Optical films, retardation films, and liquid crystal display comprising the same
The present invention relates to an optical film that comprises a block copolymer that comprises a vinyl polymer block containing styrene or a derivative thereof, and a poly-dimethylsiloxane block, a retardation film using the same, a method of manufacturing them, and a liquid crystal display comprising the films.
1. A retardation film consisting essentially of:
a block copolymer comprising a vinyl polymer block containing styrene or a derivative thereof, and a polydimethylsiloxane block,
wherein a weight ratio of the polydimethylsiloxane block and the vinyl polymer block is in the range of 3:20 to 3:40,
wherein the styrene or a derivative thereof is represented by the following Formula 1:
wherein R1s may be same or different from each other and are each independently a hydrocarbon radical selected from alkyl having 1 to 20 carbon atoms or halogen and n is an integer in the range of 0 to 5,
wherein the styrene or the derivative thereof is comprised in an amount in the range of 50 to 100 mol % in the vinyl polymer block,
wherein the block copolymer is a A-(B-A) p -B type or a A-(B-A) m type, in which A is the polydimethylsiloxane block, B is the vinyl polymer block, in which p is an integer in the range of 0 to 3, and m is an integer in the range of 1 to 3,
wherein a thickness retardation value (R th ) of the retardation film measured at 590 nm and calculated by Equation 1 is in the range of 196 to 480 nm and an in-plane retardation value (R in ) measured at 590 nm and calculated by Equation 2 is in the range of 153 to 500 nm,
R th =( n z −n y )× d [Equation 1]
R in =( n x −n y )× d [Equation 2]
wherein the n x is the refractive index in the direction in which the refractive index is highest in respects to the plane of the retardation film, the n y is the refractive index in the transverse direction in respects to the nx in the plane, the n z is the refractive index in the direction which is perpendicular in respects to the plane of the retardation film and the d is the thickness of the retardation film,
wherein the retardation film is an uniaxially or biaxially stretched film, and
wherein the retardation film does not break when folded 180 degrees.
2. The retardation film according to claim 1 , wherein the vinyl polymer block further comprises one or more comonomers selected from the group consisting of a (meth)acrylic ester compound, a vinyl cyanide compound, and a maleimide compound.
3. The retardation film according to claim 1 , wherein the polydimethylsiloxane block comprises a compound that is represented by the following Formula 2:
wherein R2, R3, R4, R5, R6, and R7 are same or different from each other, and are each independently alkyl having 1 to 12 carbon atoms, arylalkyl having 6 to 12 carbon atoms, or aryl having 6 to 12 carbon atoms,
X1 and X2 are same or different from each other, and are each independently alkyl having 1 to 12 carbon atoms, arylalkyl having 6 to 12 carbon atoms, or aryl having 6 to 12 carbon atoms, and
q is an integer of 1 or more.
4. The retardation film according to claim 3 , wherein X1 and X2 of Formula 2 are further bonded to an end group that is selected from the group consisting of hydroxy, amine, isocyanate, and epoxy.
5. A liquid crystal display comprising:
one or more retardation films according to claim 1 .
6. A retardation film consisting essentially of:
a block copolymer comprising a vinyl polymer block containing styrene or a derivative thereof, and a polydimethylsiloxane block; and
a compound including a nitroxide radical,
wherein a weight ratio of the polydimethylsiloxane block and the vinyl polymer block is in the range of 3:20 to 3:40,
wherein the styrene or a derivative thereof is represented by the following Formula 1:
wherein R1s may be same or different from each other and are each independently a hydrocarbon radical selected from alkyl having 1 to 20 carbon atoms or halogen and n is an integer in the range of 0 to 5,
wherein the styrene or the derivative thereof is comprised in an amount in the range of 50 to 100 mol % in the vinyl polymer block,
wherein the block copolymer is a A-(B-A) p -B type or a A-(B-A) m type, in which A is the polydimethylsiloxane block, B is the vinyl polymer block, in which p is an integer in the range of 0 to 3, and m is an integer in the range of 1 to 3,
wherein a thickness retardation value (R th ) of the retardation film measured at 590 nm and calculated by Equation 1 is in the range of 196 to 480 nm and an in-plane retardation value (R in ) measured at 590 nm and calculated by Equation 2 is in the range of 153 to 500 nm,
R th =( n z −n y )× d [Equation 1]
R in =( n x −n y )× d [Equation 2]
wherein the n x is the refractive index in the direction in which the refractive index is highest in respects to the plane of the retardation film, the n y is the refractive index in the transverse direction in respects to the nx in the plane, the n z is the refractive index in the direction which is perpendicular in respects to the plane of the retardation film and the d is the thickness of the retardation film,
wherein the retardation film is an uniaxially or biaxially stretched film, and
wherein the retardation film does not break when folded 180 degrees.
7. The retardation film according to claim 6 , wherein the compound that includes the nitroxide radical is TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl), MTEMPO (2,2,4,6,6-pentamethylpiperidine-1-oxyl), or a compound that is represented by the following Formula 3:
wherein r is 1, 2, 3 or 4,
R 1 , R 2 , R 3 , and R 4 may be same or different from each other, and are each independently methyl or ethyl, or R 1 and R 2 , or R 3 and R 4 may form pentamethylene,
when r is 1, E is C 1 ˜C 19 alkyl, C 2 ˜C 17 alkenyl, phenyl, or phenyl in which 1 to 3 C 1 ˜C 4 alkyls are substituted,
when r is 2, E is C 2 ˜C 12 alkylene, ortho phenylene, metal phenylene, or para phenylene,
when r is 3, E is C 3 ˜C 7 alkanetriyl, 1,2,4-benzenetriyl, or 1,3,5-benzenetriyl, and
when r is 4, E is C 4 ˜C 8 alkanetetrayl, or 1,2,4,5-benzenetetrayl.
8. An integrated polarizing plate comprising:
a polarizing film;
a retardation film that consists essentially of a block copolymer comprising a vinyl polymer block containing styrene or a derivative thereof, and a polydimethylsiloxane block on a side or both sides of the polarizing film as a protective film,
wherein a weight ratio of the polydimethylsiloxane block and the vinyl polymer block is in the range of 3:20 to 3:40,
wherein the styrene or a derivative thereof is represented by the following Formula 1:
wherein R1s may be same or different from each other and are each independently a hydrocarbon radical selected from alkyl having 1 to 20 carbon atoms or halogen and n is an integer in the range of 0 to 5,
wherein the styrene or the derivative thereof is comprised in an amount in the range of 50 to 100 mol % in the vinyl polymer block,
wherein the block copolymer is a A-(B-A) p -B type or a A-(B-A) m type, in which A is the polydimethylsiloxane block, B is the vinyl polymer block, in which p is an integer in the range of 0 to 3, and m is an integer in the range of 1 to 3,
wherein a thickness retardation value (R th ) of the retardation film measured at 590 nm and calculated by Equation 1 is in the range of 196 to 480 nm and an in-plane retardation value (R in ) measured at 590 nm and calculated by Equation 2 is in the range of 153 to 500 nm,
R th =( n z −n y )× d [Equation 1]
R in =( n x −n y )× d [Equation 2]
wherein the n x is the refractive index in the direction in which the refractive index is highest in respects to the plane of the retardation film, the n y is the refractive index in the transverse direction in respects to the nx in the plane, the n z is the refractive index in the direction which is perpendicular in respects to the plane of the retardation film and the d is the thickness of the retardation film,
wherein the retardation film is an uniaxially or biaxially stretched film, and
wherein the retardation film does not break when folded 180 degrees.
9. A liquid crystal display comprising:
a liquid crystal cell; and
a first polarizing plate and a second polarizing plate provided on both sides of the liquid crystal cell respectively,
wherein the first polarizing plate, the second polarizing plate, or both the first polarizing plate and the second polarizing plate are the integrated polarizing plate of claim 8 .