Polycarbonate blends having low-temperature impact strength
View Patent ↗The present invention relates to a polycarbonate composition comprising polyalkyl(alkyl)acrylate having a specific molecular weight and an impact modifier, as well as to moulded bodies obtainable from these compositions. Compositions according to the present invention exhibit superior properties, in particular with respect of low-temperature strength and melt flowability.
1. A composition comprising
A) from 55 to 78 parts by weight of at least one aromatic polycarbonate and/or aromatic polyester carbonate,
B) from 12 to 30 parts by weight of polymethyl methacrylate,
C) from 7 to 25 parts by weight of a graft polymer of,
C.1 from 25 to 50 wt. %, based on the component C, of at least one vinyl monomer on
C.2 from 75 to 50 wt. %, based on the component C, of at least one graft base selected from the group consisting of diene rubbers, EP(D)M rubbers, acrylate, polyurethane, silicone, silicone acrylate, chloroprene and ethylene/vinyl acetate rubbers,
D.1) from 0 to 5 part by weight of at least one lubricant and/or mould release agent,
D.2) from 0 to 5 part by weight of at least one antistatic and/or conductivity additive,
D.3) from 0 to 5 part by weight of at least one stabilizer,
D.4) from 0 to 7 part by weight of at least one colouring and/or pigment,
D.5) from 0 to 10 part by weight of at least one mineral filler and/or reinforcing material,
D.7) from 0 to 2 part by weight of at least one antidripping agent and/or flameproofing synergist, and
D.8) from 0 to 10 parts by weight of at least one further polymeric or oligomeric compound, the parts by weight in each case being based on the sum of the parts by weight of the components A+B+C,
wherein the aromatic polycarbonate according to the component A has a weight-average molecular weight Mw determined by GPC of from 24,000 to 30,000 g/mol, and
wherein the polymethyl methacrylate according to the component B has a weight-average molecular weight Mw, determined by GPC in THF at 40° C. with polystyrene as standard, of from 30,000 to 65,000 g/mol,and
wherein the ratio of weight-average to number-average molecular weight Mw/Mn of the polymethyl methacrylate according to the component B, determined by GPC in THF at 40° C. with polystyrene as standard, has a value from 1 to 2.5.
2. The composition according to claim 1 , wherein the polymethyl methacrylate according to the component B has a weight-average molecular weight Mw, determined by GPC in THF at 40° C. with polystyrene as standard, of from 40,000 to 62,000 g/mol.
3. The composition according to claim 1 , wherein the composition is free of flameproofing agent (D.6) and antidripping agent and flameproofing synergists (D.7).
4. The composition of claim 1 having a Vicat B120 heat distortion temperature measured according to ISO 306 of at least 110° C.
5. The composition of claim 1 , wherein the transition from ductile to brittle fracture behavior in the notched impact test according to ISO 180-1A occurs at a temperature of -10° C. or lower.
6. The composition of claim 5 , wherein the transition from ductile to brittle fracture behavior in the notched impact test according to ISO 180-1A occurs at a temperature of -20° C. or lower.
7. The composition of claim 1 comprising a total emission of volatile organic compounds measured according to VDA 277 of less than about 50 mg carbon equivalents per kg.
8. The composition of claim 1 having a residual acrylonitrile content measured by headspace method of less than about 2 ppm.
9. The composition according to claim 1 , wherein the polymethyl methacrylate according to the component B has a weight-average molecular weight Mw, determined by GPC in THF at 40° C. with polystyrene as standard, of from 50,000 to 60,000 g/mol.
10. The composition according to claim 1 , wherein the component C is an ABS polymer or MBS polymer.
11. The composition of claim 1 comprising a total emission of volatile organic compounds measured according to VDA 277 of less than about 35 mg carbon equivalents per kg.
12. A process for the production of the composition according to claim 1 , comprising mixing the components A, B, C and optionally D to form a mixture and melt compounding or melt extruding the mixture at an elevated temperature.
13. The process of claim 12 , wherein said elevated temperature is from 200° -340° C.
14. A method for production of a moulding comprising forming a moulding comprising the composition of claim 1 .
15. A moulding comprising the composition according to claim 1 .
16. A composition consisting of
A) from 55 to 78 parts by weight of at least one aromatic polycarbonate and/or aromatic polyester carbonate,
B) from 12 to 30 parts by weight of polymethyl methacrylate,
C) from 7 to 25 parts by weight of a graft polymer of,
C.1 from 25 to 50 wt. %, based on the component C, of at least one vinyl monomer on
C.2 from 75 to 50 wt. %, based on the component C, of at least one graft base selected from the group consisting of diene rubbers, EP(D)M rubbers, acrylate, polyurethane, silicone, silicone acrylate, chloroprene and ethylene/vinyl acetate rubbers,
D.1) from 0 to 5 part by weight of at least one lubricant and/or mould release agent,
D.2) from 0 to 5 part by weight of at least one antistatic and/or conductivity additive,
D.3) from 0 to 5 part by weight of at least one stabilizer,
D.4) from 0 to 7 part by weight of at least one colouring and/or pigment,
D.5) from 0 to 10 part by weight of at least one mineral filler and/or reinforcing material,
D.6) from 0 to 5 part by weight of at least one flameproofing agent,
D.7) from 0 to 2 part by weight of at least one antidripping agent and/or flameproofing synergist, and
D.8) from 0 to 10 parts by weight of at least one further polymeric or oligomeric compound, the parts by weight in each case being based on the sum of the parts by weight of the components A+B+C,
wherein the aromatic polycarbonate according to the component A has a weight-average molecular weight Mw determined by GP of from 24,000 to 30,000 g/mol,
wherein the polymethyl methacrylate according to the component B has a weight-average molecular weight Mw, determined by GPC in THF at 40° C. with polystyrene as standard, of from 30,000 to 65,000 g/mol, and
wherein the ratio of weight-average to number-average molecular weight Mw/Mn of the polymethyl methacrylate according to the component B, determined by GPC in THF at 40° C. with polystyrene as standard, has a value from 1 to 2.5.
17. The composition according to claim 16 , consisting of
A) from 55 to 78 parts by weight of the at least one aromatic polycarbonate and/or aromatic polyester carbonate,
B) from 12 to 30 parts by weight of the polymethyl methacrylate,
C) from 7 to 25 parts by weight of a the graft polymer of,
C.1 from 25 to 50 wt. %, based on the component C, of at least one vinyl monomer on
C.2 from 75 to 50 wt. %, based on the component C, of at least one graft base selected from the group consisting of diene rubbers, EP(D)M rubbers, acrylate, polyurethane, silicone, silicone acrylate, chloroprene and ethylene/vinyl acetate rubbers,
D.1) from 0 to 5 part by weight of the at least one lubricant and/or mould release agent,
D.2) from 0 to 5 part by weight of the at least one antistatic and/or conductivity additive,
D.3) from 0 to 5 part by weight of the at least one stabilizer,
D.4) from 0 to 7 part by weight of the at least one colouring and/or pigment,
D.5) from 0 to 10 part by weight of the at least one mineral filler and/or reinforcing material, and
D.8) from 0 to 10 parts by weight of the at least one further polymeric or oligomeric compound.
18. The composition according to claim 16 , consisting of
A) from 55 to 78 parts by weight of the at least one aromatic polycarbonate and/or aromatic polyester carbonate,
B) from 12 to 30 parts by weight of the polymethyl methacrylate,
C) from 7 to 25 parts by weight of the a graft polymer of,
C.1 from 25 to 50 wt. %, based on the component C, of at least one vinyl monomer on
C.2 from 75 to 50 wt. %, based on the component C, of at least one graft base selected from the group consisting of diene rubbers, EP(D)M rubbers, acrylate, polyurethane, silicone, silicone acrylate, chloroprene and ethylene/vinyl acetate rubbers,
D.1) from 0 to 5 part by weight of the at least one lubricant and/or mould release agent,
D.2) from 0 to 5 part by weight of the at least one antistatic and/or conductivity additive,
D.3) from 0 to 5 part by weight of the at least one stabilizer,
D.4) from 0 to 7 part by weight of the at least one colouring and/or pigment, and
D.5) from 0 to 10 part by weight of the at least one mineral filler and/or reinforcing material.