Reflective polymeric article and manufacture
View Patent ↗In one embodiment, the method for making a polymer article comprises: orienting polymer chains in one direction more than any other direction to form an oriented article, contacting the oriented article with a foaming agent, and foaming the material to form the reflective polymer article comprising planar cell structures having a length “l” and a thickness “t”.
1. A method of making a reflective polymer article comprising:
orienting polymer chains in one direction more than any other direction, to form an oriented article;
contacting the oriented article with a foaming agent; and
foaming the material to form the reflective polymer article comprising planar cell structures having a length “l” and a thickness “t”.
2. The method of claim 1 , wherein the length “l” is greater than or equal to 10 times the thickness “t”.
3. The method of claim 1 , wherein the polymer chains are selected from the group consisting of polyetherimide chains, polycarbonate chains, and combinations comprising at least one of the foregoing polymer chains.
4. The method of claim 1 , wherein orienting the polymer chains comprises stretching a polymer material in one direction more than the polymer material is stretched in another direction.
5. The method of claim 4 , wherein the polymer material is stretched under uni-axial tension.
6. The method of claim 1 , wherein the reflective polymer article is designed to reflect a particular wavelength of light, and wherein the average thickness “t” is less than or equal to the particular wavelength.
7. The method of claim 6 , wherein the average thickness “t” is equivalent to 0.25 times the particular wavelength to 0.75 times the particular wavelength.
8. The method of claim 1 , wherein the reflective polymer article comprises less than or equal to 10 layers of the polymer material.
9. The method of claim 1 , further comprising placing the oriented article between plates and constraining the oriented article during the foaming of the material.
10. A reflective polymer article formed by the method comprising:
orienting polymer chains in one direction more than any other direction to form an oriented article;
contacting the oriented article with a foaming agent; and
foaming the material to form the reflective polymer article comprising planar cell structures having a length “l” and a thickness “t”.
11. The article of claim 10 , wherein the reflective polymer article is designed to reflect a particular wavelength of light, and wherein the average thickness “t” is less than or equal to the particular wavelength.
12. A reflective polymer article comprising:
layers of polymer material comprising polymer chains oriented one direction more than any other direction; and
layers of gas cells having a planar cell structure.
13. The article of claim 12 , wherein the reflective polymer article is designed to reflect a particular wavelength of light, and wherein an average thickness “t” is less than or equal to the particular wavelength.
14. The article of claim 12 , comprising a total number of layers of less than or equal to 15 including both layers of polymer material and layers of gas cells, and has a reflectivity of greater than 80% at wavelengths of 280 nm to 1,200 nm.
15. The method of claim 1 , wherein orienting the polymer chains comprises stretching a polymer material at a temperature less than the glass transition temperature of the polymer material.
16. The method of claim 15 , wherein stretching the polymer material occurs at a temperature 5° C. to 20° C. less than the glass transition temperature of the polymer material.
17. The method of claim 1 , wherein foaming the material occurs at a temperature less than the glass transition temperature of the polymer material.
18. The method of claim 1 , wherein the average thickness “t” is 100 nanometers to 2,000 nanometers.
19. The article of claim 10 , wherein orienting the polymer chains comprises stretching a polymer material at a temperature less than the glass transition temperature of the polymer material and wherein foaming the material occurs at a temperature less than the glass transition temperature of the polymer material.
20. The article of claim 12 , wherein foaming the material occurs at a temperature less than the glass transition temperature of the polymer material.