Coated article with ion treated underlayer and corresponding method
View Patent ↗A coated article is provided that may be used as a vehicle windshield, insulating glass (IG) window unit, or the like. Ion beam treatment is performed on a layer(s) of the coating. For example, a silicon nitride layer of a low-E coating may be ion beam treated. It has been found that ion beam treatment, for example, of a silicon nitride underlayer is advantageous in that sodium migration from the glass substrate toward the IR reflecting layer(s) can be reduced during heat treatment.
1. A coated article including a glass substrate which supports a coating thereon, the coating comprising at least the following layers:
an ion beam-treated layer comprising silicon nitride supported by the glass substrate;
an IR reflecting layer located on and supported by the substrate, the IR reflecting layer being located over at least the layer comprising silicon nitride; and
wherein the ion beam-treated layer comprising silicon nitride comprises nitrogen-doped Si 3 N 4 .
2. The coated article of claim 1 , wherein the layer comprising nitrogen-doped Si 3 N 4 is doped with at least 2% nitrogen.
3. The coated article of claim 1 , wherein the coated article has a visible transmission of at least about 70% and a sheet resistance of less than or equal to about 6 ohms/square.
4. The coated article of claim 1 , wherein the layer comprising silicon nitride is located in direct contact with the glass substrate.
5. The coated article of claim 1 , further comprising an overcoat layer comprising silicon nitride located on the substrate over at least the IR reflecting layer, wherein the overcoat layer comprising silicon nitride has compressive stress.
6. The coated article of claim 1 , wherein the IR reflecting layer comprises silver.
7. The coated article of claim 1 , further comprising a layer comprising zinc oxide, wherein the IR reflecting layer is located over and contacts the layer comprising zinc oxide.
8. The coated article of claim 1 , wherein the layer comprising silicon nitride has compressive stress and is ion beam treated.
9. The coated article of claim 1 , wherein the coating comprises first and second layers comprising silver with at least one dielectric layer provided therebetween.
10. The coated article of claim 1 , wherein the coated article is heat treated, has a visible transmission of at least 70% and a sheet resistance (R s ) of no greater than 5.5 ohms/square.
11. The coated article of claim 1 , further comprising an oxidation graded layer comprising NiCr contacting the IR reflecting layer.
12. The coated article of claim 1 , wherein the layer comprising silicon nitride further includes at least one of aluminum and oxygen.
13. The coated article of claim 1 , wherein the coated article is a window.
14. The coated article of claim 1 , wherein the layer comprising silicon nitride has an average hardness of at least 20 GPa.
15. The coated article of claim 1 , wherein the layer comprising silicon nitride has an average hardness of at least 24 GPa.
16. A coated article including a glass substrate which supports a coating thereon, the coating comprising at least the following layers:
a layer comprising nitrogen-doped silicon nitride which has an average hardness of at least 22 GPa, wherein the nitrogen-doped silicon nitride is doped with at least 2% nitrogen;
an IR reflecting layer located on the substrate over at least the layer comprising silicon nitride; and
wherein the coated article has a visible transmission of at least about 70% and a sheet resistance of less than or equal to about 6 ohms/square.
17. The coated article of claim 16 , wherein the layer comprising silicon nitride has an average hardness of at least 24 GPa.
18. The coated article of claim 16 , wherein the coated article is thermally tempered.
19. The coated article of claim 16 , wherein the layer comprising silicon nitride comprises nitrogen-doped Si 3 N 4 .
20. A coated article including a glass substrate which supports a coating thereon, the coating comprising at least the following layers:
a layer comprising silicon nitride supported by the glass substrate;
an IR reflecting layer located on and supported by the substrate, the IR reflecting layer being located over at least the layer comprising silicon nitride;
wherein the layer comprising silicon nitride comprises nitrogen-doped Si 3 N 4 , and wherein at least some excess nitrogen present in the layer due to doping is not bonded to silicon.
21. The coated article of claim 1 , wherein the ion beam-treated layer is nitrogen ion beam-treated.