Process for the carbonylation of dimethyl ether
View Patent ↗Process for the production of methyl acetate by carbonylating a dimethyl ether feed with carbon monoxide under substantially anhydrous conditions, in the presence of a zeolite catalyst effective for the carbonylation. The carbonylation is carried out at a temperature in the range of 275 to 350° C. and in the presence of hydrogen.
1. A process for the production of methyl acetate which process comprises the carbonylation of a dimethyl ether feed with carbon monoxide under substantially anhydrous conditions, in the presence of a zeolite catalyst effective for said carbonylation, wherein said carbonylation is carried out at a temperature in the range of 275 to 350° C. and in the presence of hydrogen.
2. A process according to claim 1 wherein the molar ratio of carbon monoxide:hydrogen is in the range 1:3 to 15:1.
3. A process according to claim 1 wherein the process is carried out at a hydrogen partial pressure in the range 0.1 to 50 barg.
4. A process according to claim 3 wherein the process is carried out at a hydrogen partial pressure in the range 5 to 25 barg.
5. A process according to claim 1 wherein the process is carried out at a total pressure in the range 10 to 100 barg.
6. A process according to claim 5 wherein the process is carried out at a total pressure in the range 30 to 80 barg.
7. A process according to claim 1 wherein the zeolite is loaded with one or more metals.
8. A process according to claim 1 wherein the zeolite contains at least one channel which is defined by an 8-member ring.
9. A process according to claim 8 wherein the zeolite is selected from the group consisting of mordenite, ferrierite, offretite and gmelinite.
10. A process according to claim 9 wherein the mordenite is H-mordenite or is ion-exchanged or otherwise loaded with at least one metal selected from the group consisting of copper, nickel, iridium, silver, rhodium, platinum, palladium and cobalt.
11. A process according to claim 10 wherein the metal is present in the mordenite at a loading in the range 50 to 120 mol % relative to aluminum.
12. A process according to claim 1 wherein at least some of the methyl acetate product is hydrolyzed to acetic acid.
13. A process according to claim 1 wherein the carbonylation is carried out in the presence of a mordenite zeolite at a temperature in the range of 275° C. to 350° C., at a total pressure in the range 30 to 80 barg and a carbon monoxide:hydrogen molar ratio of 1:1 to 4:1.
14. A process according to claim 1 wherein the carbonylation is carried out in the presence of a mordenite zeolite at a temperature in the range of 275° C. to 350° C., at a total pressure in the range 30 to 80 barg and a hydrogen partial pressure in the range 5 to 25 barg.