IP Library Granted Patent US 8,790,793
Granted Patent B2
US 8,790,793 · App. 12/463,250 · Granted Jul 29, 2014

Organic electroluminescent element with electron transport layer containing condensed aromatic heterocyclic compound, display device and lighting device

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Quick Facts
Patent No.
US 8,790,793
App. No.
12/463,250
Granted
Jul 29, 2014
Kind
B2
Abstract

Provided is an organic electroluminescent element comprising a substrate having thereon an anode, a cathode, and a plurality of organic layers sandwiched between the anode and the cathode, wherein the plurality of organic layers comprise: a light emitting layer containing a phosphorescence emitting compound; and an electron transport layer containing a compound represented by Formula (1), (Ar1)n1-Y1  Formula (1) wherein n1 is an integer of 1 or more; Y 1 is a substituent when n1 is 1, and Y 1 is a single bond or a linking group of n1 valences when n1 is two or more; Ar1 is a group represented by Formula (A), a plurality of Ar1 may be the same or different with each other when n1 is two or more; and the compound represented by Formula (1) contains at least two condensed aromatic heterocyclic rings each comprising 3 or more rings condensed with each other.

Claims (20)

1. An organic electroluminescent element comprising a substrate having thereon an anode, a cathode, and a plurality of organic layers sandwiched between the anode and the cathode, wherein the plurality of organic layers comprise:

a light emitting layer containing a phosphorescence emitting compound; and

an electron transport layer containing an electron transport compound represented by Formula (1),

(Ar1)n1-Y1  Formula (1)

wherein Y1 is a single bond or a heteroaryl group of n1 valences; the heteroaryl group being one selected from the group consisting of a carboline ring, a diazacarbazole ring, a triazole ring, a pyrrole ring, a quinoxaline ring, and an indole ring; and n1 is an integer of two or more; Ar1 is a group represented by Formula (A), a plurality of Ar1 may be the same or different with each other; and the compound represented by Formula (1) contains at least two condensed aromatic heterocyclic rings each comprising 3 or more rings condensed with each other:

wherein X is —O— or —S—; E1 to E8 each are —C(R1)═, R1 is a hydrogen atom, a substituent or a bonding site to Y1, (*) is a bonding site to Y1; Y2 is a single bond; Y3 is a group derived from a 6 membered aromatic ring, and Y4 is a group derived from a 6 membered aromatic heterocyclic ring containing a nitrogen atom in the ring; Y3 is bonded to Y4 at an ortho position or a meta position of Y3; and n2 is an integer of 1 to 4; and

wherein the light emitting layer further contains a host compound which has a different structure from the compound represented by Formula (1).

2. The organic electroluminescent element of claim 1 , wherein n2 in Formula (A) is an integer of 1 or 2.

3. The organic electroluminescent element of claim 1 , wherein Y4 of Formula (A) is a group derived from a pyridine ring.

4. The organic electroluminescent element of claim 1 , wherein Y3 of Formula (A) is a group derived from a benzene ring.

5. The organic electroluminescent element of claim 1 , wherein the phosphorescence emitting compound contained in the light emitting layer is a compound represented by Formula (4):

wherein P and Q each are a carbon atom or a nitrogen atom; A1 is a group of atoms which forms an aromatic hydrocarbon ring or an aromatic heterocyclic ring together with P—C; A2 is a group of atoms which forms an aromatic heterocyclic ring together with Q-N; P1-L1-P2 is a bidentate ligand, P1 and P2 each independently are a carbon atom, an nitrogen atom or an oxygen atom, L1 is a group of atoms which forms a bidentate ligand together with P1 and P2; j1 is an integer of 1 to 3; j2 is an integer of 0 to 2, provided that a sum of j1 and j2 is 2 or 3; and M1 is a transition metal of Groups 8 to 10 of the Element Periodic Table.

6. The organic electroluminescent element of claim 5 , wherein the compound represented by Formula (4) is further represented by Formula (5):

wherein Z is a hydrocarbon ring or a heterocyclic ring; A1 is a group of atoms which forms an aromatic hydrocarbon ring or an aromatic heterocyclic ring together with P—C; A3 is —C(R01)=C(R02)-, —N═C(R02)-, —C(R01)=N— or —N═N—, R01 and R02 each are a hydrogen atom or a substituent; P1-L1-P2 is a bidentate ligand, P1 and P2 each independently are a carbon atom, an nitrogen atom or an oxygen atom, L1 is a group of atoms which forms a bidentate ligand together with P1 and P2; j1 is an integer of 1 to 3; j2 is an integer of 0 to 2, provided that a sum of j1 and j2 is 2 or 3; and M1 is a transition metal of Groups 8 to 10 of the Element Periodic Table.

7. The organic electroluminescent element of claim 5 , wherein M1 of Formula (4) is iridium.

8. The organic electroluminescent element of claim 1 , wherein the electron transport layer is produced by a step of forming the layer using a wet process.

9. The organic electroluminescent element of claim 1 , wherein the light emitting layer is produced by a step of forming the layer using a wet process.

10. The organic electroluminescent element of claim 1 emitting a white light.

11. A lighting device provided with the organic electroluminescent element of claim 1 .

12. A display device provided with the organic electroluminescent element of claim 1 .

Assignments (4)
NUNC PRO TUNC ASSIGNMENT Recorded Oct 7, 2021
From: KONICA MINOLTA INC
To: MERCK PERFORMANCE MATERIALS GERMANY GMBH
Reel/Frame 057748/0075 →
NUNC PRO TUNC ASSIGNMENT Recorded Oct 7, 2021
From: MERCK PERFORMANCE MATERIALS GERMANY GMBH
To: MERCK PATENT GMBH
Reel/Frame 057748/0146 →
CHANGE OF NAME Recorded Mar 23, 2020
From: KONICA MINOLTA HOLDINGS, INC.
To: KONICA MINOLTA, INC.
Reel/Frame 052207/0010 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 13, 2009
From: YASUKAWA, NORIKO; KITA, HIROSHI; KATOH, EISAKU; TANAKA, TATSUO; OTSU, SHINYA; KATAKURA, RIE; OZEKI, HIDEKANE; TAKA, HIDEO
To: KONICA MINOLTA HOLDINGS, INC.
Reel/Frame 022675/0043 →