sum of said atactic polypropylene and said isotactic polypropylene (aPP/(aPP+iPP)) is at least 0.50 wt.-%.
1. Article selected from the group consisting of a refrigerator, a dishwasher and a washing machine wherein the article comprises a polypropylene composition having a reduced surface energy, comprising:
a mixture of:
(a) an isotactic polypropylene (iPP) produced in the presence of a single site metallocane catalyst having a molecular weight distribution (MWD) of below 4.00 and a mean isotactic block length between two structural chain defects, as a statistical average, greater than 70, and
b) an atactic polypropylene (aPP) with an absorbance ratio of the absorption band at 998 cm −1 to the absorption band at 973 cm −1 (A 998 /A 973 ) below 0.10,
wherein the weight ratio of said atactic polypropylene to the sum of said atactic polypropylene and said isotactic polypropylene (aPP/(aPP+iPP)) is 0.50 to 9.00 wt.-%, and
wherein the polypropylene composition has surface energy of between 23.88 and 27 mN/m.
2. Article according to claim 1 , wherein the isotactic and/or the atactic polypropylene is a homopolymer.
3. Article according to claim 1 , wherein the isotactic block length of the atactic polypropylene molecule between two structural chain defects is, as a statistical average, below 20.
4. Article according to claim 1 , wherein the isotactic polypropylene has a melting temperature of below 163° C.
5. Article according to claim 1 , wherein the polypropylene composition has a xylene cold soluble fraction of below 15.00 wt. %.
6. Process for the reduction of surface energy of a polypropylene composition used in the manufacture of a refrigerator, a dishwasher, or a washing machine, comprising:
(a) providing an atactic polypropylene (aPP) with an absorbance ratio of the absorption band at 998 cm −1 to the absorption band at 973 cm −1 (A 998 / A 973 ) below 0.10,
(b) providing an isotactic polypropylene (iPP) produced in the presence of a single site metallocene catalyst having a molecular weight distribution (MWD) of below 4.00 and a mean isotacic block length between two structural chain defects, as a statistical average, greater than 70; and,
(c) reducing the surface energy of said isotactic polypropylene by mixing the atactic polypropylene (aPP) with the isotactic polypropylene (iPP) in an amount to provide a weight ratio of said atactic polypropylene to the sum of said atactic polypropylene and said isotactic polypropylene (aPP/(App+iPP)) of 0.50 to 9.00 wt.-%; and
wherein the obtained polypropylene composition has a surface energy of between 23.88 and 27 mN/m.
7. Process according to claim 6 , wherein the isotactic and/or the atactic polypropylene is a homopolymer.
8. Process according to claim 6 , wherein the isotactic block length of the atactic polypropylene molecule between two structural chain defects is, as a statistical average, below 20.
9. Process according to claim 6 , wherein the isotactic polypropylene has a melting temperature of below 163° C.
10. Process according to claim 6 , wherein the polypropylene composition has a xylene cold soluble fraction of below 15.00 wt. %.