Zinc ferrite catalysts, method of preparing thereof and method of preparing 1,3-butadiene using thereof
View Patent ↗The present invention relates to a zinc ferrite catalyst, a method of producing the same, and a method of preparing 1,3-butadiene using the same. Specifically, the present invention relates to a zinc ferrite catalyst which is produced in a pH-adjusted solution using a coprecipitation method, a method of producing the same, and a method of preparing 1,3-butadiene using the same, in which the 1,3-butadiene can be prepared directly using a C4 mixture including n-butene and n-butane through an oxidative dehydrogenation reaction. The present invention is advantageous in that 1,3-butadiene can be obtained at a high yield directly using a C4 fraction without performing an additional process for separating n-butene, as a reactant, from a C4 fraction containing impurities.
1. A method of preparing 1,3-butadiene, comprising:
(i) producing a zinc ferrite catalyst consisting of:
(A) dissolving a zinc precursor and an iron precursor in distilled water to form an aqueous precursor solution;
(B) adding the aqueous precursor solution and simultaneously an alkaline solution having a molar concentration of 1.5-4.0 M to distilled water to form a mixed solution and simultaneously adjusting a pH of the mixed solution within a range of 6-10;
(C) filtering the pH-adjusted mixed solution to obtain a solid catalyst;
(D) drying the solid catalyst at 70-200° C.; and
(E) heat-treating the dried solid catalyst at 350-800° C.
(ii) continuously passing a reactant consisting of a mixed gas of a C4 mixture, air and steam through a catalyst layer supported with the zinc ferrite catalyst to conduct an oxidative dehydrogenation reaction, the C4 mixture comprises 0.5˜50 wt % of n-butane, 40˜99 wt % of n-butene, and 0.5˜10 wt % other than n-butane and n-butene,
(iii) obtaining 1,3-butadiene from the catalyst layer.
2. The method of preparing 1,3-butadiene according to claim 1 , wherein, in (ii), a mixing ratio of n-butene:air:steam in the reactant is 1:0.5˜10:1˜50.
3. The method of preparing 1,3-butadiene according to claim 1 , wherein, in (ii), the oxidative dehydrogenation reaction is conducted at a reaction temperature of 300˜600° C. and at a space velocity of 50˜5000 h −1 based on n-butene.